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Environment preservation, energy, and the growing economy are becoming strongly interconnected themes requiring new solutions to be exploited. An example of this interconnection is the demand for the development of almost zero-energy buildings, i.e. buildings capable to be almost autonomous from external energy supply or at least not dependent on the energy supply from utilities. The actual conception of a zero energy building is a very complex system formed by several subsystems, with the consequence that costs are very high and reliability relatively low. The aim of this research program is to deepen the possibility to employ the Stirling engine and cooler technology to lower the number of components required in a near zero-energy building, increase the efficiency, and contemporary raise the reliability of the overall system. Stirling cooler could be used to convert mechanical work into heating and cooling effects and produce the temperature difference by the expanding and compressing the working fluid. A similar concept of the Stirling cooler could also be adopted to develop a heat pump. Compared to the traditional vaporcompression refrigeration systems, the Stirling coolers are of higher efficiency and with no components like compressor, expansion valve, evaporator, or condensers. Therefore, they are considered to be clean cooling devices. On the other hand, the Stirling engine is an external combustion engine, which is compatible with a variety of thermal sources, such as solar radiation, waste heat, geothermal energy, combustion, and so on. With the heat input to the hot end of the engine, the Stirling engine could be operated to produce mechanical work/electricity at high thermal efficiency. In principle, the Stirling machines are capable to provide all the forms of energy (heat, cool, and electricity) that form the almost total energy load of a building.

AbstractDendronic antennae systems containing pyrene units as energy donors and a styrylpyridinium derivative as energy acceptor show efficient energy transfer from the green‐emitting pyrene excimer to the red‐emitting acceptor. For the third dendron generation the effective screening of the pyrene units on the acceptor provides thin films showing bright red emission. Single‐layer light‐emitting diodes prepared by properly balancing the dendrons and donor units concentration in polyvinylcarbazole show electroluminescence from the blue, green and red components of the monomeric donor, the donor excimer and the acceptor when excitons are generated in the polymer and subsequently transferred to the molecules by resonant energy transfer.

This paper addresses the current knowledge on climate change impacts on mass movement activity in mountain environments by illustrating characteristic cases of debris flows, rock slope failures and landslides from the French, Italian, and Swiss Alps. It is expected that events are likely to occur less frequently during summer, whereas the anticipated increase of rainfall in spring and fall could likely alter debris-flow activity during the shoulder seasons (March, April, November, and December). The magnitude of debris flows could become larger due to larger amounts of sediment delivered to the channels and as a result of the predicted increase in heavy precipitation events. At the same time, however, debris-flow volumes in high-mountain areas will depend chiefly on the stability and/or movement rates of permafrost bodies, and destabilized rock glaciers could lead to debris flows without historic precedents in the future. The frequency of rock slope failures is likely to increase, as excessively warm air temperatures, glacier shrinkage, as well as permafrost warming and thawing will affect and reduce rock slope stability in the direction that adversely affects rock slope stability. Changes in landslide activity in the French and Western Italian Alps will likely depend on differences in elevation. Above 1500 m asl, the projected decrease in snow season duration in future winters and springs will likely affect the frequency, number and seasonality of landslide reactivations. In Piemonte, for instance, 21st century landslides have been demonstrated to occur more frequently in early spring and to be triggered by moderate rainfalls, but also to occur in smaller numbers. On the contrary, and in line with recent observations, events in autumn, characterized by a large spatial density of landslide occurrences might become more scarce in the Piemonte region.

Starting from an interpretation of “sustainable mobility”, this study describes a possible taxonomy of the modalities of urban travels related to sustainability and it suggests an inclusive approach to implement urban policies for “soft mobility” inside the urban contexts. These policies aim at improving the levels of urban liveability, reducing the polluting emissions and promoting the recovery of a sober moral behaviour in acting and reacting inside the city. The underway photovoltaic bikesharing project “Bene Bike” in Benevento shows how the bike station plays an innovative role. It represents a multifunctional element able of managing material and immaterial “flows of urban travels” (people, energy, information).

Forest trees dominate many Alpine landscapes that are currently exposed to changing climate. Norway spruce is one of the most important conifer species of the Italian Alps, and natural populations are found across steep environmental gradients with large differences in temperature and moisture availability. This study seeks to determine and quantify patterns of genetic diversity in natural populations toward understanding adaptive responses to changing climate. Across the Italian species range, 24 natural stands were sampled with a major focus on the Eastern Italian Alps. Sampled trees were genotyped for 384 selected single nucleotide polymorphisms (SNPs) from 285 genes. A wide array of potential candidate genes was tested for correlation with climatic parameters. To minimize false-positive association between genotype and climate, population structure was investigated. Pairwise F ST estimates between sampled populations ranged between 0.000 and 0.075, with the highest values involving the two disjoint populations, Valdieri, on the western Italian Alps, and Campolino, the most southern population on the Apennines. Despite considerable genetic admixture among populations, both Bayesian and multivariate approach identified four genetic clusters. Selection scans revealed five F ST outliers, and the environmental association analysis detected ten SNPs associated to one or more climatic variables. Overall, 13 potentially adaptive loci were identified, three of which have been reported in a previous study on the same species conducted on a broader geographical scale. In our study, precipitation, more than temperature, was often associated with genotype; therefore, it appears as the most important environmental variable associated with the high sensitivity of Norway spruce to soil water supply. These findings provide relevant information for understanding and quantifying climate change effects on this species and its ability to genetically adapt.

The Alpine Forest Genomics Network was formed in 2011 and held its first annual meeting on June 24–26, 2012, in the Natural Park Adamello Brenta in Trentino Region, Italy. The meeting was attended by 30 researchers from the alpine region of Europe and had two primary goals: (1) for researchers to introduce each other to current and planned research activities in forest landscape genomics and (2) to develop a strategic vision for the network. A steering committee was elected and will develop a white paper over the next year. The next annual meeting will be held in Austria in June 2013.

Abstract The feasibility of integrating a commercially available reheat gas turbine with a methane steam reformer is analyzed. A slight modification to the original reheat design is proposed to improve the methane conversion rate in the reforming process and, consequently, the efficiency in recovering waste exhaust heat from the gas turbine. Two solutions are proposed for the heat recovery scheme: a first reformer has a single pressure level while the second has two in order to match the different pressures of the combustors. While the single pressure scheme gives good performance with respect to the stand alone gas turbine, the dual pressure reformer can give a further benefit, as far as an accurate optimization of the steam management is performed.

Abstract Dye-sensitized solar cells (DSSCs) with photoanodes composed of chirality selected single-wall carbon nanotubes (SWNTs) have been fabricated and tested for first time. Single chirality SWCNTs separation (93% purity) have been achieved by modifying standard size exclusion gel chromatography. Chirality selection has allowed for “tuning” of the energy barrier at the TiO2/SWNT/FTO interface, electronic conductivity enhancement, and reduced SWCNTs-ruthenium dye competition for light absorption resulting in a 81% energy conversion efficiency improvement compared to mixed chirality cells. Unfortunately, energy conversion efficiency has been limited by cells’ low shunt resistance. Additionally, SWCNTs electron transfer properties have been exploited to prepare mixed and chirality specific CNTs based DSSCs’ counter electrodes.