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Biodiesel is a fuel generally consisting of a mixture of fatty acid methyl esters (FAMEs) which is used in alternative or in combination with petroleum diesel for its environmental benefits. Biodiesel is conveniently manufactured from vegetable oils by transesterification of triglycerides with methanol. However, the process brings about the concurrent formation of glycerol, which may become an oversupplied chemical if biodiesel production keeps growing. A novel biodiesel-like material (abbreviated as DMC-BioD) was developed by reacting soybean oil with dimethyl carbonate (DMC), which avoided the co-production of glycerol. The main difference between DMC-BioD and biodiesel produced from vegetable oil and methanol (MeOH-biodiesel) was the presence of fatty acid glycerol carbonate monoesters (FAGCs) in addition to FAMEs. In the following study, details regarding synthesis and composition of DMC-BioD are provided along with physical properties relevant for its use as a fuel. In addition, the production of potential pyrogenic contaminants was investigated by analytical pyrolysis and compared with those from MeOH-biodiesel, and the model compounds tristearin, triolein, trilinolein and oleic acid glycerol carbonate ester (OAGC). The presence of FAGCs influenced both fuel and flow properties, while the distribution of main pyrogenic compounds, including polycyclic aromatic hydrocarbons (PAHs), was little affected. Benefits and drawbacks of DMC as a candidate transmethylating reagent for producing biofuel from renewable resources and alternative co-products (glycerol carbonate and glycerol dicarbonate) are discussed.

Pyroelectric energy harvesting has the ability to transform wasted heat into useful energy and as such has a potential to create “green” energy from freely available sources such as ambient temperature changes, and contribute to the fight against climate change. Current pyroelectrics applications are limited to low-power electronics, portable systems or tasks needing only very low range of power (μW–mW). Developing further this highly promising technology should ultimately lead to the creation of more powerful, autonomous and self-powered electronic devices that could one day use to recycle currently “lost” thermal energy to power electronic devices in both domestic and industrial settings. To the best of our knowledge, hexagonal phase ZnS (wurtzite ZnS) has not been studied as a possible energy harvesting pyroelectric material despite w-ZnS being isostructural to the well-exploited and widely praised hexagonal ZnO [1]. In addition, the Tc temperature (1020 ˚C for bulk material) is high enough for ZnS that it has the ability to operate at higher temperature that are good match with the working temperature of power plants and automobiles, and hence w-ZnS ceramics should have a potential to be used in pyroelectric harvesters of waste heat coming from those activities [2]. Here we report on the pyroelectric output registered for a wurtzite phase ZnS ceramic fabricated as part of our project. To probe the pyroelectric output for a w-ZnS ceramic a simple device (a “pyro-cell”) was created by evaporating gold electrods on both sides of a ceramic sample, which was mounted on a Cu-metalized rectangular insulating base (vetronite) using silver paint. This device is stable from room temperature up to approximately 180°C. Two different heating and cooling testing set-ups were established: Set-up n°1 used an industrial scale laser, providing a source with fast temperature change, and Set-up n°2 had a standard lab hot plate heating element, providing a much slower temperature change. The characterization required an accurate measurement of the currents of the order of 10-9 A. In addition, using the Pyroelectric Test System (PK‐SPIV17T, State College, PA, USA) with a Keithley 6517 B Picoammeter, we were able to measure the pyroelectric coefficient and monitor its change at different frequencies as a function of temperature from 20 °C up to 150° C, with a heating rate of between 2 and 10 °C/min. Figure 1: Pyroelectric current measurements on an ZnS ceramic sample, using testing set-up n°1. The horizontal axis shows the time (seconds). References [1] Y. Yang, W. Guo, K.C. Pradel, G. Zhu, Y. Zhou, Y. Zhang, Y. Hu, L. Lin, Z. Lin Wang, “Pyroelectric Nanogenerators for Harvesting Thermoelectric Energy”, Nano Lett, 12 (6), 2012, 2833–2838 [2] L.A. Chavez, F.O. Zayas Jimenez, B.R. Wilburn, L.C. Delfin, H. Kim, N. Love, Y. Lin, “Characterization of Thermal Energy Harvesting Using Pyroelectric Ceramics at Elevated Temperatures”, Energy Harvesting and Systems, 5(1-2), 2018, 3–10 This project was also partially supported by the Piano triennale di realizzazione 2019-2021 della ricerca di sistema elettrico nazionale – Progetto 1.3 Materiali di frontiera per usi energetici (C.U.P. code: I34I19005780001).

Synthesis of cork-derived ceria ecoceramic, an emerging porous catalyst, for enhancing solar thermochemical water splitting.

Aeroengine manufacturers must continuously develop new high-performance engines, in terms of both specific fuel consumption and pollutant emissions. During the combustion of kerosene, CO 2 and lower amounts of SO 2 , CO, NO x and hydrocarbons are produced; those gases are directly or indirectly responsible for greenhouse effect. Large emission of NO x is produced by engines during the aircraft operation in airport. In the near future, the target in Europe for the aviation sector provides a reduction of SO% of NO x and 50% of CO 2 . For this reason, the hybrid-electric propulsion systems (HEPS) are becoming a viable alternative propulsion technology in the field of aviation, useful to guarantee a massive reduction of pollution. In the paper, the authors analyze and simulate a hybrid turbine/electric engine for a passengers regional aircraft, comparing the results in terms of pollutant and fuel consumption with the conventional thermal engine ones.

Abstract This literature review was built upon recently published articles on Life Cycle Assessments (LCAs) of agricultural biogas plants, to: enhance understanding of the relevant literature in the field and the related question by readers worldwide. It was designed to highlight methodological issues and impact indicators, which best represent this research field; consequently, they should be considered in performing environmental assessments of agro-biogas derived energy systems. The literature review highlighted the wide variability of environmental results due to the ways the feedstock mixtures were produced, managed, and supplied; and due to the regions in which the anaerobic digesters were located and operated. Differences were found to be related to the aim and function of the study and to the methodological approach used, especially for the development of the environmental impact assessments. Other differences resulted from the ways the energy produced was utilised, whether it was used as an input to the natural gas national grid, and/or if it was used within the production system. The authors of this review concluded that, although much progress has been made, many unsolved challenges and methodological choices must be addressed to further improve the robustness of LCA in relation to AD and to related approaches.

En este documento, proponemos una solución de eficiencia energética para implementar la codificación de red (NC) en redes inalámbricas basada en el estándar IEEE 802.11. El mecanismo propuesto, llamado GreenCode, permite a los nodos realizar el ciclo de trabajo cambiando a un estado de baja potencia (suspensión) cuando escuchan transmisiones de paquetes codificados que no proporcionarán ninguna información nueva para ellos. Para facilitar la operación de suspensión, las transmisiones bidireccionales que involucran paquetes codificados y no codificados entre pares de nodos remitente-receptor se integran en la operación de GreenCode. Tanto los resultados analíticos como de simulación presentados en este documento muestran la alta eficiencia energética de GreenCode con ganancias de hasta el 360% en comparación con los mecanismos existentes basados en el Estándar IEEE 802.11. Dans cet article, nous proposons une solution écoénergétique pour la mise en œuvre du codage de réseau (NC) dans les réseaux sans fil basée sur la norme IEEE 802.11. Le mécanisme proposé, appelé GreenCode, permet aux nœuds de fonctionner en passant à un état de faible puissance (veille) lorsqu'ils entendent des transmissions de paquets codés qui ne leur fourniront aucune nouvelle information. Pour faciliter le fonctionnement en veille, des transmissions bidirectionnelles impliquant à la fois des paquets codés et non codés entre des paires de nœuds expéditeurs-récepteurs sont intégrées dans le fonctionnement de GreenCode. Les résultats d'analyse et de simulation présentés dans cet article montrent l'efficacité énergétique élevée de GreenCode avec des gains allant jusqu'à 360% par rapport aux mécanismes existants basés sur la norme IEEE 802.11. In this paper, we propose an energy-efficient solution for implementing Network Coding (NC) in wireless networks based on the IEEE 802.11 Standard. The proposed mechanism, called GreenCode, allows nodes to duty cycle by switching to a low-power (sleep) state when they overhear coded packet transmissions that will not provide any new information for them. To facilitate the sleep operation, bidirectional transmissions involving both coded and non-coded packets between pairs of sender-receiver nodes are integrated into the operation of GreenCode. Both analytical and simulation results presented in this paper show the high energy efficiency of GreenCode with gains of up to 360% when compared to the existing mechanisms based on the IEEE 802.11 Standard. في هذه الورقة، نقترح حلاً موفرًا للطاقة لتنفيذ ترميز الشبكة (NC) في الشبكات اللاسلكية بناءً على معيار IEEE 802.11. تسمح الآلية المقترحة، المسماة GreenCode، للعقد بدورة العمل عن طريق التبديل إلى حالة منخفضة الطاقة (السكون) عندما تسمع عمليات إرسال الحزم المشفرة التي لن توفر أي معلومات جديدة لها. لتسهيل عملية السكون، يتم دمج عمليات الإرسال ثنائية الاتجاه التي تنطوي على كل من الحزم المشفرة وغير المشفرة بين أزواج من عقد المرسل والمستقبل في تشغيل GreenCode. تُظهر كل من النتائج التحليلية والمحاكاة المقدمة في هذه الورقة كفاءة الطاقة العالية للـ GreenCode مع مكاسب تصل إلى 360 ٪ بالمقارنة مع الآليات الحالية القائمة على معيار IEEE 802.11.

It is shown that due to power take-off losses, optimal control provides maximum energy absorption, but not maximum energy production. A new reactive control criterion in the frequency-domain is deduced assuming constant power take-off efficiency, respectively, in the power feeding and power absorption parts of the wave cycle. If applied in the time-domain, this criterion requires the incident wave to be predicted some time into the future. Whilst the OWC type of Wave Energy Converters (WEC) is presented in the paper, the extension to WECs of the floating body type is also considered. Illustrative numerical results for a two-dimensional OWC of simple geometry are presented, which include the performance of this device in three wave spectra with increasing demands of active control for improved energy production. Linear hydrodynamic theory is considered throughout the paper.

Abstract European and Italian standards establish high levels of energy performance of buildings that have to be designed considering their energy balance near zero. To achieve this goal, the reduction of energy demand, attainable by improving energy efficiency of the construction, and the use of renewable energy available both on site and off site are effective solutions to be applied. In particular, in buildings that use energy produced from renewable sources, due to their unstable and unpredictable nature, having the right strategy to compensate the variations is essential. A technical solution reevaluated as a consequence of passive design principles, is to provide an adequate thermal inertia in order to store energy when it is offered and to use it when the source is not available. In these cases, the ability of construction elements to retain heat becomes fundamental as they contribute to maintain internal comfort conditions. This paper aims to investigate how various types of heating and cooling systems, based on different modes of heat transfer, are able to interact differently with the thermal mass of the building, producing a different level of its activation. The investigation considers a case study used to carry out dynamic simulation by means of DesignBuilder which is a user interface of EnergyPlus. The model consists of a building with elementary geometry and a single thermal zone, delimited by walls with outside thermal insulation and a heat accumulation layer inside. The variation of the internal temperature by using different types of conditioning system is analyzed in order to individuate the technology that takes the greatest advantages from the thermal mass.