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Abstract This paper presents a non-stoichiometric equilibrium model for the simulation of biomass downdraft gasifiers. The chemical equilibrium is determined by minimizing the Gibbs free energy. Five elements characterize the biomass and 15 chemical species are considered in the syngas. The model calculates the lower heating value of the syngas and the relative abundances of gasification products. An advantage of this model is that it can easily calculate not only the concentrations of the main gasification products, but also the concentrations of minor product, especially the pollutant chemical species containing Nitrogen and Sulfur. To analyse the model behaviour, a sensitivity analysis on process parameters is presented. The model is validated by comparing its results with the results of simulation carried out with a stoichiometric model and with experimental data found in literature. Finally, the model is applied to the study of the gasification of forest waste.

Abstract Probability density functions (PDFs) are normally used to describe wind speed distribution for the proper selection of wind turbines in a given location. The identification of a suitable PDF is fundamental for accurately assessing the wind energy potential and designing the wind farms. To achieve this objective, the use of a mixture of two truncated normal distributions (MTTND), defined for v ≥ 0 and obtained by linearly combining two normal distributions with different means and variances, is proposed in this work for the representation of the wind speed PDF. The distribution is a function of five parameters, does not require a high computational burden and allows the representation of wind calm hours (v = 0). The use of the MTTND allows an accurate estimation to be obtained of the experimental discrete distribution of the probability density and cumulative probability, and the characteristic statistical quantities used to estimate the available energy and the performance indicators in the selection of both the site and wind turbine. The validity of the use of the MTTND was verified by comparison with the most widespread PDFs in the scientific literature: Weibull, Rayleigh, lognormal, gamma, inverse Gaussian and Burr. This comparison was developed using experimental wind speed data relating to five Italian locations and a location in Colorado (USA) belonging to the National Renewable Energy Laboratory. For each location, the parameters of each PDF were obtained with the least squares non-linear regression method. The results of the comparisons, in terms of the coefficient of determination R2 and root mean square error (RMSE) for goodness of fit and in terms of relative error in the calculation of the statistical quantities, show that the use of the MTTND gives rise to greater accuracy than a conventional wind speed PDF.

Abstract Reaching universal access to electricity by 2030 requires a massive deployment of mini-grids in rural areas of developing countries. Among the many challenges hindering this process, there are the high uncertainties in assessing demand patterns in rural communities, the costs of field survey campaigns, and the absence of ample and reliable datasets coming from existing projects. This paper tries to address these issues by presenting and discussing a database of load profiles from sixty-one off-grid mini-grids from developing countries worldwide, gathered from the literature, private developers and fieldworks, and reported with technical, socio-economic and geographical characterization factors. A clustering procedure led to the identification of five archetypal load profile clusters, which are presented and analyzed together with their load duration curves. Subsequently, the distribution among the clusters of the various characterization factors selected is studied. The proposed approach allows to widen the range of load profiles usually considered, and to seek correlations between the load profile shapes, the peak power and average energy consumption per connection, the number of customers, the age of measurement, geographical position, operator model, type of tariff and generation technologies present. This work establishes a first step in the creation of a shared database for load profiles of rural mini-grids, helping to overcome the lack of available data and difficulties of demand assessment, proposing original insights for researchers to understand load patterns, and contributing to reduce risks and uncertainties for mini-grid developers.

As part of the Copenhagen Accord, individual countries have submitted greenhouse gas reduction proposals for the year 2020. This paper analyses the implications for emission reductions, the carbon price, and abatement costs of these submissions. The submissions of the Annex I (industrialised) countries are estimated to lead to a total reduction target of 12-18% below 1990 levels. The submissions of the seven major emerging economies are estimated to lead to an 11-14% reduction below baseline emissions, depending on international (financial) support. Global abatement costs in 2020 are estimated at about USD 60-100 billion, assuming that at least two-thirds of Annex I emission reduction targets need to be achieved domestically. The largest share of these costs are incurred by Annex I countries, although the costs as share of GDP are similar for Annex I as a group and the seven emerging economies as a group, even when assuming substantial international transfers from Annex I countries to the emerging economies to finance their abatement costs. If the restriction of achieving two-thirds of the emission reduction target domestically is abandoned, it would more than double the international carbon price and at the same time reduce global abatement costs by almost 25%.

The pandemic caused by Covid-19 has tested the resilience of public institutions, already burdened by a deep and complex crisis (political, economic, managerial). This crisis has revealed a discrepancy between the needs expressed by the community and the solutions adopted to satisfy them. This has been accompanied by a progressive worsening of decision-making efficiency and weak implementation capacity in a context of increasing environmental uncertainty. It is in local institutions, in particular, that the greatest problems are revealed, because of many endemic negative factors: political fragmentation, reduced economic resources, new forms of poverty. Against the background of this scenario, our study aims to analyze the reaction of local institutions to the pandemic crisis by looking at both welfare and communication services. The objective is to identify key features in understanding the resilience of municipalities. In other words, their ability to react and adapt to change, which is essential not only to deal with emergencies, such as the pandemic, but also to make the institution itself sustainable. Our interest is focused on a specific dimension of the resilience of the municipalities, related to collaboration with the third sector. The pandemic has shown that the continuous activism of non-profit organizations has allowed for the continuation of many so-called "ordinary" services, as well as the launch of several initiatives aimed at alleviating other social problems. The research has, first of all, an exploratory character that befits a new and still ongoing phenomenon. The basic questions concern the production of local welfare policies by municipalities. The data show different levels of "interventism" and different modes of communication. On this latter point, we observe the presence of significant attention-seeking among Mayors as community builders able, on the one hand, to reinforce the spirit of solidarity and, on the other, to uphold respect for the rules. On the services side, three main models of response to the pandemic emerge, two of which refer to the public-private relationship in local welfare policies. Findings suggest that these different reactions will have consequences in the immediate future for the management of the pandemic crisis (still ongoing). Specifically, the tendency is to employ a management of services based on partnership-model, which means that public-private collaboration is a pillar of local welfare. This seems to entail a greater legitimacy for individuals or associations to participate in the formulation and implementation of policies.

Environmental dataBioclimatic data and environmental data for all 56 European peatland site (geo referenced by longitude [long], latitude [lat] and altitude [ALT]. MAT = Mean annual temperature (°C), TS = Seasonality in temperature, MAP = Mean annual precipitation (mm), PS = Seasonality in precipitation, tot_sox = Total sulphur deposition SOx (mg m-2 yr-1), tot_noy = Total oxidized nitrogen deposition (mg m-2 yr-1), tot_nhx = Total reduced nitrogen deposition (mg m-2), PT warm = Lang’s moisture index. The four bioclimatic variables (MAT, TS, MAP, PS) were extracted from the WorldClim database (Hijmans, R. J., Cameron, S. E., Parra, J. L., Jones, P. G. & Jarvis, A. Very high resolution interpolated climate surfaces for global land areas. Int. J. Climatol. 25, 1965–1978 (2005)), and averaged over the 2000-2009 period. Atmospheric deposition data were produced using the EMEP (European Monitoring and Evaluation Programme)-based IDEM (Integrated Deposition Model) model (Pieterse, G., Bleeker, A., Vermeulen, A. T., Wu, Y. & Erisman, J. W. High resolution modelling of atmosphere‐canopy exchange of acidifying and eutrophying components and carbon dioxide for European forests. Tellus B 59, 412–424 (2007)) and consisted of grid cell averages of total reduced (NHx) and oxidised (NOy) nitrogen and sulphur (SOx) deposition. The moisture index (PTwarm) was calculated as the ratio between mean precipitation and mean temperature in the warmest quarter (Thornwaite, C. W. & Holzman, B. Measurement of evaporation from land and water surfaces. USDA Technical Bulletin 817, 1–143 (1942))Data 1_environmental data.txtplant community dataAbundance data (% cover) for all vascular plant and bryophyte species from five randomly chosen hummocks and lawns (0.25 m2 quadrats; ten in total) across 56 European Sphagnum-dominated peatlands were collected in two consecutive summers (2010 and 2011). Vascular plants and Sphagnum mosses were identified to the species level. Non-Sphagnum bryophytes were identified to the family level. Lichens were recorded as one group.Data 2_plant community data.txttraits vascular plantsPlant functional traits used to calculate functional indices for the vascular plant communities. Traits were extracted from LEDA (Kleyer, M. et al. The LEDA Traitbase: a database of life‐history traits of the Northwest European flora. J. Ecol. 96, 1266–1274 (2008)). Only trait data available for all species our data-set were extracted.ncomms_Data 3_traits vascular plants.txttraits SphagnumTrait values (means) for Sphagnum spp. C = tissue carbon content (mg g-1), N = tissue nitrogen content (mg g-1), P = tissue phosphorus content (mg g-1), Productivity ( St.w = stem width (mm), l.h.c. = length hyaline cells (µm), w.h.c. = width hyaline cells (µm), l.s.l. = length stem leaves (mm), w.s.l. = width stem leaves. These measured traits were complemented with traits extracted from the literature. These latter traits included plant length (Hill, M. O., Preston, C. D., Bosanquet, S. & Roy, D. B. BRYOATT: attributes of British and Irish mosses, liverworts and hornworts. Centre for Ecology & Hydrology, Huntingdon, UK (2007)), spore diameter and capsule diameter (Sundberg, S., Hansson, J. & Rydin, H. Colonization of Sphagnum on land uplift islands in the Baltic Sea: time, area, distance and life history. Journal of Biogeography 33, 1479–1491 (2006)), productivity (Gunnarsson, U. Global patterns of Sphagnum productivity. J. Bryol. 27, 269–279 (2005))ncomms_Data 4_traits Sphagnum.txt In peatland ecosystems, plant communities mediate a globally significant carbon store. The effects of global environmental change on plant assemblages are expected to be a factor in determining how ecosystem functions such as carbon uptake will respond. Using vegetation data from 56 Sphagnum-dominated peat bogs across Europe, we show that in these ecosystems plant species aggregate into two major clusters that are each defined by shared response to environmental conditions. Across environmental gradients, we find significant taxonomic turnover in both clusters. However, functional identity and functional redundancy of the community as a whole remain unchanged. This strongly suggests that in peat bogs, species turnover across environmental gradients is restricted to functionally similar species. Our results demonstrate that plant taxonomic and functional turnover are decoupled, which may allow these peat bogs to maintain ecosystem functioning when subject to future environmental change.

Project: Coupled Model Intercomparison Project Phase 6 (CMIP6) datasets - These data have been generated as part of the internationally-coordinated Coupled Model Intercomparison Project Phase 6 (CMIP6; see also GMD Special Issue: http://www.geosci-model-dev.net/special_issue590.html). The simulation data provides a basis for climate research designed to answer fundamental science questions and serves as resource for authors of the Sixth Assessment Report of the Intergovernmental Panel on Climate Change (IPCC-AR6). CMIP6 is a project coordinated by the Working Group on Coupled Modelling (WGCM) as part of the World Climate Research Programme (WCRP). Phase 6 builds on previous phases executed under the leadership of the Program for Climate Model Diagnosis and Intercomparison (PCMDI) and relies on the Earth System Grid Federation (ESGF) and the Centre for Environmental Data Analysis (CEDA) along with numerous related activities for implementation. The original data is hosted and partially replicated on a federated collection of data nodes, and most of the data relied on by the IPCC is being archived for long-term preservation at the IPCC Data Distribution Centre (IPCC DDC) hosted by the German Climate Computing Center (DKRZ). The project includes simulations from about 120 global climate models and around 45 institutions and organizations worldwide. Summary: These data include the subset used by IPCC AR6 WGI authors of the datasets originally published in ESGF for 'CMIP6.ScenarioMIP.CMCC.CMCC-CM2-SR5.ssp245' with the full Data Reference Syntax following the template 'mip_era.activity_id.institution_id.source_id.experiment_id.member_id.table_id.variable_id.grid_label.version'. The CMCC-CM2-SR5 climate model, released in 2016, includes the following components: aerosol: MAM3, atmos: CAM5.3 (1deg; 288 x 192 longitude/latitude; 30 levels; top at ~2 hPa), land: CLM4.5 (BGC mode), ocean: NEMO3.6 (ORCA1 tripolar primarly 1 deg lat/lon with meridional refinement down to 1/3 degree in the tropics; 362 x 292 longitude/latitude; 50 vertical levels; top grid cell 0-1 m), seaIce: CICE4.0. The model was run by the Fondazione Centro Euro-Mediterraneo sui Cambiamenti Climatici, Lecce 73100, Italy (CMCC) in native nominal resolutions: aerosol: 100 km, atmos: 100 km, land: 100 km, ocean: 100 km, seaIce: 100 km.

Datasets associated with Agostini, S., Houlbreque, F., Biscéré, T., Harvey, B. P., Heitzman, J. M., Takimoto, R., et al. (2020). Greater mitochondrial energy production provides resistance to ocean acidification in ‘winning’ hermatypic corals. Front. Mar. Sci. 7. doi:10.3389/fmars.2020.600836.