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According to the renewable energy directive 2009/28/EC, the European Union Member States should increase by 2020 the use of renewable energy to 20% of gross final energy consumption and to reach a mandatory share of 10% renewable energy in the transport sector. This study aims to quantify the impact of 2020 bioenergy targets on the land use in the EU, based on the projections of the National Renewable Action Plans in four scenarios: Scenario 1. Bioenergy targets according to NREAPs; Scenario 2. Bioenergy targets according to NREAPs, no second generation biofuels; Scenario 3. Bioenergy targets according to NREAPs, reduced import of biofuels and bioliquids; Scenario 4. Bioenergy targets according to NREAPs, high imports of biofuels and bioliquids. This study also considers the credit for co-products generated from biofuel production. The analysis reveals that the land used in the EU for bioenergy would range between 13.5 Mha and 25.2 Mha in 2020. This represent between 12.2% and 22.5% of the total arable land used and 7.3% and 13.5% of the Utilised Agricultural Area (UAA). In the NREAPS scenario, about 17.4 Mha would be used for bioenergy production, representing 15.7% of arable land and 9.4% of UAA. The increased demand from biofuels would lead to an increased generation of co-products, replacing conventional fodder for animal feed. Considering the co-products, the land used for bioenergy would range between 8.8 Mha and 15.0 Mha in 2020 in the various scenarios. This represent between 7.9% and 13.3% of the total arable land used in the EU and 4.7% and 8.0% of the UAA. In the NREAPS scenario, when co-products are considered, about 10.3 Mha would be used for biofuels, bioliquids and bioenergy production, representing 9.3% of arable land and 5.6% of agricultural land. This study further provides detailed data on the impact on land use in each Member State.

Abstract In recent years living walls have increasingly spread, thus becoming a diffuse architectural envelope cladding technology. Consequently, a more precise understanding of their thermal behavior and impact on the building energy balance are needed. One of the most important effects provided by the use of living walls is the shading of the building envelope, with clear benefits during the cooling period. Furthermore, many features characterize the thermal behavior of living walls, namely plant species, leaf area index (LAI), evapotranspiration, emissivity and air cavity type. All these particular characteristics have been accounted in the mathematical model developed in the frame of the presented research, whose aim is to provide a tool for the prediction of the thermal behavior of living walls. Two kinds of living walls, one with grass and closed air cavity and the other one with vertical garden and open air cavity were considered. The results achieved by means of the developed model show a good agreement with the measurements also supported by model efficiency indexes such as Nash–Sutcliffe efficiency index (NSEC). Values of around 0.7 were obtained for the NSEC index for both the investigated living walls.

The paper proposes a critical assessment of municipal solid waste gasification today, starting from basic aspects of the process (process types and steps, operating and performance parameters) and arriving to a comparative analysis of the reactors (fixed bed, fluidized bed, entrained bed, vertical shaft, moving grate furnace, rotary kiln, plasma reactor) as well as of the possible plant configurations (heat gasifier and power gasifier) and the environmental performances of the main commercially available gasifiers for municipal solid wastes. The analysis indicates that gasification is a technically viable option for the solid waste conversion, including residual waste from separate collection of municipal solid waste. It is able to meet existing emission limits and can have a remarkable effect on reduction of landfill disposal option.

It's not only the carbon in the trees Forest loss affects climate not just because of the impacts it has on the carbon cycle, but also because of how it affects the fluxes of energy and water between the land and the atmosphere. Evaluating global impact is complicated because deforestation can produce different results in different climate zones, making it hard to determine large-scale trends rather than more local ones. Alkama and Cescatti conducted a global assessment of the biophysical effects of forest cover change. Forest loss amplifies diurnal temperature variations, increases mean and maximum air temperatures, and causes a significant amount of warming when compared to CO 2 emission from land-use change. Science , this issue p. 600

A procedure for the design of an aerobic cometabolic process for the on-site degradation of chlorinated solvents in a packed bed reactor was developed using groundwater from an aquifer contaminated by trichloroethylene (TCE) and 1,1,2,2-tetrachloroethane (TeCA). The work led to the selection of butane among five tested growth substrates, and to the development and characterization from the site's indigenous biomass of a suspended-cell consortium capable to degrade TCE (first order constant: 96 L gprotein(-1) day(-1) at 30 °C and 4.3 L gprotein(-1) day(-1) at 15 °C) with a 90 % mineralization of the organic chlorine. The consortium immobilization had strong effects on the butane and TCE degradation rates. The microbial community structure was slightly changed by a temperature shift from 30 to 15 °C, but remarkably affected by biomass adhesion. Given the higher TCE normalized degradation rate (0.59 day(-1) at 15 °C) and attached biomass concentration (0.13 gprotein Lbioreactor(-1) at 15 °C) attained, the porous ceramic carrier Biomax was selected as the best option for the packed bed reactor process. The low TeCA degradation rate exhibited by the developed consortium suggested the inclusion of a chemical pre-treatment based on the TeCA to TCE conversion via β-elimination, a very fast reaction at alkaline pH. To the best of the authors' knowledge, this represents the first attempt to develop a procedure for the development of a packed bed reactor process for the aerobic cometabolism of chlorinated solvents.

Binary and ternary systems of Ni(2+), Zn(2+), and Pb(2+) were investigated at initial metal concentrations of 0.5, 1.0 and 2.0mM as competitive adsorbates using Arthrospira platensis and Chlorella vulgaris as biosorbents. The experimental results were evaluated in terms of equilibrium sorption capacity and metal removal efficiency and fitted to the multi-component Langmuir and Freundlich isotherms. The pseudo second order model of Ho and McKay described well the adsorption kinetics, and the FT-IR spectroscopy confirmed metal binding to both biomasses. Ni(2+) and Zn(2+) interference on Pb(2+) sorption was lower than the contrary, likely due to biosorbent preference to Pb. In general, the higher the total initial metal concentration, the lower the adsorption capacity. The results of this study demonstrated that dry biomass of C. vulgaris behaved as better biosorbent than A. platensis and suggest its use as an effective alternative sorbent for metal removal from wastewater.

The importance of emission control has increased sharply due to increased need of energy from combustion. However, biomass utilization in energy production is not free from problems because of physical and chemical characteristics which are substantially different from conventional energy sources. In this situation, the quantity and quality of emissions as well as used renewable source as wood or corn grain are often unknown. To assess this problem the paper addresses the objectives to quantify the amount of greenhouse gases during the combustion of corn as compared to the emissions in fossil combustion (natural gas, LPG and diesel boiler). The test was carried out in Friuli Venezia Giulia in 2006-2008 to determine the air pollution (CO, NO, NO2, NOx, SO2 and CO2) from fuel combustion in the family boilers with power between 20-30 kWt. The flue gas emission was measured with a professional semi-continuous multi-gas analyzer, (Vario plus industrial, MRU air Neckarsulm-Obereisesheim). Data showed a lower emission of fossil fuel compared to corn in family boilers in reference to pollutants in the flue gas (NOx, SO2 and CO). In particular way the biomass combustion make a higher concentration of carbon monoxide (for a incomplete combustion because there aren’t a good mixing between fuel and air) and nitrogen oxides (in relation at higher content of nitrogen in herbaceous biomass in comparison of another fuel). Proceedings of the 19th European Biomass Conference and Exhibition, 6-10 June 2011, Berlin, Germany, pp. 1296-1304

The main challenge for concrete industry - and in general for construction materials - is to serve the two major needs of human society, the protection of the environment, on one hand, and the requirements of buildings and infrastructures by the world?s growing population, on the other. In the past concrete industry has satisfied these needs well. However, for a variety of reasons, the situation has changed dramatically in the last years. First of all, the concrete industry is the largest consumer of natural resources. Secondly, Portland cement, the binder of modern concrete mixtures, is not as environmentally friendly. The world's cement production, in fact, contributes to the earth's atmosphere about 7% of the total CO2 emissions, CO2 being one of the primary greenhouse gas (GHG) responsible for global warming and climate change. As a consequence, concrete industry in the future has to face two antithetically needs. In other words, how the concrete industry can feed the growing population needs being - at the same time - sustainable? The answer to this question is represented by the ?3R-Green Strategy? widely discussed in the first chapter of this PhD thesis: Reduction in consumption of gross energy for construction materials production, Reduction in polluting emissions and Reduction in consuming not renewable natural resources. In particular, this thesis is focused on the alternative binders to Portland cement such as alkali-activated slag cements and calcium sulphoaluminate cement-based binders in order to manufacture sustainable mixtures for special applications such as repair mortars, lightweight reinforced plasters and concretes for slabs on ground. The experimental results show the feasibility of manufacturing both EN 1504-3 R3 class mortars and Portland-free concretes for jointless slabs on ground with calcium sulphoaluminate cement, supplementary cementitious materials (fly ash, ground granulated blast furnace slag) and hydrated lime instead of Portland cement. Moreover, alkali-activated mortars and concretes seem to be a reasonable alternative to natural hydraulic lime-based and/or traditional Portland cement-based mixtures for rehabilitation or restoration of ancient masonry buildings and existing concretes structures. Finally, a new sustainability index was developed taking into account the environmental impact, the performances and the durability of mixtures. In particular, in the environmental impact section, the natural raw materials consumption, the greenhouse gas emissions and the energy consumption have been considered. Furthermore, depending on the applications and the environments, design parameters and properties related to durability have been assigned to each mixture. less