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Project: Coupled Model Intercomparison Project Phase 6 (CMIP6) datasets - These data have been generated as part of the internationally-coordinated Coupled Model Intercomparison Project Phase 6 (CMIP6; see also GMD Special Issue: http://www.geosci-model-dev.net/special_issue590.html). The simulation data provides a basis for climate research designed to answer fundamental science questions and serves as resource for authors of the Sixth Assessment Report of the Intergovernmental Panel on Climate Change (IPCC-AR6). CMIP6 is a project coordinated by the Working Group on Coupled Modelling (WGCM) as part of the World Climate Research Programme (WCRP). Phase 6 builds on previous phases executed under the leadership of the Program for Climate Model Diagnosis and Intercomparison (PCMDI) and relies on the Earth System Grid Federation (ESGF) and the Centre for Environmental Data Analysis (CEDA) along with numerous related activities for implementation. The original data is hosted and partially replicated on a federated collection of data nodes, and most of the data relied on by the IPCC is being archived for long-term preservation at the IPCC Data Distribution Centre (IPCC DDC) hosted by the German Climate Computing Center (DKRZ). The project includes simulations from about 120 global climate models and around 45 institutions and organizations worldwide. Summary: These data include the subset used by IPCC AR6 WGI authors of the datasets originally published in ESGF for 'CMIP6.AerChemMIP.MIROC.MIROC6' with the full Data Reference Syntax following the template 'mip_era.activity_id.institution_id.source_id.experiment_id.member_id.table_id.variable_id.grid_label.version'. The MIROC6 climate model, released in 2017, includes the following components: aerosol: SPRINTARS6.0, atmos: CCSR AGCM (T85; 256 x 128 longitude/latitude; 81 levels; top level 0.004 hPa), land: MATSIRO6.0, ocean: COCO4.9 (tripolar primarily 1deg; 360 x 256 longitude/latitude; 63 levels; top grid cell 0-2 m), seaIce: COCO4.9. The model was run by the JAMSTEC (Japan Agency for Marine-Earth Science and Technology, Kanagawa 236-0001, Japan), AORI (Atmosphere and Ocean Research Institute, The University of Tokyo, Chiba 277-8564, Japan), NIES (National Institute for Environmental Studies, Ibaraki 305-8506, Japan), and R-CCS (RIKEN Center for Computational Science, Hyogo 650-0047, Japan) (MIROC) in native nominal resolutions: aerosol: 250 km, atmos: 250 km, land: 250 km, ocean: 100 km, seaIce: 100 km.

A mixed-potential-type sensor was fabricated using yttria-stabilized zirconia and various zinc-based oxide sensing electrodes (SEs) with the goal of detecting hydrocarbons (HCs) in automobile exhausts. Among the various zinc-based oxide SEs examined, ZnCr 2 O 4 was found to give highly selective and sensitive response to C 3 H 6 at 550°C even in the presence of 5 vol % H 2 O. The Aemf (electromotive force) of the sensor showed almost linear dependence with the logarithm of C 3 H 6 concentration. In addition, it was found that the sensitivity of the present sensor varied linearly with the carbon number of various HCs examined.

Global warming caused by the emission of fossil fuel consumption has become critical, leading to the inevitable trend of clean energy development. Of the power generation systems using solar energy, the floating photovoltaic (FPV) system is a new type, attracting wide attention because of its many merits. The latest progress in the research and applications of FPVs from multiple aspects is summarized in this paper. First, the development of FPVs is briefly described with a summary of typical installed FPV systems. Innovative photovoltaic design concepts and hybrid usage with other renewable energies are emphasized for offshore applications. Furthermore, critical structural design considerations are discussed, particularly emphasizing critical aspects such as load estimations, wave-structure interaction analysis, floating structure types, and mooring system design. Finally, several significant future challenges to the development and applications of marine FPV systems are identified, including survivability in the open sea, long-term reliability, and environmental impact. It aims to provide a broad overview of the development status, offering limited insights into the trends and challenges for marine FPV systems.

Abstract not Available.

The influence of microporous layer (MPL) design parameters for gas diffusion layers (GDLs) on the performance of polymer electrolyte fuel cells (PEFCs) was clarified. Appropriate MPL design parameters vary depending on the humidification of the supplied gas. Under low humidification, decreasing both the MPL pore diameter and the content of polytetrafluoroethylene (PTFE) in the MPL is effective to prevent drying-up of the membrane electrode assembly (MEA) and enhance PEFC performance. Increasing the MPL thickness is also effective for maintaining the humidity of the MEA. However, when the MPL thickness becomes too large, oxygen transport to the electrode through the MPL is reduced, which lowers PEFC performance. Under high humidification, decreasing the MPL mean flow pore diameter to 3 μm is effective for the prevention of flooding and enhancement of PEFC performance. However, when the pore diameter becomes too small, the PEFC performance tends to decrease. Both reduction of the MPL thickness penetrated into the substrate and increase in the PTFE content to 20 mass% enhance the ability of the MPL to prevent flooding.

Abstract In order to investigate the potential of high temperature gas-cooled reactors (HTGRs) for transmutation of long-lived fission products (LLFPs), numerical simulation of four types of HTGRs were carried out. In addition to the gas-turbine high temperature reactor system “GTHTR300”, which is the subject of our previous research, a small modular HTGR plant “HTR50S” and two types of plutonium burner HTGRs “Clean Burn with MA” and “Clean Burn without MA” were considered. The simulation results show that an early realization of LLFP transmutation using a compact HTGR may be possible since the HTR50S can transmute fair amount of LLFPs for its thermal output. The Clean Burn with MA can transmute a limited amount of LLFPs. However, an efficient LLFP transmutation using the Clean Burn without MA seems to be convincing as it is able to achieve very high burn-ups and produce LLFP transmutation more than GTHTR300. Based on these results, we propose utilization of variety of HTGRs for LLFP transmutation and storage.

Abstract An estimation of passive cooling techniques was conducted for 14 cities in Brazil, using a fairly accurate algorithm that accounts for heat conduction, convection, radiation, and evaporation; this was done to determine the amount of heat gain/loss of room air, defined as a particular quantitative index for passive techniques. Heat gains and losses were calculated for four envelope conditions – namely, insulated, high-albedo, wet surface, and a combination of the previous two – and compared to a case assumed to be the standard condition. A conclusion drawn was that a passive design is efficient in decreasing the need for cooling in typical dwellings in Brazil; solutions should differ with regional climate characteristics. In semi-arid areas, evaporative cooling showed the best results. Reduced heat gain was found during the warm seasons for all cities, along with increased heat gain during the cool seasons for mid-latitude cities. In particular, a combination of high-albedo enveloping and evaporation can greatly decrease heat gain in building walls. High-albedo surfaces in the sub-tropical areas found in southern Brazil are more efficient. It is suggested that passive techniques should be conceived in such a way so as to work during the cooling season and be disabled during mild ones.

The paper describes the development of chemical modules simulating the prechemical and chemical stages of charged particle tracks in pure liquid water. These calculations are based on our physical track structure codes for electrons and ions (KURBUC, LEPHIST and LEAHIST) which provide the initial spatial distribution of H2O+, H2O* and subexcitation electrons at approximately 10(-15) s. We considered 11 species and 26 chemical reactions. A step-by-step Monte Carlo approach was adopted for the chemical stage between 10(-12) s and 10(-6) s. The chemistry codes enabled to simulate the non-homogeneous chemistry that pertains to electron, proton and alpha-particle tracks of various linear energy transfers (LET). Time-dependent yields of chemical species produced by electrons and ions of different energies were calculated. The calculated primary yields (G values at 10(-6) s) of 2.80 for OH and 2.59 for e(aq)- for 1 MeV electrons are in good agreement with the published values. The calculated G values at 10(-6) s for a wide range LETs from of 0.2 to 235 keV microm(-1) were obtained. The calculations show the LET dependence for OH and H2O2. The electron penetration ranges were calculated in order to discuss the role of low energy electrons.

Abstract The synthesis of LiNi0.5Mn1.5O4 has been reported to change the crystal structure with the oxygen partial pressure and affect the battery characteristics. LiNi0.5Mn1.5O4 involves the formation of impurities, such as LixNi1−xO, LixMn3−xO4, and Li2CO3, at a high temperature range exceeding 700 °C because oxygen loss occurs during synthesis. LiNi0.5Mn1.5O4 electrochemically contains Mn4+, however, Mn3+ is formed because of oxygen deficiency. The Li–Ni–Mn-oxide causes a disproportionation of Mn3+ in an oxygen-deficient state. The synthesized Li–Ni–Mn-oxide nanoparticles at 10,000 K by induction thermal plasma formed spinel-type LiNi0.5Mn1.5O4 (space group Fd3m) of Mn4+. The crystal structure of the cubic-spinel nanoparticles approached a LiNi0.5Mn1.5O4 single phase as the flow rate of O2 increased from 2.5 to 5 l min−1. The formation of LiNi0.5Mn1.5O4 was shown to be accelerated by increasing the O2 gas flow rate. The measured current–voltage characteristics of LiNi0.5Mn1.5O4 nanoparticles appeared at around 4.7–4.8 V as the reaction peak of Ni2+/Ni3+ and Ni3+/Ni4+. In contrast, the Mn of the Li–Ni–Mn-oxide nanoparticles synthesized in the oxygen-deficient state was less than trivalent, which caused disproportionation of Mn. The measured current-voltage characteristics showed peak of an oxygen desorption at near 4.6 V. This study investigated the factors affecting the crystal structure formation and electrochemical properties of high-voltage LiNi0.5Mn1.5O4 nanoparticles formed in thermal plasma.

The effects of multiple inclined blades on the flow and mixing characteristics of a high-viscosity fluid were investigated in an agitated thin-film evaporator under isothermal conditions. The residence time distribution, mean residence time, material exchange-rate and power consumption were measured, and the effects of the inclined blades on the measured quantities were examined by comparison with the measurements in a vertical-blade evaporator. The results show that the flow and mixing characteristics in the axial direction are almost the same in the inclined-blade evaporator as in the vertical-blade evaporator, and that the mean residence time can be controlled by using inclined blades. Multiple inclined blades can provide almost the same material exchange rate as multiple vertical blades, even when the distance between upper and lower inclined blades is reduced to about half that between vertical blades. The results further show that the power consumption of inclined blades can be reduced to about half that of vertical blades.