• Energy Research
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Interfacial resistance at electrode‐high Li+ conductive solid electrolytes must be reduced well to develop high‐power all‐solid‐state batteries using oxide‐based solid electrolytes (Ox‐SSBs). Herein, crystalline electrode films of LiCoO2 (LCO) are formed on a high Li+ conductive crystalline‐glass solid electrolyte sheet, Li1.3Al0.3Ti2(PO4)3 (LATP) (σ25 °C = 1 × 10−4 S cm−1), at room temperature by aerosol deposition (AD), and the effects of the annealing temperature on the interfacial resistivities (Rint) at the LCO/LATP are investigated. The Rint visibly increases by annealing over 500 °C with the growth of Co3O4 as a reactant. In contrast, Rint is reduced to ≈100 Ω cm2 by low‐temperature annealing at 250–350 °C due to superior contact through the structural rearrangement of an artificial metastable interface formed by the AD. These results are applied to bulk‐type Ox‐SSB, Li/Li7La3Zr2O12(LLZ)/LCO–LATP, and our best Ox‐SSB delivers a discharge capacity of 100 mA cm−2 at 100 °C.

Abstract Gas crossover is an unavoidable phenomenon in proton exchange membrane fuel cells. Gas crossover leads to heat and water generations without conducting any useful works, hence increasing fuel consumption. Particularly, Gas crossover can result in the degradation and formation of pinholes inside the membrane. Therefore, the gas crossover is a critical factor significantly affecting the durability of a fuel cell and quality of the membrane. Herein, we numerically investigate the effects of gas crossover across the membrane in a proton exchange membrane fuel cell. A two-dimensional, two-phase, steady state model of the gas crossover using the partial differential equation solver FreeFem++, was built to investigate the crossover characteristics of hydrogen and oxygen across the membrane versus changes in operating conditions and various geometric structure of components in the proton exchange membrane fuel cell. Results indicated that higher equivalent weight of Nafion® is required to significantly decrease gas crossover phenomenon while the cell performance was reduced negligibly. In addition, as the increase in the stoichiometric flow ratio and channel length, the gas crossover decreased and the cell performance improved.

Chinese long flame coal named Naomaohu was pyrolyzed at 600 °C under hydrogen pressures of 0.1–3.0 MPa. The resultant chars were gasified at 900 °C under carbon dioxide to illustrate the correlatio...

The microdosimetric kinetic (MK) model underestimates the cell-survival fractions for high linear energy transfer (LET) and high dose irradiations. To address the issue, some researchers previously extended the MK model to the stochastic microdosimetric kinetic (SMK) model. In the SMK model, the radiation induced cell-survival fractions were estimated from the specific energies z d and z n absorbed by a microscopic subnuclear structure domain and a cell nucleus, respectively. By taking the stochastic nature of z n as well as that of z d into account, the SMK model could reproduce the measured cell-survival fractions for radiations with wide LET and dose ranges. However, treatment planning based on the SMK model was unrealistic in clinical practice due to its long computation time and huge memory space required for the computation. In this study, we modified the SMK model to shorten the computation time and to reduce the memory space required for the computation. By using the dose-averaged cell-nucleus specific energy per event [Formula: see text] in the SMK formalism, the stochastic nature of z n was reflected onto the estimated cell-survival fractions. The accuracy of the modified SMK model was examined through the comparison between the estimated and the measured survival fractions of human salivary gland tumor cells and V79 cells. We then implemented the modified SMK model into the in-house treatment planning software for scanned charged-particle therapy to validate its applicability in clinical practice. As examples, treatment plans of helium-, carbon-, and neon-ion beams were made for an orbital tumor case. The modified SMK model could reproduce the measured cell-survival fractions more accurately compared to the MK model especially for high-LET and high-dose irradiations. In summary, the modified SMK model offers the accuracy and simplicity required in treatment planning of scanned charged-particle therapy for wide LET and dose ranges.

Abstract It is demonstrated that the fuel deposit has a significant influence on the NOx and particular matter (PM) emissions, especially with the consideration of the more and more strict emission regulations issued by the governments, which results in that the near-nozzle spray has been received the increased attention, recently. In this study, the near-nozzle spray characteristics at the initial and end stages were investigated by a high-resolution camera with a laser as the light source. At the initial stage, microscopic behaviors of the near-nozzle spray were observed at upstream, midstream and downstream, respectively. Moreover, the injection frequency was changed to check the effect on the near-nozzle spray morphology. Next, the micro spray length, width and angle were obtained from the processed images. While, at the end stage, the near-nozzle spray evolutions were observed and characterized at 0.5, 0.3, 0.2 and 0.1 ms before the end of injection (BEOI), the end of injection (EOI), 0.05, 0.1, 0.15 and 0.2 ms after the end of injection (AEOI), respectively. Furthermore, the droplet area, spray area without droplets, droplet number and averaged diameter were calculated. Results show that three structures of the near-nozzle spray at the initial stage can be classified as mushroom, steeple and cylinder shapes. And the injection frequency has an influence on their formations owing to the residual fuel and sucked air AEOI. Moreover, although more droplets can be identified at the end stage with time, it does not indicate the better atomization. On the contrary, these droplets AEOI are responsible for the injector deposit in the real engine.

Active pharmaceutical ingredients are composed of single-component or multicomponent crystals. Multicomponent crystals include salts, co-crystals, and solvates. Indinavir sulfate is the ethanol solvate form of indinavir that is known to deliquesce through moisture absorption. However, the detailed behavior of solvent molecules in the crystal has not been investigated. In this study, we studied the desolvation mechanism of indinavir sulfate ethanol and investigated the behavior of solvent molecules in the solid from. Indinavir sulfate ethanol contained 1.7 molecules of ethanol, 0.7 of which desolvated at room temperature. They were originally two ethanol solvent molecules; one molecule of ethanol desolvated at room temperature, and the conformation of the remaining ethanol and t-butyl groups changed in conjunction with the removal of one ethanol molecule. Desolvation could hardly be detected by powder X-ray diffraction; however, it was detected using terahertz spectroscopy. Terahertz measurement of desolvation showed a high correlation with thermogravimetry data, suggesting that desolvation could be observed non-destructively using terahertz spectroscopy. We concluded that indinavir sulfate 1 ethanol deliquesced at 60% relative humidity, and it turned into an amorphous solid after drying.

Abstract Novel interfacial microwave heating of a layered structure has been applied to the process of low-temperature annealing of titania mesoporous films for dye-sensitized solar cells. Interfacial microwave annealing dramatically enhances the cell performances as compared with conventional heating in an electric oven. The improvement of cell performance is attributed to the electron transport properties in the titania films annealed by MW resulting in longer diffusion length as compared with conventional heating.