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Abstract The clathrate hydrate formation at the interface between liquefied carbon dioxide (CO 2 ) and liquid water is one of the key processes in the course of direct CO 2 disposal into deep seas—an option to mitigate the emission of CO 2 into the atmosphere. Eight different models have been proposed so far on the formation and metabolic self-preservation of a hydrate film at the interface and also the mass transfer of CO 2 across the hydrate film. This paper reviews those rival models one by one and illustrates how they are discrepant. Each model is critically examined, and if any, its weakness in physical reality or mathematical formulation is pointed out. The state of the art of hydrate-film modeling thus revealed suggests the necessity of more careful consulting of pertinent experimental observations to establish our physical view about hydrate films, which should serve as the base of any further work on hydrate-film modeling.

Abstract This paper attempts to measure consumers' perceived net benefits (or net costs) of energy-saving measures in using energy-consuming durable goods. Using the estimated net costs and the volume of CO2 reduced by the measures, a marginal abatement cost (MAC) curve for the average household's CO2 emissions is produced. An analysis using the curve suggests that in order to provide households with an incentive to take actions that can lead to CO2 emission reductions in using energy-consuming durables, a high level of carbon price is needed. In addition, a regression analysis reveals that the net benefits of the measures are larger for households that put a higher priority on energy saving, for those living in detached houses, for those with a smaller number of persons living together, and for those with less income. The result of the analysis using the MAC curve may suggest that promoting energy-saving behavior will require not only a policy to provide economic incentives but also interventions to influence psychological factors of household behavior.

Abstract This paper reviews the current status of biodiesel production mainly under supercritical conditions. Various methods such as homogeneous acid- and alkali-catalyzed transesterification, heterogeneous acid and alkali-catalyzed transesterification, enzyme-catalyzed transesterification, and supercritical reactions have been employed so far to synthesize biodiesel. Herein, we review the reaction mechanisms and experimental results for these approaches. Recently, supercritical biodiesel production has undergone a vigorous development as the technology offers several advantages over other methods, including the fact that it does not require a catalyst, short residence time, high reaction rate, no pretreatment requirement, and applicability to a wide variety of feedstock. This technology was first designed for biodiesel production using methanol and ethanol. Biodiesel production without glycerol as a byproduct is attractive and has been achieved using supercritical methyl acetate and dimethyl carbonate (DMC). Most recently, biodiesel production in supercritical tert-butyl methyl ether (MTBE) has been developed also. In this review, supercritical biodiesel production will be discussed in detail. Empirical rate expressions are derived for biodiesel production in supercritical methanol, ethanol, methyl acetate, DMC, and MTBE in this study for the first time. These rate equations are critical to predicting biodiesel yields and to comparing the reaction behaviors in different solvents. Lastly challenges for improving energy recovery in supercritical biodiesel production and recommendations for future work are provided.

This study presents an investigation on the influence of hydrothermally treated municipal solid waste (MSW) on the co-combustion characteristics with different rank coals, i.e. Indian, Indonesian and Australian coals. MSW blends of 10%, 20%, 30% and 50% (wt.%) with different rank coals were tested in a thermogravimetric analyser (TGA) in the temperature range from ambient to 700 °C under the heating rate of 10 °C/min. Combustion characteristics such as volatile release, ignition and burnout were studied for the blend fuel. Different ignition behavior was observed depending on the blends composition and the coal rank. The result of this work indicates that the blending of MSW improves devolatization properties of coal. But it was found that the co-combustion characteristics of MSW and coal blend cannot be predicted only from the pyrolytic and or devolatization phenomena as the other factors such as the coal quality also plays a vital role in deciding the blends co-combustion characteristics. The TGA combustion profiles showed that the combustion characteristics of blends followed those of parent fuels in both an additive and non-additive manners. These experimental results help to understand and predict the behavior of coal and MSW blends in practical applications.

A balance between industrial pollution and economic growth becomes a major policy issue to attain a sustainable society in the world. To discuss the problem from economics and business perspectives, this study proposes a new use of DEA (Data Envelopment Analysis) as a methodology for unified (operational and environmental) assessment. A unique feature of the proposed approach is that it separates outputs into desirable and undesirable categories. Such separation is important because energy industries usually produce both desirable and undesirable outputs. This study discusses how to unify the two types of outputs under natural and managerial disposability. The proposed DEA approach evaluates various organizations by the three efficiency measures such as OE (Operational Efficiency), UEN (Unified Efficiency under Natural disposability) and UENM (Unified Efficiency under Natural and Managerial disposability). An important feature of UENM is that it separates inputs into two categories and unifies them under the two disposability concepts in addition to the proposed output separation and unification. This study incorporates an amount of capital assets for technology innovation, as one of the two input group, into the measurement of UENM. Then, it compares UENM with the other two efficiency measures. This study is the first research effort in which DEA has an analytical capability to quantify the importance of investment on capital assets for technology innovation. To confirm the practicality of the proposed approach, this study applies the three efficiency measures to a data set regarding manufacturing and non-manufacturing industries of 47 prefectures in Japan. This study empirically confirms the validity of Porter hypothesis in Japanese manufacturing industries, so implying that environmental regulation has been effective for betterment on the performance of Japanese manufacturing industries. Another important finding is that the emission of greenhouse gases is a main source of unified inefficiency in the two groups of industries. Therefore, Japanese industries, examined in this study, need to make their efforts to reduce the greenhouse gas emissions and air pollution substances by investing in capital assets for technology innovation.

The concept of resilience is a crucial part in crafting visions of desirable futures designed to withstand the widest variety of external shocks to the system. Backcasting scenarios are widely used to envision desirable futures with a discontinuous change from the present in mind. However, less effort has been devoted to developing theoretical frameworks and methods for building backcasting scenarios with a particular focus on resilience, although resilience has been explored in related sustainability fields. This paper proposes a method that helps design backcasting scenarios for resilient futures. A characteristic of the method is to delineate “collapse” futures, based upon which resilient futures are described to avoid the various collapsed states. In the process of designing backcasting scenarios, fault tree analysis (FTA) is used to support the generation of various risk factors and countermeasures to improve resilience. In order to test the effectiveness of the proposed method, we provide a case study to describe resilient energy systems for a Japanese community to 2030. Four expert workshops involving researchers from different disciplines were organized to generate diversified ideas on resilient energy systems. The results show that three scenarios of collapsed energy systems were described, in which policy options to be taken toward achieving resilient energy systems were derived.

Climate change is triggering a global reorganization of marine life. Biogeographical transition zones, diversity-rich regions straddling biogeographical units where many species live at, or close to, their physiological tolerance limits (i.e., range distribution edges), are redistribution hotspots that offer a unique opportunity to understand the mechanisms and consequences of climate-driven thermophilization processes in natural communities. In this context, we examined the impacts of climate change projections in the 21st century (2026-2100) on marine biodiversity in the Eastern Bering and Chukchi seas within the Pacific Arctic, a climatically exposed and sensitive boreal-to-Arctic transition zone. Overall, projected changes in species distributions, modeled using species distribution models, resulted in poleward increases in species richness and functional redundancy, along with pronounced reductions in phylogenetic distances by century's end (2076-2100). Future poleward shifts of boreal species in response to warming and sea ice changes are projected to alter the taxonomic and functional biogeography of contemporary Arctic communities as larger, longer-lived and more predatory taxa expand their leading distributional margins. Drawing from the existing evidence from other Arctic regions, these changes are anticipated to increase the susceptibility and vulnerability of the Arctic ecosystems, as trophic connectance between biological components increases, thus decreasing the modularity of Arctic food webs. Our results demonstrate how integrating multiple diversity facets can provide key insights into the relationships between climate change, species composition and ecosystem functioning across marine biogeographic regions.

Abstract Decarbonization of the energy system is a key goal of the Paris Agreements, in order to limit temperature rises to under 2° Celsius. Hydrogen has the potential to play a key role through its versatile production methods, end uses and as a storage medium for renewable energy, engendering the future low-carbon energy system. This research uses a global model cognizant of energy policy, technology learning curves and international carbon reduction targets to optimize the future energy system in terms of cost and carbon emissions to the year 2050. Exploring combinations of four exploratory scenarios incorporating hydrogen city gas blend levels, nuclear restrictions, regional emission reduction obligations and carbon capture and storage deployment timelines, it was identified that hydrogen has the potential to supply approximately two percent of global energy needs by 2050. Irrespective of the quantity of hydrogen produced, the transport sector and passenger fuel cell vehicles are consistently a preferential end use for future hydrogen across regions and modeled scenarios. In addition to the potential contribution of hydrogen, a shift toward renewable energy and a significant role for carbon capture and storage is identified to underpin carbon target achievement by 2050.

Abstract The methane reforming process combined with metal–oxide reduction was examined on iron-based oxides of Ni(II)–, Zn(II)–, and Co(II)–ferrites, for the purpose of converting solar high-temperature heat to chemical fuels of CO-rich syngas and reduced metal oxide as storage and transport of solar energy. It was found that the Ni(II)-doping effectively improves the reactivity of magnetite as an oxidant for methane reforming. A two-step cyclic steam reforming of methane, which produces CO-rich syngas and hydrogen uncontaminated with carbon oxides alternately in the separate steps, was successfully demonstrated by using a ZrO 2 -supported Ni(II)–ferrite (Ni 0.39 Fe 2.61 O 4 /ZrO 2 ) as a working material in the temperature range of 1073–1173 K. The produced CO-rich syngas had the H 2 /CO ratio that was more suitable for methanol production than that produced by a conventional single-step steam reforming. This syngas production using the Ni 0.39 Fe 2.61 O 4 /ZrO 2 as an oxidant was also demonstrated under direct irradiation by a solar-simulated, high-flux visible light in laboratory-scale fixed bed system. The directly-irradiated Ni 0.39 Fe 2.61 O 4 /ZrO 2 particles acted simultaneously as good radiant absorbers and reactive chemical reactants to yield more than 90% of methane conversion to a 2:1 molar mixture of CO and H 2 under flux irradiation of 500 kW m −2 in the residence time less than 1 s.