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This study introduces novel phenothiazine-based organic dyes, 2-LBH-100, 2-LBH-44, and 2-Ryu-4, specifically designed for quasi-solid-state dye-sensitized solar cells (QsDSSCs). Employing a donor-π-acceptor architecture, these dyes incorporate varying electron-donating moieties, including bis(3-(hexyloxy)phenyl)amine and diphenylamino, coupled with a cyanoacrylic acid acceptor. Alkoxy substitutions in 2-LBH-100 and 2-LBH-44 enhanced solubility and dye loading on TiO2, leading to improved performance in QsDSSCs. 2-LBH-100 exhibited a power conversion efficiency (PCE) exceeding 5% with excellent stability, while 2-LBH-44 demonstrated a PCE of over 3%, increasing to 4% over time. 2-Ryu-4, with its diphenylamino donor, achieved an initial PCE of over 6%. This research highlights the crucial role of donor–acceptor interactions in optimizing organic dye design for high-performance QsDSSCs, paving the way for efficient and stable next-generation solar energy technologies.

The paper presents a preliminary technical-economic comparison between a 3 kV DC railway and the use of trains with on-board storage systems. Numerical simulations have been carried out on a real railway line, which presents an electrified section at 3 kV DC and a non-electrified section, currently covered by diesel-powered trains. Different types of ESS have been analyzed, implementing the models in Matlab/Simulink environment. A preparatory economic investigation has been carried out.

Lithium-ion batteries exhibit a dynamic voltage behaviour depending nonlinearly on current and state of charge. The modelling of lithium-ion batteries is therefore complicated and model parametrisation is often time demanding. Grey-box models combine physical and data-driven modelling to benefit from their respective advantages. Neural ordinary differential equations (NODEs) offer new possibilities for grey-box modelling. Differential equations given by physical laws and NODEs can be combined in a single modelling framework. Here we demonstrate the use of NODEs for grey-box modelling of lithium-ion batteries. A simple equivalent circuit model serves as a basis and represents the physical part of the model. The voltage drop over the resistor–capacitor circuit, including its dependency on current and state of charge, is implemented as a NODE. After training, the grey-box model shows good agreement with experimental full-cycle data and pulse tests on a lithium iron phosphate cell. We test the model against two dynamic load profiles: one consisting of half cycles and one dynamic load profile representing a home-storage system. The dynamic response of the battery is well captured by the model.

Mixing under high pressure conditions plays a central role in several engineering applications, such as direct-injection engines and liquid rocket engines. Numerical flow simulations have become a complementary tool to study the mixing process under these conditions but require complex thermodynamic modeling as well as validation with accurate experimental data. For this reason, we use experiments of supercritical single-phase jet mixing from the literature, where the mixing is quantified by the mixture speed of sound, as a reference for our work. We here focus on the thermodynamic modeling of multi-component flows under high pressure conditions and the analytical calculation of the mixture speed of sound. Our thermodynamic model is based on cubic equations of state extended for multi-components. Using an extension of OpenFOAM, we perform large-eddy simulations of hexane and pentane injections and compare our results with the experimentally measured mixture speed of sound at specific positions. The simulation results show the same characteristic trends, indicating that the mixing effects are well reproduced in the simulations. Additionally, the effect of the sub-grid scale modeling is assessed by comparing results using different models (Smagorinsky, Vreman, and Wall-Adapting Local Eddy-viscosity). The comprehensive simulation data presented here, in combination with the experimental data, provide a benchmark for numerical simulations of jet mixing in high pressure conditions.

Intra-day price spreads are of interest to electricity traders, storage and electric vehicle operators. This paper formulates dynamic density functions, based upon skewed-t and similar representations, to model and forecast the German electricity price spreads between different hours of the day, as revealed in the day-ahead auctions. The four specifications of the density functions are dynamic and conditional upon exogenous drivers, thereby permitting the location, scale and shape parameters of the densities to respond hourly to such factors as weather and demand forecasts. The best fitting and forecasting specifications for each spread are selected based on the Pinball Loss function, following the closed-form analytical solutions of the cumulative distribution functions.

Global fossil fuel reserves are declining due to differential uses, especially for power generation. Everybody can help to do their bit for the environment by using solar energy. Geographically, Bangladesh is a potential zone for harnessing solar energy. In March 2021, the renewable generation capacity in Bangladesh amounted to 722.592 MW, including 67.6% from solar, 31.84% from hydro, and 0.55% from other energy sources, including wind, biogas, and biomass, where 488.662 MW of power originated from over 6 million installed solar power systems. Concurrently, over 42% of rural people still suffer from a lack of electricity, where solar energy can play a vital role. This paper highlights the present status of various forms of solar energy progress in Bangladesh, such as solar parks, solar rooftops, solar irrigation, solar charging stations, solar home systems, solar-powered telecoms, solar street lights, and solar drinking water, which can be viable alternative sources of energy. This review will help decision-makers and investors realize Bangladesh’s up-to-date solar energy scenario and plan better for the development of a sustainable society.

This paper presents a one-dimensional finite-volume model of an unglazed photovoltaic/thermal (PVT) solar collector. The unit consists of a conventional solar photovoltaic (PV) collector coupled with a suitable heat exchanger. In particular, the collector includes a roll bond heat exchanger and it is not equipped with back and frame insulation. The system is discretized along the flow direction (longitudinal) of the cogenerative collector. For each finite-volume element of the discretized computational domain, mass and energy balances are implemented. The collector geometry and materials parameters are taken from a commercially available device. An on-field experimental investigation is performed in order to validate the proposed model. The model is used to evaluate both electrical and thermodynamic parameters for each element of the domain and for fixed operating conditions. Finally, a sensitivity analysis is also performed in order to investigate the energetic performance of the cogenerative collector as a function of the main design/environmental parameters.