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While firms understand that implementing green supply chain management (GSCM) is important, they seem uncertain about how to manage their green initiatives by looking beyond their own facilities. Building a green supply chain requires the participation of all partner firms across the supply chain. However, partner firms are different in size, situation, capabilities, and even industries. Thus, encouraging them to participate in green initiatives is difficult. Many small and medium enterprises (SMEs) hesitate to comply with green initiatives as they require a substantial amount of investment. This study empirically examines the causal relationship between the partnership governance mechanism and the success of GSCM. Based on transaction-cost economics theory (i.e., opportunism) and relational perspectives (i.e., trust) as the theoretical background, this study found that governance mechanisms between suppliers and manufacturers are positively related to GSCM performance. It showed that formal governance is important in the process-management side, while relational governance is critical for sharing knowledge in GSCM. The implications of the study results provide strategic insights on how the choice of governance mechanism affects GSCM performance and thus a firm’s competitiveness.

Pharmaceutical and personal care products (PPCPs) are discharged into receiving water bodies mainly from sewage treatment plants. Due to the inefficient removal in conventional wastewater treatment facilities, PPCPs have become a major concern to aquatic ecosystems, water quality, and public health worldwide since they cause harmful effects on aquatic life and human even at low doses. Among the PPCPs, carbamazepine (CBZ) is one of the most commonly prescribed anticonvulsant drugs and consumed more than 1,000 tons per year. Due to its structural complexity, CBZ is known as recalcitrant compound highly stable during wastewater treatment. Consequently, it has become one of the most frequently detected pharmaceuticals in waste water, surface water, and even drinking water. In this study, Korean indigenous microalgae strains were tested as eco-friendly and cost-effective solutions for CBZ removal. Based on the preliminary biological CBZ degradation tests, Tetradesmus obliquus KNUA061 demonstrating the best CBZ removal rate was selected for further experiments. In order to increase strain KNUA061's CBZ removal efficiency, NaOCl, which is widely accepted in the water purification process, was used as an additional stimulus to induce stress conditions. At around 20 μg L−1 CBZ, addition of 1.0 mg NaOCl resulted in approximately 20% of removal rate increase without suppressing cells growth. Roughly 90% of CBZ remained its original form and the composition of the transformed secondary metabolites was less than 10% during the biodegradation process by the microalga. Based on the results of the antioxidant enzyme activities, degree of lipid oxidation, and amino acid contents, it was concluded that the redox-defence system in microalgal cells may have been activated by the NaOCl treatment. Biomass analysis results showed that higher heating value (HHV) of strain KNUA061 biomass was higher than those of lignocellulosic energy crops suggesting that it could be utilized as a possible renewable energy source. Even though its biodiesel properties were slightly below the international standards due to the high PUFA contents, the biodiesel produced from T. obliquus KNUA061 could be used as a blending resource for transportation fuels. It was also determined that the microalgal biomass has acceptable feasibility as a sustainable dietary supplement feedstock due to its high essential amino acid contents.

This review covers the main examples of fuel-free light-driven micro/nanomotors and their different swimming styles, highlighting the most important parameters to consider when designing photocatalytic-based devices with a high propulsion efficiency.

Geotrichum sp. strain, which is able to decolorize azo dyes enzymatically, was used in this study for decolorization of synthetics solutions contaminated by toxic azo dyes orange G, trypan blue, azorubine, and methyl red. The biomass of Geotrichum sp. was immobilized in calcium alginate and polyacrylamide gels and used for the decolorization of tested azo dyes in fluidized bed bioreactor. The highest specific decolorization rate was obtained when the fungal biomass was entrapped in calcium alginate beads. Immobilized biomass in calcium alginate continuously decolorized azo dyes after eight repeated batch decolorization experiments without significant loss of activity whereas polyacrylamide immobilized biomass retained only 10% of its activity after 4 days of incubation. The effects of some physicochemical parameters such as temperature, pH, and dyes concentration on decolorization performance of isolated fungal strain were also investigated.

Abstract Considerable effort has been directed at improving the power conversion efficiency of organic photovoltaics, using oxide/metal/oxide multilayers as transparent electrodes, because of their numerous advantages including lower sheet resistance, higher transmittance, and higher flexibility in comparison to typical indium tin oxides. However, to date, most organic photovoltaics based on oxide/metal/oxide electrodes exhibit a lower conversion efficiency than indium tin oxide-based organic photovoltaics, without any clarification. In this investigation, we identify crucial factors that influence the power conversion efficiency of oxide/metal/oxide-based organic photovoltaics to fully exploit the potential of these devices, based on the correlation between the optical cavity and the transmittance. For this purpose, we fabricate five sets of inverted organic photovoltaics using poly({4,8-bis[(2-ethylhexyl)oxy]benzo[1,2-b:4,5-b′]dithiophene-2,6-diyl}{3-fluoro-2-[(2-ethylhexyl)carbonyl]thieno[3,4-b]thiophenediyl}) and [6,6]-Phenyl C71 butyric acid methyl ester-based active layers and ZnO/Ag/ZnO electrodes with top ZnO layers of varying thicknesses, with reference organic photovoltaics using indium tin oxides, on both rigid and flexible substrates. The highest power conversion efficiency of 8.71% and 7.53% is obtained from single-junction organic photovoltaics with 40/9/8-nm-thick ZnO/Ag/ZnO electrodes on each substrate, due to strong micro-cavity effects between the top and bottom Ag layers, despite the relatively low transmittance of the electrode. This result is supported by the relation between the electric-field intensity and the transmittance curves of the ZnO/Ag/ZnO/solution-based ZnO/active bulk optical stacks based on simulation results. Furthermore, flexible organic photovoltaics with the ZnO/Ag/ZnO electrodes demonstrate much better performance in mechanical bending tests in comparison to the performance of standard indium tin oxide-based organic photovoltaics, and the previously reported oxide/metal/oxide-based organic photovoltaics.

Discovery of a chemically stable, light absorbing and low resistivity metal oxide with band edges aligned to the water redox potentials has been a goal of physical scientists for the past forty years. Despite an immense amount of effort, no solution has been uncovered. We present a combined theoretical and experimental exploration of a series of unconventional ternary cobalt spinel oxides, which offer chemical functionality through substitution on the octahedral spinel B site. First-principles predictions of the substitution of group 13 cations (Al, Ga, In) in Co3O4 to form a series of homologous CoX2O4 spinel compounds are combined with experimental synthesis and photoelectrochemical characterization. Ultimately, while tunable band gaps in the visible range can be obtained, the material performance is limited by poor carrier transport properties associated with small polaron carriers. Future design pathways for metal oxide exploration are discussed.

We report a novel approach for a fast phase transition of FAPbI3 at low-temperature and the effective removal of interfacial recombination in MAPbI3.

AbstractSituated in the near of Schwarze Pumpe power station southeast of Berlin, Germany, Vattenfall operates a 30 MWth pilot plant in order to investigate the Oxyfuel process. Hitachi Power Europe delivered a DST-burner (DST-Brenner®) for the indirect firing system of the plant which was installed without modifications to the pressure part of the boiler. The combustion behavior during Oxyfuel operation was investigated and optimal burner settings for different operation points were established. The results show that the burner can be operated in a wide range of oxygen concentrations in the oxidant gas flow. The burner is characterized by low emissions of carbon monoxide and nitrogen oxides. The high flame stability was found to be unaffected by operational influences such as fluctuations in the coal mass flow, coal quality or soot blowing. Due to the high flame stability the change-over from air blown to Oxyfuel combustion can be realized very easily and is automated. During Oxyfuel operation measurements of temperatures and flue gas species in the flame were performed. The measurement values were compared with the values of the combustion modeling by computational fluid dynamics. The good agreement between both measurement and modeling shows the suitability of the applied models to predict the combustion behavior under Oxyfuel conditions.