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The objectives of this study are to: estimate African countries’ Government Openness Index (AGOI) to see the updated progress of open government in those countries, examine which areas African countries should further improve for sustainable development, and compare the performance of the Open Government Partnership (OGP) member countries to that of non-OGP countries in forming AGOI. This study developed the AGOI with 32 selected countries and four factors (ACC (accountability), TRA (transparency), CPF (citizen participation and freedom) and ICT (information and communication technology)) for the period of 2006–2019. The results show that African countries have continuously increased the values of AGOI for the period. ACC has barely changed, but TRA has increased slightly. Both CPF and ICT have increased at higher growth rates during the period. The OGP group reached much better scores than their non-OGP counterparts, with positive differences in AGOI, ICT, CPF, and TRA, except ACC. The results of this study suggest that the constantly increasing CPF and ICT levels in countries that have similar conditions as African countries should be further improved to function well enough to build accountability and transparency. It is also recommended that countries join the OGP in order to move towards improving government openness and creating sustainable development.

As high rate charge and discharge characteristics of energy storage devices become more important with the market of electric vehicles intensively growing, the kinetics of lithiation or delithiation of electrode materials for lithium ion batteries require enhancement. Graphites, the most widely used anode materials, have a limited power density at high discharge rates, while their alternatives, such as silicon and transition metal oxides, show even inferior rate capability. This work was motivated from an idea of what if the edge opening of graphite was zipped more open to lithium ions in the electrolyte. By edge-selective functionalization, the peripheral d-spacing of graphite (d(0)) was locally controlled. Larger values of d(0) led to higher capacity especially at high discharge rates. Around 2-fold enhancement of capacity or energy density was achieved at 50C discharge rate from 110 to 190 mAh g(-1) by exfoliating graphite locally in its edge region. Also, the d(0) dependency of delithiation kinetics confirmed that the electrochemical step of Li(+) influx into or efflux out of the interlayer space of graphite is possibly the rate-determining step of lithiation or delithiation.

This paper presents experimental results of the impact of CO(2) co-feed on a gasification/pyrolysis process for various feedstocks (biomass, coal, and municipal solid waste (MSW)). Various feedstocks were thermo-gravimetrically characterized under various atmospheric conditions and heating rates. A substantial amount of char burn out was identified in the presence of CO(2) via a series of thermo-gravimetric analysis tests, which enabled high conversion of final mass (approximately 99%) to be achieved. The impact of CO(2) co-feed on the volatilization regime during the pyrolysis/gasification process was not apparent at a heating rate of 10-40 degrees C min(-1). However, the impact of CO(2) on the volatilization regime at a fast heating rate (950 degrees C min(-1)) was substantial. For example, significant enhancement in the generation of CO, by a factor of approximately 2, was observed in the presence of CO(2). The generation of major chemical species, such as CH(4) and C(2)H(4), were enhanced, but this was not as apparent as in the case with CO. In addition, introducing CO(2) to the pyrolysis/gasification process enabled the amount of condensable liquid hydrocarbons, such as tar (approximately 30-40%) to be significantly reduced in the presence of CO(2), in that injecting CO(2) into the pyrolysis/gasification process expedites cracking the volatilized chemical species. Experimental work confirmed that biomass and MSW could be feasible and desirable feedstocks for the pyrolysis/gasification process as these feedstocks can be easily treated compared to coal. To extend this understanding to a more practical level, various feedstocks were tested in a tubular reactor and drop tube reactor under various experimental conditions.

Abstractπ‐Conjugated polyelectrolytes (CPEs) have been studied as interlayers on top of a separate hole transport layer (HTL) to improve the wetting, interfacial defect passivation, and crystal growth of perovskites. However, very few CPE‐based HTLs have been reported without rational molecular design as ideal HTLs for perovskite solar cells (PeSCs). In this study, the authors synthesize a triphenylamine‐based anionic CPE (TPAFS‐TMA) as an HTL for p‐i‐n‐type PeSCs. TPAFS‐TMA has appropriate frontier molecular orbital (FMO) levels similar to those of the commonly used poly(bis(4‐phenyl)‐2,4,6‐trimethylphenylamine) (PTAA) HTL. The ionic and semiconducting TPAFS‐TMA shows high compatibility, high transmittance, appropriate FMO energy levels for hole extraction and electron blocking, as well as defect passivating properties, which are confirmed using various optical and electrical analyses. Thus, the PeSC with the TPAFS‐TMA HTL exhibits the best power conversion efficiency (PCE) of 20.86%, which is better than that of the PTAA‐based device (PCE of 19.97%). In addition, it exhibits negligible device‐to‐device variations in its photovoltaic performance, contrary to the device with PTAA. Finally, a large‐area PeSC (1 cm2) and mini‐module (3 cm2), showing PCEs of 19.46% and 18.41%, respectively, are successfully fabricated. The newly synthesized TPAFS‐TMA may suggest its great potential as an HTL for large‐area PeSCs.

Cogeneration plants, which simultaneously produce electricity and heat energy, have been introduced increasingly for commercial and domestic applications in Korea because of their energy efficiency. The optimal plant configuration of a specific commercial building can be determined by selecting the sizes and the number of cogeneration systems and the auxiliary equipment based on the annual demands of electricity, heating and cooling. In this study, a mixed-integer, linear programming, utilizing the branch and bound algorithm was used to obtain the optimal solution. Both the optimal configuration system equipment and the optimal operational mode were determined based on the annual cost method for the installation of a cogeneration system to a hospital and a group of apartments in Seoul, Korea. In addition, the economic evaluation for the optimal cogeneration system depending on the fuel tariff system was calculated. A short payback period and higher internal rate of return on the initial investment were found to be essential for the adoption of cogeneration plants to hospitals and apartments.

A high efficiency 2 stage vapour compression cycle is developed for domestic refrigerator-freezer application. The 2 stage refrigeration system consists of two evaporators, two compressors, a condenser, two heat exchangers, expansion valves and a vapour-liquid separator. A new high efficiency cycle is selected depending on the arrangement of evaporators and compressors. The cycle simulation is carried with the refrigerant of R600a. It is found the 2 stage cycle with two serial evaporators and two parallel compressors gives the highest COP. COP of 2 stage cycle with two serial evaporators and two parallel compressors is more than 10.74% COP of 2 stage cycle with two parallel evaporators and two serial compressors.

The potential of deoiled Azolla pinnata biomass (DAB) as electrode and substrate was evaluated for microbial fuel cell (MFC) operation. The anode electrode was fabricated using biochar obtained by subjecting DAB to pyrolysis at 600 °C, while the reducing sugars after hydrolysis of DAB by acid pretreatment was used as substrate. The post pyrolyzed biochar (P-DAB) was characterized for structural and elemental functionalities using SEM, XRD and Raman spectroscopy, whereas the reducing sugar obtained from hydrolyzed DAB (H-DAB) was analyzed for its composition. Experimental results indicated that at a given 3 g COD/L resulted in a voltage of 382 mV with 65.6% of COD reduction in closed circuit (CC) mode of operation. Cyclic voltammetric analysis depicted maximum oxidative and reductive peak currents of 3.42 mA and -4.0 mA. Noticeable peaks were also identified in CC (-0.2 V to +0.2 V and -0.19 V to -0.3 V) and OC (+0.2 V to +0.4 V and -0.1 V to -0.3 V) corresponding to complex IV cytochrome c couples (cytochrome Cox (Cyt Cox)/cytochrome Crd (Cyt Crd)), signifying the participation of electron carriers during electron transfer. The microbiome diversity showed dominance of Proteobacteria, a phylum known for exo-electrogenic bacterial species. The DAB-derived products account to environmental sustainability and support circular bioeconomy in a biorefinery mode.

Mobile edge computational power faces the difficulty of balancing the energy consumption of many devices and workloads as science and technology advance. Most related research focuses on exploiting edge server computing performance to reduce mobile device energy consumption and task execution time during task processing. Existing research, however, shows that there is no adequate answer to the energy consumption balances between multi-device and multitasking. The present edge computing system model has been updated to address this energy consumption balance problem. We present a blockchain-based analytical method for the energy utilization balance optimization problem of multi-mobile devices and multitasking and an optimistic scenario on this foundation. An investigation of the corresponding approximation ratio is performed. Compared to the total energy demand optimization method and the random algorithm, many simulation studies have been carried out. Compared to the random process, the testing findings demonstrate that the suggested greedy algorithm can improve average performance by 66.59 percent in terms of energy balance. Furthermore, when the minimum transmission power of the mobile device is between five and six dBm, the greedy algorithm nearly achieves the best solution when compared to the brute force technique under the classical task topology.

A noncompartmented microbial fuel cell (NCMFC) composed of a Mn(IV)-carbon plate and a Fe(III)-carbon plate was used for electricity generation from organic wastewater without consumption of external energy. The Fe(III)-carbon plate, coated with a porous ceramic membrane and a semipermeable cellulose acetate film, was used as a cathode, which substituted for the catholyte and cathode. The Mn(IV)-carbon plate was used as an anode without a membrane or film coating. A solar cell connected to the NCMFC activated electricity generation and bacterial consumption of organic matter contained in the wastewater. More than 99 degrees of the organic matter was biochemically oxidized during wastewater flow through the four NCMFC units. A predominant bacterium isolated from the anode surface in both the conventional and the solar cell-linked NCMFC was found to be more than 99 degrees similar to a Mn(II)-oxidizing bacterium and Burkeholderia sp., based on 16S rDNA sequence analysis. The isolate reacted electrochemically with the Mn(IV)-modified anode and produced electricity in the NCMFC. After 90 days of incubation, a bacterial species that was enriched on the Mn(IV)-modified anode surface in all of the NCMFC units was found to be very similar to the initially isolated predominant species by comparing 16S rDNA sequences.