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Carbon capture and storage (CCS) technology has been studied actively in recent years to address global warming. This paper aimed to make a consistent comparison of different capture technologies applied to the natural gas-fired combined cycle (NGCC). Multiple power plant systems based on a standard NGCC using three different carbon capture technologies (post-combustion, pre-combustion, and oxycombustion) were proposed, and their net performance was compared. The optimal pressure ratio of the oxy-combustion technology system was obtained. The variations in the net cycle performance of the three systems were compared using the specific CO2 capture. The net power of the post-combustion capture scheme is lower than that of all other systems, but it has the highest efficiency. However, its biggest disadvantage is a much lower CO2 capture rate than the oxy-combustion capture which exhibits nearly 100 % capture rate. The conclusion is that the oxy-combustion capture would provide both the highest net efficiency and power output if a high capture rate of over 92 % was required.

Enriching the interface: metal–organic framework-derived copper oxide nanowires with abundant crystalline interfaces contribute to the efficient electrochemical CO2 reduction towards fast hydrocarbon generation.

Abstract Herein, pyrolysis of chicken manure is investigated to establish a sustainable platform for the disposal of chicken manure while efficiently recovering energy as a form of syngas. To this end, this study lays great emphasis on the exploitation of CO2 in pyrolysis of chicken manure. As an initial assay for the role CO2 in the pyrolysis process, thermal degradation of chicken manure in N2 and CO2 is characterized thermo-gravimetrically. Except the temperature regime (≥720 °C) governed by the Boudouard reaction, the TGA results with chicken manure do not reveal any differences associated with physical aspects such as onset and end temperatures. For in-depth study, pyrogenic products generated from pyrolysis of chicken manure in N2 and CO2 are characterized. Particularly, an enhanced generation of CO is substantial at temperatures higher than 500 °C. This enhanced generation of CO is likely due to an enhanced thermal cracking behavior of volatile organic carbons (VOCs) evolved from pyrolysis of chicken manure. The enhancement of CO generation is catalytically expedited by biogenic salt such as calcite (CaCO3) in chicken manure. The introduced approach for utilizing CO2 in pyrolysis could be a sustainable option to treat biowaste such as chicken manure along with developing an effective waste-to-energy strategy.

Abstract The co-combustion of sewage sludge and woody biomass is a key issue in coal power plants. Different combustion and ash behaviors of sewage sludge and woody biomass cause unpredictable operating concerns. In this study, the combustion and ash agglomeration behavior of blended fuel of sewage sludge and woody biomass (BSW) were investigated while coal co-combusted with it. Thermogravimetric analysis (TGA) revealed that adding a high amount of BSW into the coal lowered volatilization, ignition, and burn-out temperature. The char combustion reactivity of coal differed from that of BSW. The shrinking core model (SCM) and volumetric reaction model (VRM) were used to fit the char combustion reactivity of coal and BSW. In the case of ash agglomeration behavior, BSW addition led to increasing particle agglomeration at fouling temperatures. In particular, phosphorus composition influenced particle growth, which was verified using scanning electron microscopy with energy dispersive X-ray spectroscopy (SEM–EDX) analysis. Furthermore, the ash mixture ratio of BSW and coal changed the intensity of the phosphorus-bearing mineral phase from X-ray diffraction (XRD) analysis, and finally influenced the melting temperature of the ash.

Abstract A change in the thermal environment of an urban area affects health, living conditions, and energy consumption. In urban planning, urban parks are one of the methods for improving the thermal environment and saving cooling energy. Urban park construction can mitigate temperature, but it also causes urban development by increasing local attractiveness. To achieve efficient energy saving through parks in urban planning, the purpose of this study is to investigate the relationship between building energy consumption and urban characteristics both before and after the construction of an urban park. This study targeted Seoul's Gyeongui line forest, which was recently converted into a linear park on the former railway as an urban regeneration project. We analyzed the relationship between energy consumption and urban characteristics using a regression model, focusing on the changes before and after the construction. In this study, urban characteristics include environment, building physical characteristics, and economic variables. The results show that the construction of the urban park reduced not only temperature but also building energy consumption. The energy reduction effect of the park was limited to a marginal distance. Meanwhile, the urban park construction caused land prices to rise and prompted new development, and this changed the urban characteristics of the area and affected energy consumption. Despite changes in urban characteristics, urban park planning is an effective methods of reducing the energy consumption involved in cooling urban areas. We recommend comprehensive consideration of the urban factors when making park policy to reduce urban temperature and energy consumption.

Plastic film mulching (FM) became a general practice to enhance crop productivity and its net primary production (NPP), but it can increase greenhouse gas (GHG) emissions. The proper addition of organic amendments might effectively decrease the impact of FM on global warming. To evaluate the feasibility of biomass addition on decreasing this negative influence, cover crop biomass as a green manure was incorporated with different recycling levels (0-100% of aboveground biomass) under FM and no-mulching. The net global warming potential (GWP) which integrated with soil C stock change and GHG (N2O and CH4) fluxes with CO2-equivalent was evaluated during maize cultivation. Under the same biomass incorporation, FM significantly enhanced the grain productivity and NPP of maize by 22-61 and 18-58% over no-mulching, respectively. In contrast, FM also highly increased the respired C loss, which was 11-95% higher than NPP increase, over no-mulching. Irrespective with biomass recycling ratio and mulching system, negative NECB which indicates the decrease of soil C stock was observed, mainly due to big harvest removal. FM decreased more soil C stock by 57-158% over no-mulching, but its C stock was clearly increased with increasing biomass addition. FM significantly increased total N2O and CH4 fluxes by 4-61 and 140-600% over no-mulching, respectively. Soil C stock changes mainly decided net GWP scale, but N2O and CH4 fluxes negligibly influenced. As a result, FM highly increased net GWP over no-mulching, while this net GWP was clearly decreased with increasing biomass application. However, cover cropping, and its biomass recycling was not enough to compensate the negative impact of FM on global warming. Therefore, more biomass incorporation might be essential to compensate this negative effect of FM.

Abstract Since the increase in greenhouse gas emissions has increased the global warming potential, an international agreement on carbon emissions reduction target (CERT) has been formulated in Kyoto Protocol (1997). This study aimed to develop a framework for the analysis of the low-carbon scenario 2020 to achieve the national CERT. To verify the feasibility of the proposed framework, educational facilities were used for a case study. This study was conducted in six steps: (i) selection of the target school; (ii) establishment of the reference model for the target school; (iii) energy consumption pattern analysis by target school; (iv) establishment of the energy retrofit model for the target school; (v) economic and environmental assessment through the life cycle cost and life cycle CO 2 analysis; and (vi) establishment of the low-carbon scenario in 2020 to achieve the national CERT. This study can help facility managers or policymakers establish the optimal retrofit strategy within the limited budget from a short-term perspective and the low-carbon scenario 2020 to achieve the national CERT from the long-term perspective. The proposed framework could be also applied to any other building type or country in the global environment.

Electronic waste (e-waste) is the world's fastest-growing type of waste, with lighting accounting for 9% of the total. Light-emitting diodes (LEDs) are composed of the most concentrated critical elements (Ag and Au) and recovery of these metals could generate economic benefits and reduce the burdens of environmental pollution; nevertheless, the absence of information about their composition currently presents a challenge in recycling these metals with minimal prospects for recovery. This study assessed the distribution and variation of elemental concentrations of 16 different elements in three generations of LEDs (12 different LED units): sub-mounted-device (SMD #10), chip-on-board (COB #1), and positive-intrinsic-negative (PIN #1). The SMD LEDs contained a considerable amount of Au with a median average concentration of 1204 mg/kg (ranging from 323 - 3687 mg/kg), which was similar to that of COB (1550 mg/kg), but higher than that of PIN LED (175 mg/kg). Based on the total threshold limiting concentration (TTLC), the Cu levels (605,823 mg/kg) in the SMD package exceeded the regulatory limits (2500 mg/kg). Concentrations of the hazardous elements Cr (29 mg/kg), Pb (12 mg/kg), Cd (0.1 mg/kg), and As (1 mg/kg) in the LED packages were within the regulatory limits. To recycle precious metals and other technological metals, a well-organized and dedicated optimized assessment of the value of metals is required especially in accordance with the concept of criticality and recyclability. Two factors, i.e., a high resource index (RI) and technology index (TI), suggest the importance of waste to the economy and has a significant potential for recycling with less processing burdens. Present findings indicated that the COB and a few of the studied SMD LEDs (3020, 4014, 5630, and 7020), exhibit high criticality and recyclability. For the RI and TI index, the contribution of metals such as Cu, Fe, Al, and Au were dominant. These findings can serve as a reference for the development of a viable approach for the recycling and recovery of targeted metals from LED e-waste.