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[EN] The objective of this article is to compare the behaviour of the most representative domestic hot water systems (DHW) in single-family buildings. The study evaluates the energy consumption, equivalent CO2 emissions and cost for each system over a 15-year life period. This analysis is carried out in four cli- matic zones across Europe to observe the influence of climatic conditions on the results. The four climatic zones are located in the cities of Athens, Madrid, London and Berlin. The analysed systems are: a) natural gas-fired instantaneous water heaters, b) electric storage water heater, c) solar thermal system with gas- fired instantaneous, d) solar thermal system with electric storage water heater, e) air-source heat pump, f) photovoltaic system with electric storage water heater, and g) photovoltaic system with air-source heat pump. This range of technologies covers the most likely solutions to be implemented across domestic buildings in Europe.The heat pump system (HPWH) with PV considering self-consumption shows the lowest environmen- tal impact in all zones, but is not an attractive investment in the coldest zones due to lower natural gas prices. Thermal solar systems have a high purchase and maintenance costs which do not compensate their energy savings. The PV HPWH system has a greater reduction of emissions and a lower cost than HPWH across a 15-year life. The gas boiler system has the lowest cost in a 15-year period in the coldest areas, despite having a greater environmental impact than the heat pump.(c) 2023 Elsevier B.V. All rights reserved.

Network temperatures in district heating systems are important operational factors for obtaining efficient performance. A low network return temperature allows for the recovery of low-grade heat from assets such as condensing boilers, waste incineration, geothermal sources and industrial waste heat. Fluctuations in heating and cooling demands affect the return temperatures of the building substations and in the network. This variability impacts the economic viability and environmental sustainability of the entire system. This paper presents a nonlinear optimization strategy to maintain sufficient energy flows in the network's primary and secondary circuits to achieve low return temperatures from all substations in the network. The defined optimization strategy incorporates the thermodynamic model of the substation and building heating system as opposed to traditional weather-based supply temperature adjustments. The estimated heat demands and tariffs, CO2 penalties are inputs used by the optimizer to find theoptimal solution. The total operational expenditure for electricity and gas consumption shows an 18% reduction with 8% reduction in emissions and 6% efficiency improvement when compared with the measured weather-based approach. The developed strategy will aid the network operators in the economic dispatch of heat generation while ensuring the user's thermal comfort.

Abstract: To maximize the sustainable and economic benefits of collective heating systems, proper sizing is fundamental. This paper presents the validation of a novel sizing approach for collective systems producing and distributing heat for both space heating and domestic hot water, utilizing residential heat meter data. A validation methodology is developed to overcome the limitations of this type of data to identify the peak heat demand and estimate the peak heat demand under design outdoor conditions. The latter is estimated utilizing multiple linear regression coupled with an analysis of the maximum deviations. The power-storage characteristic, which shows all combinations of thermal power and thermal storage to meet the peak heat demand is determined and used to validate the novel sizing approach for six case studies. Although the results are promising, undersizing problems may arise in cases with decentralized heat storage

Abstract: To achieve net-zero emissions by 2050, as outlined in the European Green Deal, nuclear power is expected to double between 2020 and 2050, mainly due to its low-carbon baseload capacity. Small modular reactors, new nuclear reactors designed to generate up to 300 MW of electricity, could help achieve this goal. Small modular reactors have unique advantages over existing large reactors, such as modularization, learning and co-location economics. However, these small modular reactors should also be economically viable. This review therefore focuses on the costs of small modular reactors. This review found an average capital cost of €7,031/kW and an average levelized cost of electricity of 85 €/MWh for small modular reactors, while capital costs were found to be on average 41% higher than for the large reactors. Carbon and gas prices are not included in this cost estimate, yet these volatile prices also affect small modular reactor costs. However, as the absolute cost is lower, the financial risk is lower for small modular reactors. The importance of regulations, discount rates, country and project specifications and public acceptance are also considered.

Vacuum pressure swing adsorption (VPSA) has demonstrated promising features for the upgrading of biogas to biomethane. In this study, a biogas upgrading plant, comprised of a hybrid of an N-column VPSA unit (2 ≤N≤ 6) with a combined heat and power (CHP) engine, was developed and its techno-economic characteristics were assessed via a mathematical approach. Moreover, the techno economic analysis was used for the state-of-the-art VPSA configuration (a sophisticated configuration) and compared with the developed hybrid process. The prominent parameters including feedstock transport, biogas production, desulfurization, drying, upgrading, combustion, and grid injection were considered in the analyses of the plant for the upgrading capacity in the range of 100 - 6,500 Nm3/h. Sensitivity analysis of the most influencing parameters, i.e., electricity price, gas price, and feed processing revenues, was conducted for the developed models. Beside comparing upgrading cost of the sophisticated VPSA with other upgrading technologies, a detailed comparison with the best available membrane unit for biogas upgrading was conducted. The limitations of adsorption process and VPSA in reducing the upgrading cost were also investigated. The results showed that in the absence of subsidies and requirements for CO2 capture, the hybrid plant outperforms the sophisticated VPSA units. Also, higher market price of natural gas or feedstock processing revenues were necessary in order to render the plant profitable. The results showed that, at flowrates larger than 175 Nm3/h, the sophisticated VPSA unit required a lower investment cost than the membrane unit for identical outputs. The results also show that even at the most idealistic conditions in the adsorption process, the upgrading is not economically favorable without subsidies. The findings of this study shed light on the importance of process design for biogas upgrading.

Abstract: Second-generation biofuels, starting from lignocellulosic biomass, are considered as a renewable alternative for fossil fuels with lower environmental impact and potentially higher supply and energy security. The economic and environmental performance of second-generation bioethanol production from corn stover in the European Union (EU) is studied, starting in Belgium as base case. A comparative environmental techno-economic assessment has been conducted, with process simulations in Aspen Plus and corn stover availability data in thirteen EU countries to calculate minimum ethanol selling prices (MESP) and Greenhouse gas emissions (GHGe). In this analysis, the emphasis is on the comparison of different pretreatment technologies, namely (i) dilute acid, (ii) alkaline, (iii) steam explosion and (iv) liquid hot water. Dilute acid showed the best economic and environmental performance for the base case scenario. Within the EU, Hungary and Romania presented the lowest MESP for the steam explosion model at 0.39 and 0.43 EUR/L respectively. Poland showed the lowest GHGe, at 0.46 kg CO2eq/L for the alkaline model, mainly due to the avoided product allocation on electricity and its high carbon intensity in the electricity generation sector. The second lowest GHGe were obtained in France for the dilute acid model and are attributed to its low agricultural emissions intensity. This study identifies a location-dependence of the economic and environmental performance of pretreatment technologies, which can be extrapolated from the EU to other large regions around the world and should be taken into consideration by decision-makers.

Abstract The study presents recent developments in the Turkish power market and introduces an Analytic Hierarchy Process model to evaluate and compare the relative overall attractiveness of power plant options for Turkey. The developed model incorporates technical characteristics, resource availability, socio-economic, environmental, cost, political, legal and organisational aspects, for evaluating and prioritising power plant types (biomass, coal, geothermal, hydro, natural gas, nuclear, petroleum, solar and wind). The study incorporates perspectives of different experts that represent various stakeholders of the Turkish power sector. The study reveals that supply reliability, investment costs and contribution to national economy are perceived as most important factors, whereas waste disposal and decommissioning costs are perceived as least important factors. Considering the overall weights, the most attractive power plant types for the Turkish power market are coal, hydro and natural gas power plants. The study indicates that Turkey should drastically decrease the installed capacity share of traditionally dominant power plants (to 58% from 89% in 2016) and fossil fuel power plants (to 40% from 56% in 2016), and increase the share of renewable power plants (to 52% from 44% in 2016), indigenous resource based power plants (to 67% from 56% in 2016) and nuclear power plants.

Cement-based materials are widely used for stabilizing and conditioning radioactive waste in low- and intermediate-level repositories. In this study, the adequacy of four different types of mortars, obtained from four different commercial cements, CEM I, II and IV (A and B), to act as barrier to 137Cs migration was analysed. Diffusion experiments using the in-diffusion (ID) method with constant tracer concentration in the reservoirs were carried out, at increasing experimental times (150, 380 and 1500 days approximately). In the experiments of less duration, and especially in CEM II and CEM I, two different pathways for diffusion were identified (fast and slow), leading to a double porosity system. However, the ???fast??? contribution to Cs diffusion, in all cases, could be neglected at larger experimental time, indicating a rearrangement of the pore structure that becomes more tight and homogeneous over time. Thus, if the experiments last enough time, only one diffusion coefficient properly describe Cs transport in these systems. Apparent diffusion coefficients, Da, obtained for Cs, range between 6.0??10???13 and 1.0??10???14 m2/s. Mortars produced with CEM IV (A and B) are the most efficient barrier for cesium transport, amongst those analysed in this study. Mortars with CEM II, which contain blast furnace slag, present the highest diffusion coefficient.

Ammonia is a promising clean and sustainable energy carrier, yet challenges persist in achieving stable combustion, particularly concerning poor ignition quality and elevated NOx emissions. Recent research suggests that the Moderate or Intense Low-oxygen Dilution (MILD) regime could address these challenges for ammonia combustion. This study aims to optimize the MILD regime using non-equilibrium plasma discharges, specifically nanosecond repetitive pulsed discharges (NRPD). While the beneficial effects of NRPD on ammonia chemistry have been demonstrated in traditional applications, their impact under the highly diluted conditions characteristic of the MILD regime remains unexplored. This numerical study employs a detailed two-temperature model to investigate the effects of pulsed discharges in ammonia/air mixtures, simulating conditions representative of the MILD regime. The research comprehensively explores the selection of optimal discharge settings and examines plasma effects on various parameters, including ignition delay time, flammability limit, radical production, and emissions. Equivalence ratios ranging from 0.2 to 2 and dilution levels up to 2.5% O2 are considered in this investigation. Results indicate that NRPD show a notable benefit by enlarging fuel-lean and fuel-rich stability limits, promising enhanced operational flexibility. Examining OH radicals and NOx emissions underscored a consistent plasma-driven mechanism, reducing emissions, also in the MILD regime. Novelty and Significance Statement The novelty of this research is the application of non-equilibrium plasma discharges to improve ammonia combustion in the MILD regime. It offers a new and original solution to the challenges associated with the poor ignition quality and high NOx emissions that are currently limiting its practical implementation. For the first time, a numerical analysis is provided to quantify the benefits of plasma chemistry activation on the combustion performance. Another novel aspect of this work is the use of a detailed two-temperature model to describe the plasma-combustion interactions in an integrated computational framework. The literature reports only a few references on the interaction of plasma with MILD combustion conditions. The former were modeled using a very simplified model to describe the evolution of the plasma species. Consequently, we believe that this contribution will significantly advance the state-of-the-science in field of plasma-assisted ammonia combustion.