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A good process understanding is the foundation for process optimization, process monitoring, end-point detection, and estimation of the end-product quality. Performing good process measurements and the construction of process models will contribute to a better process understanding. To improve the process knowledge it is common to build process models. These models are often based on first principles such as kinetic rates or mass balances. These types of models are also known as hard or white models. White models are characterized by being generally applicable but often having only a reasonable fit to real process data. Other commonly used types of models are empirical or black-box models such as regression and neural nets. Black-box models are characterized by having a good data fit but they lack a chemically meaningful model interpretation. Alternative models are grey models, which are combinations of white models and black models. The aim of a grey model is to combine the advantages of both black-box models and white models. In a qualitative case study of monitoring industrial batches using near-infrared (NIR) spectroscopy, it is shown that grey models are a good tool for detecting batch-to-batch variations and an excellent tool for process diagnosis compared to common spectroscopic monitoring tools.

Plant-soil feedback (PSF) describes the process whereby plant species modify the soil environment, which subsequently impacts the growth of the same or another plant species. Our aim was to explore PSF by two maize varieties (a landrace and a hybrid variety) and three arbuscular mycorrhizal fungi (AMF) species (Funneliformis mosseae, Claroideoglomus etunicatum, Gigaspora margarita, and the mixture). We carried out a pot experiment with a conditioning and a feedback phase to determine PSF with different species of AMF and with a non-mycorrhizal control. Sterilized soil was conditioned separately by each variety, with or without AMF; in the feedback phase, each soil community was used to grow each in its "home" soil and in the "away" soil. Plant performance was assessed as shoot biomass, phosphorus (P) concentration and P content, and fungal performance was assessed as mycorrhizal colonization and hyphal length density. Both maize varieties were differentially influenced by AMF in the conditioning phase. In the feedback phase, PSF was generally negative for non-mycorrhizal plants or when plants were colonized by G. margarita, whereas PSF was positive in the other three AMF treatments. When plants were grown on home soil, hyphal length density was larger than on away soil. We conclude that different maize varieties can strengthen positive plant-soil feedback for themselves through beneficial mutualists for themselves, but not across the maize varieties.

Thermokinetics of Biochar production.

Treball final de Grau en Psicologia. Codi: PS1048. Curs acadèmic 2015-2016 El estresante estilo de vida de la sociedad actual junto con la mala concepción sobre las posibles consecuencias del consumo de alcohol podrían ser algunas de las causas de que actualmente el alcohol sea una de las drogas más consumidas a nivel mundial según la OMS. Sin embargo, a pesar de todos los avances de la neurociencia, el mecanismo exacto de cómo actúa el alcohol en el SNC nos es aún desconocido. El objetivo de este trabajo es tratar de plantear y dar pruebas a favor de una hipótesis sobre como podría actuar realmente el alcohol en el cerebro. El método de este trabajo consta del análisis de 4 estudios que muestran las manipulaciones de diferentes mediadores de calcio y AMPc-­‐PKA y las consecuencias de esas manipulaciones a nivel molecular, celular, neurobiológico y conductual. Por una parte los resultados obtenidos nos muestran que posiblemente, estos mediadores de calcio tengan una función muy importantes a la hora de explicar el mecanismo de acción del alcohol en el cerebro. Pero, no obstante, no son suficientes evidencias como para afirmar con completa claridad y certeza que este sea el mecanismo exacto de actuación del alcohol en el SNC. The stressfull way of life of our nowadays society in adition to the missconception of the potencial consequences from alcohol consum could be some of the reasons for why alcohol is the worldwide most consumed drug according to OMS. However, besides all the neuroscience developments, the true mechanism of alcohol functionament on the SNC has been not proved. The method of this paper consists of the analysis of 4 studies that show the manipulations of the different mediators of calcium and cAMP-­‐PKA and the consequences of these manipulations at a molecular, cellular, neurobiological and behavioural level. The results, in one hand, show that is possible that those mediators of calcium are important for understands the true mechanism of how alcohol works in the brain. However, there are no enough evidences to completely agree that this is the exact mechanism by which alcohol acts at a central level.

This paper deals with the medium between two reconfigurable sensor nodes characterized by radio interfaces that support multiple channels for exchanging real-time messages under energy constraints. These constraints are violated if the consumed energy in transmission is higher than the remaining quantity of energy. A reconfiguration, i.e., any addition or removal of tasks in devices and consequently of messages on the medium, can cause the violation of real-time or energy constraints at run time. To achieve a feasible scheduling in time (i.e., message deadlines will be respected) and energy (i.e., there is available energy) on the medium, we propose new dynamic solutions: Balance, Dilute, and a Combination of them to manage any addition or removal of messages. The proposed approach utilizes the energy harvesting techniques and the PowerControl algorithm to reduce the nonharvested consumed energy. The proposed strategies achieve significant improvement over existing methods and provide the highest percentage of adding messages, with a lower average in response time and energy consumption. They reach a percentage of success in adding the highest priority messages while meeting deadlines up to 85%.

Artículos en revistas Numerical models of transmission-constrained electricity markets are used to inform regulatory decisions. How robust are their results? Three research groups used the same data set for the northwest Europe power market as input for their models. Under competitive conditions, the results coincide, but in the Cournot case, the predicted prices differed significantly. The Cournot equilibria are highly sensitive to assumptions about market design (whether timing of generation and transmission decisions is sequential or integrated) and expectations of generators regarding how their decisions affect transmission prices and fringe generation. These sensitivities are qualitatively similar to those predicted by a simple two-node model. info:eu-repo/semantics/publishedVersion

Abstract The organic Rankine cycle (ORC) has been growing in importance as a technology for producing electricity from low temperature waste and renewable heat sources. In small-scale applications, the most used working fluid has been HFC-245fa, although this is being substituted for low GWP alternatives. A new HCFO working fluid, HCFO-1224yd(Z), has appeared as a possible alternative for HFC-245fa. In this study, this alternative working fluid is analysed and, finally, the working fluid is experimentally tested as drop-in alternative in a commercial ORC system. The main purpose is to determine the feasibility of using HCFO-1224yd(Z) as a drop-in replacement for HFC-245fa in a real facility that was initially designed to operate with HFC-245fa. The results show how the use of HCFO-1224yd(Z) offers power output that ranges from 7.5% to 17.4% lower than that provided by HFC-245fa. Although HFC-245fa offers higher power output, the results show that HCFO-1224yd(Z) offers up to 7.7% higher cycle net efficiency; this is due to the higher input thermal rate required by HFC-245fa. Finally, HCFO-1224yd(Z) has been stated as a suitable alternative to HFC-245fa as a drop-in replacement in a small-scale, low-temperature ORC, which increases its attractiveness for heat source with higher temperatures.