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This study highlights how Chinese economic development detrimentally impacted water quality in recent decades and how this has been improved by enormous investment in environmental remediation funded by the Chinese government. To our knowledge, this study is the first to describe the variability of surface water quality in inland waters in China, the affecting drivers behind the changes, and how the government-financed conservation actions have impacted water quality. Water quality was found to be poorest in the North and the Northeast China Plain where there is greater coverage of developed land (cities + cropland), a higher gross domestic product (GDP), and higher population density. There are significant positive relationships between the concentration of the annual mean chemical oxygen demand (COD) and the percentage of developed land use (cities + cropland), GDP, and population density in the individual watersheds (p < 0.001). During the past decade, following Chinese government-financed investments in environmental restoration and reforestation, the water quality of Chinese inland waters has improved markedly, which is particularly evident from the significant and exponentially decreasing GDP-normalized COD and ammonium (NH4+-N) concentrations. It is evident that the increasing GDP in China over the past decade did not occur at the continued expense of its inland water ecosystems. This offers hope for the future, also for other industrializing countries, that with appropriate environmental investments a high GDP can be reached and maintained, while simultaneously preserving inland aquatic ecosystems, particularly through management of sewage discharge.

The development of heat transfer fluids (HTF) and heat storage materials (HSM) is crucial to design concentrating solar plant (CSP). Binary alkaline nitrate mixtures are currently used as sensible thermal energy storage materials. However, multi-component nitrate/nitrite systems were proposed as possible better candidates. In particular, ternaries mixtures containing sodium, potassium, and calcium are extremely promising as thermal fluids, given their reduced toxicity and greater cost-effectiveness. Nevertheless, very few data are present in the scientific literature regarding the correspondent phase diagram, and only the properties of specific compositions are reported. For this reason, a regular solution model was developed and employed in this work, and validated by comparing the simulation results with experimentally obtained phase change values. In particular, given that the common calorimetric techniques are impracticable for detecting the transition temperatures of calcium containing nitrate mixtur...

Domestic heating represents the most dominant energy function in Dutch households nowadays. Using district heat from CHP (combined heat and power) by means of a NGCC (natural gas-fired combined cycle) plants is generally acknowledged as an effective option to reduce primary energy consumption for heating. However, methods to calculate energy savings from CHP differ widely. This paper compares a number of different methods, including the method from the EU CHP Directive, to estimate primary energy savings in comparison with the typically used domestic gas-fired condensing boiler. Real hourly CHP plant performance data is used. An estimation of the CO2 mitigation cost of delivering district heat to Dutch dwellings is made. We find that supplying dwellings with district heat from an NGCC-CHP saves energy, regardless of the calculation method and for a rather wide range of reference efficiencies. CO2 mitigation costs are acceptable from a social perspective (at discount rates up to 4%, excluding fuel taxes) and negative from a private perspective (at discount rates up to 10%, including fuel taxes).

About 25 million tons of food go wasted or lost in Iran which has socio-economic and environmental consequences for both the country and the households. The main objective of this research is to develop a model to examine the relationship between FCM components and the amount of FW of households in Tehran city, with a focus on urban women. By means of a structural model, this study provides a novel approach to exploring relationships between the food-related behavior of urban households and waste control (n = 1197). Besides, this study is the first attempt to quantify food waste in Iran at the household level. According to the adopted self-reporting procedure, in Tehran, every consumer wastes about 27.6 kg of edible food annually. It is found that households with better food consumption management (FCM (have a lower level of food waste. Moreover, the results have proved that other determinants such as demographic factors, economic power, information use, ability, and motivation have direct and indirect significant effects on FCM as well as on the amount of food waste generation. The findings suggest that the above-mentioned determinants are crucial and should be considered when developing a strategically sustainable food waste prevention plan.

It is widely known that fossil fuels are limited; consequently, the generation of new sources of energy in a clean and environmentally friendly manner is a research priority. Bioethanol appears to be one potential solution, especially second-generation production from renewable biomass.In order to use lignocellulosic feedstock to produce bioethanol, its polysaccharide components, cellulose and hemicellulose, must be hydrolysed into soluble sugars, which can then be converted into ethanol by fermentative microorganisms such as Geobacillus thermoglucosidasius TM242 used by the company ReBio Technologies Ltd.To date, the cost of commercial enzymes used during the hydrolysis process remains a major economic consideration in the production of second-generation bioethanol as an alternative fuel. The research project presented in this thesis aims to improve this rate-limiting step of microbial bioethanol production through an investigation of the different enzymes associated with hemicellulose hydrolysis. Firstly, the TM242 genome sequence revealed a number of genes encoding glycoside-hydrolases. Six of these genes were cloned and expressed in E. coli and the recombinant enzymes characterised; three of them, two β-xylosidases and an α arabinofuranosidase, are relevant to xylan hydrolysis, and were found to be highly active and thermostable. Crystallisation of one of the β-xylosidases permitted the determination of a high-resolution (1.7 Å) structure of the apo-enzyme along with a lower resolution (2.6 Å) structure of the enzyme-substrate complex, resulting in the first reported structure of a GH52 family member (Espina et al., 2014).Secondly, as the TM242 microorganism lacks xylanase enzymes, four genes encoding xylanases from closely-related Geobacillus strains were cloned and expressed in E. coli, with one of them being also successfully cloned and expressed in G. thermoglucosidasius TM242. This heterologous xylanase was secreted in active form representing an enhanced biomass utilisation by TM242.In conclusion, it is felt that the findings presented here have the potential to make a valuable contribution towards second-generation bioethanol production.

Urban environments provide opportunities for greater resource efficiency and the fostering of urban ecosystems. Brownfield areas are a typical example of underused land resources. Brownfield redevelopment projects that include green infrastructure allow for further ecosystems to be accommodated in urban environments. Green infrastructure also deliver important urban ecosystem services (UES) to local residents, which can greatly contribute to improving quality of life in cities. In this case study, we quantify and assess the economic value of five UES for a brownfield redevelopment project in Antwerp, Belgium. The assessment is carried out using the “Nature Value Explorer” modelling tool. The case includes three types of green infrastructure (green corridor,infiltration gullies and green roofs) primarily intended to connect nature reserves on the urban periphery and to avoid surface runoff. The green infrastructure also provides air filtration, climate regulation, carbon sequestration and recreation ecosystem services. The value of recreation far exceeds other values, including the value of avoided runoff. The case study raises crucial questions as to whether existing UES valuation approaches adequately account for the range of UES provided and whether such approaches can be improved to achieve more accurate and reliable value estimates in future analyses.

It is possible to distribute drinking water without a disinfectant residual when the treated water is biologically stable. The objective of this study was to determine the impact of easily and slowly biodegradable compounds on the biostability of the drinking water at three full-scale production plants which use the same surface water, and on the regrowth conditions in the related distribution systems. Easily biodegradable compounds in the drinking water were determined with AOC-P17/Nox during 2012-2015. Slowly biodegradable organic compounds measured as particulate and/or high-molecular organic carbon (PHMOC), were monitored at the inlet and after the different treatment stages of the three treatments during the same period. The results show that PHMOC (300-470 μg C L-1) was approximately 10% of the TOC in the surface water and was removed to 50-100 μg C L-1. The PHMOC in the water consisted of 40-60% of carbohydrates and 10% of proteins. A significant and strong positive correlation was observed for PHMOC concentrations and two recently introduced bioassay methods for slowly biodegradable compounds (AOC-A3 and biomass production potential, BPC14). Moreover, these three parameters in the biological active carbon effluent (BACF) of the three plants showed a positive correlation with regrowth in the drinking water distribution system, which was assessed with Aeromonas, heterotrophic plate counts, coliforms and large invertebrates. In contrast, the AOC-P17/Nox concentrations did not correlate with these regrowth parameters. We therefore conclude that slowly biodegradable compounds in the treated water from these treatment plants seem to have a greater impact on regrowth in the distribution system than easily biodegradable compounds.

Abstract Public attitudes anywhere in Europe show moderate to strong support for the implementation of renewable energy. Nevertheless, planning wind power developments appears to be a complicated matter in most countries. The problems that have to be dealt with during decision making processes on the siting of wind turbines are usually referred to as mere ‘communication problems’. However, public attitudes towards wind power are fundamentally different from attitudes towards wind farms. This ‘gap’ causes misunderstandings about the nature of public support for renewables. In particular where planners easily assume support for renewables can be generated by information campaigns emphasising the environmental benefits, whereas opposition to renewable energy schemes can be explained by a selfish ‘not in my backyard’ attitude. Both explanations used by planners, authorities and, unfortunately, by many scholars, are falsified. Furthermore, policies that still take this ‘common knowledge’ for granted can have negative consequences for the implementation rates of renewables. Visual evaluation of the impact of wind power on landscape values is by far the dominant factor in explaining why some are opposed to wind power and others are supporting it. Moreover, feelings about equity and fairness appear the determinants of ‘backyard’ motives, instead of selfishness.