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Abstract An alkaline earth boro-aluminosilicate glass (Eagle XG), a soda-lime glass, and a light-weight polyethylene-terephthalate (PET) foil, used as typical substrates for photovoltaics, were treated by an energetic proton beam (3 MeV, dose 106–107 Gy) corresponding to approx. 30 years of operation at low Earth orbit. Properties of the irradiated substrates were characterized by atomic force microscopy, optical absorption, optical diffuse reflectance, Raman spectroscopy, X-ray photoelectron spectroscopy, Fourier-transform infrared (FTIR) spectroscopy, and terahertz (THz) spectroscopy. Minimal changes of optical and morphological properties are detected on the bare Eagle XG glass, whereas the bare PET foil exhibits pronounced increase in optical absorption, generation of photoluminescence, as well as mechanical bending. On the other hand, the identical substrates coated with Indium-tin-oxide (ITO), which is a typical material for transparent electrodes in photovoltaics, exhibit significantly higher resistance to the modifications by protons while ITO structural and electronic properties remain unchanged. The experimental results are discussed considering a potential application of these materials for missions in space.

The Pannonian basin is an integral part of the convergence zone between the Eurasian and Nubian plates characterized by active subductions of oceanic and continental plates, and formation of backarc basins. The first part of this paper presents an overview of the evolution of the Alpine-Mediterranean region in order to understand the large scale crustal and upper mantle processes in and around the Pannonian basin, resulting a collage of terranes of Alpine and Adriatic origin. It will be followed by a summary of the history of sedimentation, volcanism and tectonic activity. As an illustration, three regional cross sections have been prepared on the base of seismic and borehole data. Reviewing current tectonic ideas and models, we come up with a speculative tectonic scenario depicting Alcapa and Tisza-Dacia as orogenic wedges detached from their mantle lithosphere in the Alpine and Adriatic/Dinaric collision zone during the Late Oligocene to Early Miocene. They suffered a dramatic thermal impact leading to crustal melting during extrusion, when these crustal flakes could have been directly superimposed on the asthenosphere in the Carpathian embayment. Since then, the large part of the Pannonian has been cooling and a new mantle lithosphere growing. Geothermal data show that the Pannonian basin with cessation of volcanic activity in the Late Miocene is still very hot and Miocene to Quaternary clastic basin fill, together with karstified Mesozoic carbonates form good geothermal reservoirs of regional extent. In addition to these gravity-driven aquifer systems, a strongly overpressured reservoir can be found below a regional pressure seal in synrift strata and fractured basement rocks. Eventually, we show maps of geothermal installations in the Pannonian basin and suggest that at the present level of knowledge and geophysical surveying it is easy to find additional resources, however proper water management is a critical issue to avoid harmful drawdown of the groundwater table.

In the present study, Tween 80, a non-ionic surfactant, has been used for enhanced hydrogen production by crude glycerol bioconversion using co-culture of Enterobacter aerogenes and Clostridium butyricum. The purpose of introducing the surfactant was to decrease the crude glycerol viscosity, so that apparent solubility and bioavailability of glycerol could be improved at the expenses of pretreatment steps. Experiments were planned using central composite design (CCD); crude glycerol and Tween 80 concentrations were optimized whereas, hydrogen production, glycerol utilization and viscosity of the media were considered as responses. The response surface for quadratic model showed, Tween 80 concentration had significant effect (p < 0.05) on all the three responses. Using the optimized conditions at 17.5 g/L crude glycerol and 15 mg/L Tween 80, hydrogen production reached a maximum of 32.1 ± 0.03 mmol/L of medium. The increase in hydrogen production was around 1.25-fold in presence of Tween 80 in comparison to its absence with 25.56 ± 0.91 mmol/L production. Selected optimum conditions were also validated against absence of crude glycerol (4.69 ± 0.76), with pretreated crude glycerol (20.06 ± 0.51) and across mono-culture system (15.43 ± 0.79 to 22.14 ± 0.94). Introduction of Tween 80 to the fermentation medium improved the glycerol utilization rate, resulting in increased hydrogen production and eliminated pretreatment steps.

The heterotrophic biomass has the capacity of utilizing substrate predominantly for growth or storage processes under steady-state conditions. In this study, the short-term variations in growth and storage kinetics of activated sludge under disturbed feeding conditions were analyzed using a multi-component biodegradation model. The variations in growth and storage kinetics were investigated with the aid of multi-response modeling and identifiability analysis. It was found that the heterotrophic biomass is able to increase its direct growth activity together with reducing the substrate storage capability under the availability of external substrate. Reducing the sludge age (SRT) from 10 to 2 days increased the maximum specific growth rate, μ (OHO,Max) from 3.9 to 7.0 day(-1), but did not considerably affected the maximum storage rate, k (Stor,OHO). The alteration of sludge age also elevated the half-saturation constant for growth (K (S,OHO)) from 5 to 25 mg COD/L. The increase in primary growth metabolism together with reduced storage rate was validated by model for two different sludge ages in the availability of external substrate. Aside from having a lower storage capability, the biomass had fast adaptation ability to direct growth process at low SRTs. The alteration of feed conditions was found to have different impacts on storage and growth kinetics. These results are significant and advance the field of activated sludge modeling under dynamic conditions by incorporation of short-term effects. Appropriate modifications including short-term effects in model structure may also reduce dynamic model recalibration efforts in the future.

Hydrogenated microcrystalline silicon (μc-Si:H) is an important material for high-efficiency multijunction solar cells. Due to its complex microstructural properties, it is difficult to describe the electronic behavior clearly. In this study, we measure opto-electronic properties including the mobility gap of μc-Si:H films in solar cells, as well as physical properties such as the crystalline fraction profile. The height distribution function of the ZnO substrates is obtained by AFM scans, which is used for optical simulation. All the parameters that we obtained from measurements were used as input parameters of a model in the ASA simulator. We obtained a good fit between measurements and simulations.

Thin-film epitaxial silicon solar cells are an attractive future alternative for bulk silicon solar cells incorporating many of the process advantages of the latter, but on a potentially cheap substrate. Several challenges have to be tackled before this potential can be successfully exploited on a large scale. This paper describes the points of interest and how IMEC aims to solve them. It presents a new step forward towards our final objective: the development of an industrial cell process based on screen-printing for >15% efficient epitaxial silicon solar cells on a low-cost substrate. Included in the discussion are the substrates onto which the epitaxial deposition is done and how work is progressing in several research institutes and universities on the topic of a high-throughput epitaxial reactor. The industrial screen-printing process sequence developed at IMEC for these epitaxial silicon solar cells is presented, with emphasis on plasma texturing and improvement of the quality of the epitaxial layer. Efficiencies between 12 and 13% are presented for large-area (98cm 2 ) epitaxial layers on highly doped UMG-Si, off-spec and reclaim material. Finally, the need for an internal reflection scheme is explained. A realistically achievable internal reflection at the epi/substrate interface of 70% will result in a calculated increase of 3 mA/cm 2 in short-circuit current. An interfacial stack of porous silicon layers (Bragg reflectors) is chosen as a promising candidate and the challenges facing its incorporation between the epitaxial layer and the substrate are presented. Experimental work on this topic is reported and concentrates on the extraction of the internal reflection at the epi/substrate interface from reflectance measurements. Initial results show an internal reflectance between 30 and 60% with a four-layer porous silicon stack. Resistance measurements for majority carrier flow through these porous silicon stacks are also included and show that no resistance increase is measurable for stacks up to four layers.

Abstract Past research on identifying potentially negative impacts of forest management activities has primarily focused on traditional forest operations. The increased use of forest biomass for energy in recent years, spurred predominantly by policy incentives for the reduction of fossil fuel use and greenhouse gas emissions, and by efforts from the forestry sector to diversify products and increase value from the forests, has again brought much attention to this issue. The implications of such practices continue to be controversially debated; predominantly the adverse impacts on soil productivity and biodiversity, and the climate change mitigation potential of forest bioenergy. Current decision making processes require comprehensive, differentiated assessments of the known and unknown factors and risk levels of potentially adverse environmental effects. This paper provides such an analysis and differentiates between the feedstock of harvesting residues, roundwood, and salvage wood. It concludes that the risks related to biomass for energy outtake are feedstock specific and vary in terms of scientific certainty. Short-term soil productivity risks are higher for residue removal. There is however little field evidence of negative long-term impacts of biomass removal on productivity in the scale predicted by modeling. Risks regarding an alteration of biodiversity are relatively equally distributed across the feedstocks. The risk of limited or absent short-term carbon benefits is highest for roundwood, but negligible for residues and salvage wood. Salvage operation impacts on soil productivity and biodiversity are a key knowledge gap. Future research should also focus on deriving regionally specific, quantitative thresholds for sustainable biomass removal.

A comprehensive experimental and modelling study on the acid-catalysed hydrolysis of the water hyacinth plant (Eichhornia crassipes) to optimise the yield of levulinic acid (LA) is reported (T=150-175 degrees CH2SO4 = 0.1-1M, water hyacinth intake=1-5wt%). At high acid concentrations (>0.5M), LA was the major organic acid whereas at low acid concentrations (<0.1M) and high initial intakes of water hyacinth, the formation of propionic acid instead of LA was favoured. The highest yield of LA was 53mol% (35wt%) based on the amount of C6-sugars in the water hyacinth (T=175 degrees CH2SO4 =1M , water hyacinth intake=1wt%). The LA yield as a function of the process conditions was modelled using a kinetic model originally developed for the acid-catalysed hydrolysis of cellulose and good agreement between the experimental and modelled data was obtained.

In ecological risk assessment, exposure is generally modelled assuming static conditions, herewith neglecting the potential role of emission, environmental and biomass dynamics in affecting bioavailable concentrations. In order to investigate the influence of such dynamics on predicted bioavailable concentrations, the spatially-resolved dynamic model "ChimERA fate" was developed, incorporating macrophyte and particulate/dissolved organic carbon (POC/DOC) dynamics into a water-sediment system. An evaluation against three case studies revealed a satisfying model performance. Illustrative simulations then highlighted the potential spatio-temporal variability of bioavailable concentrations after a pulsed emission of four chemicals in a system composed of a pond connected to its inflow and outflow streams. Changes in macrophyte biomass and POC/DOC levels caused exposure variations which were up to a factor of 4.5 in time and even more significant (several orders of magnitude) in space, especially for highly hydrophobic chemicals. ChimERA fate thus revealed to be a useful tool to investigate such variations and to identify those environmental and ecological conditions in which risk is expected to be highest.