• Energy Research
• 13. Climate action close
• NO close
• Energy Procedia close

AbstractA metal-organic framework, UiO-66, has been evaluated as adsorbent in a post-combustion vacuum swing adsorption (VSA) process. Equilibrium isotherms of the most relevant gases (CO2 and N2) as well as breakthrough curves measured using synthetic flue gas containing 15 mol% CO2 without and with 9 mol% water vapor are reported. Based on the breakthrough data, a six step one-column VSA cycle is designed and the effects of adsorption and CO2 rinse times used on the CO2 recovery and CO2 purity are examined. With the chosen process configuration and cycle design CO2 purities around 60% and CO2 recoveries up to 70% are achieved. 50 cycle adsorption-desorption experiments show that the cyclic CO2 capacity is reduced by approximately 25% in the presence of water vapor. No reduction in cyclic capacity is observed with increased cycle number; there is rather a slight increase in cyclic capacity with cycle number indicating that a cyclic steady state still not has been reached after 50 cycles.

AbstractDuring the last decades significant effort has been put into research on the social, economical, political and technical issues related to large scale deployment of Carbon Capture and Storage (CCS). A complete CCS cycle requires safe, reliable and cost efficient solutions for transmission of CO2 from the capturing facility to the location of permanent storage. The current initiative originates from DNV’s long engagement in developing standards and guidelines for offshore pipelines and an identified need to specifically address the technical challenges related to transmission of CO2 with associated contaminants. The guideline will be based on a comprehensive literature review and gathering of experience from existing (both onshore and offshore) CO2 pipeline operators. Available pipeline codes, standards, guidelines and regulations combined with the latest available research and technical developments is set as the point of departure for this guideline development. Issues related to pipeline design, commissioning and operation as well as re-qualification/conversion of existing pipelines for transmission of CO2 will be addressed. The guideline is being developed as a joint industry project and is scheduled for delivery by end of July 2009. After completion of the JIP, the guideline will be converted into a public available Recommended Practice (RP) by Det Norske Veritas (DNV). The guideline will give “how to?” answers for safe, reliable and cost-effective transmission of CO2 in pipelines. This paper addresses main technical issues one need to manage.

AbstractAn absorption and desorption rig has been in operation at Telemark University College since 2010. The purpose of the rig is to perform measurements of CO2 removal efficiency and heat consumption at different process conditions like temperatures, flows and CO2 concentrations in the gas and the liquid. 30 wt-% monoethanolamine (MEA) in water has been the most used solvent. In earlier work, the heat consumption has been indirectly measured by the electricity consumption for steam production. In this work new results from 2012 and 2013 are presented where the steam consumption has been measured directly by a vortex flow meter.

AbstractFor a commercial Carbon Capture and Storage (CCS) chain to be successful, it must satisfy a whole range of requirements: technical, economic, environmental, safety, and societal. A comprehensive, understandable and reproducible assessment of CCS projects is a complex task due to several reasons: wide range of actors and factors involved, substantial differences in the type and nature of both actors and factors, and numerous associated uncertainties. In this paper, a standardised methodology is described and illustrated on a few examples of relatively simple case studies. The proposed methodology provides means and tools for evaluation of several economic, environmental, and in the future also risk associated criteria and thereby enables selection of the most promising options for CCS. The methodology will also help to reduce the uncertainty by improving understanding of the most important dependencies and trends for the investigated key performance indicators as enlightened by the case studies examples. It could also help to design efficient incentives and measures to stimulate realization of CCS by identifying and evaluating the most important non-technical factors affecting the CCS chain viability.

AbstractThe focus of this study is the analysis of an integrated reforming combined cycle (IRCC) with natural gas as fuel input. This IRCC consisted of a hydrogen-fired gas turbine (GT) with a single-pressure steam bottoming cycle for power production. The reforming process section consisted of a pre-reformer and an air-blown auto thermal reformer (ATR) followed by water-gas shift reactors. The air to the ATR was discharged from the GT compressor and boosted up to system pressure by an air booster compressor. For the CO2 capture sub-system, a chemical absorption setup was modeled. The design case model was modeled in GT PRO by Thermoflow, and in Aspen Plus. The Aspen Plus simulations consisted of two separate models, one that included the reforming process and the water-gas shift reactors. In this model were also numerous heat exchangers including the whole pre-heating section. Air and CO2 compression was also incorporated into the model. As a separate flow sheet the chemical absorption process was modeled as a hot potassium carbonate process. The models were linked by Microsoft Excel. For the CO2 capture system the model was not directly linked to Excel but instead a simple separator model was included in the reforming flow sheet with inputs such as split ratios, temperatures, and pressures from the absorption model. Outputs from the potassium model also included pump work and reboiler duty. A main focal point of the study was off-design simulations. For these steady-state off-design simulations GT MASTER by Thermoflow in conjunction with Aspen Plus were used. Also, inputs such as heat exchanger areas, compressor design point, etc., were linked in from the Aspen Plus reforming design model. Results indicate a net plant efficiency of 43.2% with approximately a 2%-point drop for an 80% part load case. Another off-design simulation, at 60% load, was simulated with a net plant efficiency around 39%. The CO2 capture rate for all cases was about 86%, except for the reference case which had no CO2 capture.

AbstractAnalysis of geological storage of CO2 almost always involves some set of computational models that provide a mathematical descri iption of the problem. These models can have many purposes, but ultimate they should be able to answer practical questions about the system. These questions usual involve the spatial extent of the CO2 plume, the spatial extent of pressure perturbations, the spatial and temporal dynamics of leakage out of the injection formation, and the spatial and temporal evolution of different trapping mechanisms. Answers to these questions require models that apply to large spatial and temporal scales while including certain small-scale features like leakage pathways. Development of computationally efficient models that can span the appropriate scales may be achieved by analyzing the length and time scales associated with the important processes in the system, and incorporating those scales into a systematic model development. Such a procedure can be described as multiscale modelling. Beginning with the most complex models, a sequence of simplifying assumptions may be proposed, based in part on scaling arguments for the physical processes involved, to produce a sequenc of successively simpler models. Through this approach, the assumptions in all of the simplified models are made transparent, and the length and time scales appropriate for different models can be identified. In addition, by associating length and time scales to the questions being asked,models can be developed that are consistent with those scales and therefore are appropriate to answer the questions.

AbstractPreliminary hydrolysis and photolysis data are presented for a suite of nitramines and nitrosamines relevant to post combustion CO2 capture using monoethanolamine solvent. Two nitramines (DMNA and MEA-NO2) and the nitrosamine NDELA were resistant to hydrolytic degradation at pH 4, 7 and 9. The nitrosamine NPz was hydrolytically stable at pH 4 and 9, but exhibited ∼30% degradation at pH 7. Nitrosamines appear highly susceptible to photolytic degradation, while nitramines are photolytically stable. The data form part of an ongoing study investigating the fate of nitrosamines and nitramines in terrestrial and aquatic environments.

The Nordic countries constitute a natural location for the development and deployment of Bio-Energy with Carbon Capture and Storage (BECCS). Finland, Sweden and Denmark are world-leading with respect to heat and power generation from sustainable biomass. Norway is world-leading with respect to Carbon Capture and Storage (CCS). The Nordic countries also have ambitious targets for reductions of their CO2 emissions, host leading technology providers, and have large biomass potential per capita. System studies suggest that bioenergy could be the single largest energy carrier in the Nordic countries by 2050. Negative CO2 Emissions with Chemical Looping Combustion of Biomass is a multi-partner project with the goal to develop new technology that: i) enables CO2 capture and negative CO2 emissions at the lowest possible cost, ii) is able to produce power and steam for industrial and other applications, iii) utilizes Nordic expertise in fluidized bed technology and iv) has potential to achieve improved fuel utilization. The technology capable of achieving these goals is Chemical-Looping Combustion of biomass (Bio-CLC). The article presents the project and features some early results from its implementation.