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Abstract This study sought to quantify and characterize cassava waste as fuel. The wastes from three cultivars were collected to study and were divided into three distinct parts of the cassava plant: seed stem, thick stalks, and thin stalks. Physical and chemical analyzes were carried out to determine the elemental composition of the waste: volatile matter; fixed carbon; ash; moisture; lignin; cellulose; hemicellulose; ash composition and higher heating value were determined. We conducted a thermogravimetric analysis in oxidizing and inert atmospheres to study the behavior of the waste as fuel. The root productivity obtained ranged from 7.7 to 13.0 t ha−1 yr−1 on a dry basis (db), and the ratio between waste and roots varied from 0.36 to 0.91. The physical and chemical properties of cassava waste are analogous to those of woody biomass regarding the elemental composition, the higher heating value, and thermogravimetric analysis. Ash content varied from 2.5% to 3.5%, reaching around 6.0% in samples unwashed. Approximately 60% of the ashes are alkali oxides, especially P2O5, K2O, and CaO, which have low melting points. The alkali index calculated suggests that there is a strong tendency that the combustion process leads to ash fouling and the formation of ash deposits.

Abstract AP1000® Generation III+ reactor bases its safety concept on passive systems, differently from the previous Generation II reactors. This fact has led the approximations and methodologies previously used for modeling active safety systems to be reviewed and adapted to simulate the physics of passive systems. Diverse studies about the AP1000 containment have demonstrated the difficulty to correctly model the occurring phenomenology. In this paper, an integral AP1000 3D containment GOTHIC model is presented, including the Passive Containment Cooling System (PCCS). The model includes the compartments inside and outside the metallic containment liner that influence the thermal–hydraulic behavior. The model is tested against a Large Break Loss of Coolant Accident (LBLOCA) to assess its thermal–hydraulic performance, assuming a PCS tank malfunction, what is a conservative hypothesis. The pressure and temperature evolution predicted by the 3D containment model is analyzed and compared with a single node Lumped Parameters model, allowing to evaluate some preliminary benefits of 3D modeling for containment safety analysis. The 3D containment model allows to predict the thermal evolution in each containment compartment capturing the heterogeneity of this phenomenon, with higher resolution than the lumped parameters models traditionally used in this kind of analyses. It allows to observe the thermohydraulic conditions locally at any time during the transient.

This paper estimates the profit of the joint operation of a wind farm and a li-ion battery energy storage system (BESS) in the Iberian electricity market (MIBEL). The day-ahead and first intraday energy markets, and the tertiary regulation market are considered to optimize the joint operation of both assets. A rolling window combined with a non-linear optimization model are used to design the operation strategy. The BESS lifetime (as a function of the depth of discharge) is considered in the optimization problem, and different BESS capacities and initial state of charge values are tested to determine their approximate optimum values. The model and strategy designed were tested using real data from the MIBEL market and predicted data from Sotavento wind farm. The resulting incomes were compared to the BESS investments costs to determine, for a given capacity, when the project becomes viable.

Successive international commitments relating to energy and climatic change (embodied in the Kyoto Protocol) and the need to rationalise the sources of generated energy, have meant that renewable energies have started to gain a great deal of importance within the worldwide energy network. In the case of Wind Energy, and in terms of production, Spain is the second most important country at European level and the third most important country at global level. Spain holds these positions as a result of the establishment of a stable regulatory framework, better understanding of the resource and improved technology that have afforded considerable cost reduction in terms of initial investment, maintenance and exploitation. This article focuses on these circumstances in view of their relevance at international level, which is due to the highly feasible possibility of exporting Spain's experiences to other countries with guarantees of success.

Previous work carried out for the last eight years resulted in the proposal of a complete system of dimensionless groups in order to represent the performance of different kinematic Stirling engine configurations. When looking for experimental support for the proposed model, some differences between the performances of several prototypes were observed. In this paper an equation is introduced to be applied to all known kinematic engines and to their whole range of performance. The coefficients appearing in this equation can be computed from temperature and geometrical dimensionless ratios and from experimental measurements at the maximum indicated power operating point. The meaning of those coefficients is interpreted and their usefulness to provide an engine performance overview is shown. The quasi-static simulation and the characteristic Mach number at the maximum indicated power operating point appear to be interesting criteria in order to evaluate the performance of prototypes.

Abstract High power pseudocapacitors are extremely relevant to answer specific needs in the current energy transition arena and to implement an efficient renewable energy society. However, literature shows that are still open gaps concerning improvement of their energy density at high power, conversion efficiency, cost and cycle life. Electrodes based on active transition metal compounds, and in particular metal sulphides, evidence high potential to meet these objectives. This work discusses the dependence on the synthesis route of the charge storage mechanism of manganese sulphide-based materials and relates the pseudocapacitive response of these electrodes with their polycrystalline nature. Results reveal that a manganese oxy-sulphide mixture can achieve a high specific capacitance of 231 F.g−1 at 0.5 A/g in a 0.65 V active window. These values represent a 31.5 % increase compared to pure rambergite, γ-MnS, and 436 % compared to pure hausmannite Mn3O4 prepared under the same conditions. Moreover, the results show that manganese oxy-sulphide electrodes are characterized by good charge retention (73%), and superior long term capacity retention (above 86%) after 5000 cycles, evidencing potential for high power energy storage applications.

Artículos en revistas It is shown how a standard nonlinear programming approach can be applied to solve a sophisticated version of the static optimal mix problem in generation planning. The model presented includes technical minima of thermal capacity, detailed operating models of storage-hydro and pumped-hydro units, a realistic model of capital costs for hydro plants, operating reserve and minimum demand constraints, and capacity already in existence. The model formulation is in a format that can be directly handled by the well-known MINOS code and can be efficiently solved. The use of a general-purpose nonlinear optimization program results in a great flexibility, making it possible to modify the model formulation easily or to adapt it to the characteristics of a particular electric system. A realistic application to the Spanish generation system is presented info:eu-repo/semantics/publishedVersion

This paper explores how market and regulatory factors affect stakeholders' investments in smart grid projects in Europe. Distribution System Operators (DSOs), universities, and technology manufacturers are leading investors, with a cumulative 2286 M€ financed since 2002. Statistical tests were conducted on these groups' investments in smart grid projects in the EU-28, Norway, and Switzerland from 2008-2015, to evaluate the influence of the following factors on investment: the level of distribution sector concentration, the regulatory mechanism in place, and the existence of innovation stimulus mechanisms. The level of distribution sector concentration did not significantly influence investments by these three groups. Market-minded stakeholders, such as DSOs and technology manufacturers, invested more in countries that employed hybrid, incentive, or innovation-stimulus mechanisms; meanwhile, collaborative knowledge-seeking institutions, such as universities, were not swayed by these factors. Taking these findings into consideration will help policy makers design adequate incentives for stakeholders.

An ethanol-methyl- t-butyl ether (MTBE) fuel blend was used as a substitute for hydrated ethanol to improve the vehicle cold start and drivability characteristics during the warm-up period. The vehicle was tested in a cold box, reaching a lower ambient temperature limit of -6deg;C, which represents the most severe weather condition experienced in Brazil. Different concentrations of MTBE in ethanol were investigated. The results show satisfactory drivability characteristics for the tested conditions, comparable with those found in gasoline-fuelled vehicles, thus overcoming the existing cold start difficulties in production ethanol-fuelled vehicles.