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The Intergovernmental Panel on Climate Change (IPCC) report that to limit warming to 1.5 °C, Bioenergy with Carbon Capture and Storage (BECCS) is required. Integrated assessment models (IAMS) predict that a land area between the size of Argentina and Australia is required for bioenergy crops, a 3–7 time increase in the current bioenergy planting area globally. The authors pose the question of whether vertical farming (VF) technology can enable BECCS deployment, either via land sparing or supply. VF involves indoor controlled environment cultivation, and can increase productivity per unit land area by 5–10 times. VF is predominantly being used to grow small, high value leafy greens with rapid growth cycles. Capital expenditure, operational expenditure, and sustainability are challenges in current VF industries, and will affect the ability to utilise this technology for other crops. The authors argue that, whilst challenging, VF could help reach wider climate goals. Application of VF for bioenergy crops could be a game changer in delivering BECCS technologies and may reduce the land footprint required as well as the subsequent associated negative environmental impacts. VF bioenergy could allow us to cultivate the future demand for bioenergy for BECCS on the same, or less, land area than is currently used globally.

Production of biodiesel from yellow grease (waste cooking oil and waste animal fats) is fast emerging as a promising alternative to address the twin challenges before the biodiesel industry today-fluctuation in prices of vegetable oil and the food versus fuel debate. Yellow grease has a high percentage of free fatty acids (FFA) and proves to be an unsuitable feedstock for biodiesel production from commercially viable alkali-catalyzed production systems due to saponification problems.“Green” methodologies based on heterogeneous solid acid catalyzed reactions have the potential to simultaneously promote esterification and transesterification reactions of yellow grease to produce biodiesel without soap formation and offer easy catalyst separation without generation of toxic streams. This paper presents kinetic studies for the conversion of model yellow grease feeds to biodiesel using a heteropolyacid supported on alumina (HSiW/Al2O3) using a batch autoclave. Three model yellow grease feeds were prepared using canola oil with added FFA such as palmitic, oleic and linoleic acid. A pseudo homogeneous kinetic model for the parallel esterification and transesterification was developed. The rate constants and activation parameters for esterification and transesterification reactions for the model yellow grease feeds were determined. The rate constants for esterification are higher than the transesterification rate constants. The kinetic model was validated using the experimental biodiesel data obtained from processing a commercial yellow grease feed. The kinetic model could be used to design novel processes to convert various low-value waste oils, fats and non-food grade oils to sustainable biodiesel. Keywords: Yellow grease, Canola oil, Free fatty acids, Heteropolyacid, Kinetics for esterification and transesterification

Climate change, environmental degradation, and limited resources are motivations for sustainable forest management. Forests, the most abundant renewable resource on earth, used to make a wide variety of forest-based products for human consumption. To provide a scientific measure of a product’s sustainability and environmental performance, the life cycle assessment (LCA) method is used. This article provides a comprehensive review of environmental performances of forest-based products including traditional building products, emerging (mass-timber) building products and nanomaterials using attributional LCA. Across the supply chain, the product manufacturing life-cycle stage tends to have the largest environmental impacts. However, forest management activities and logistics tend to have the greatest economic impact. In addition, environmental trade-offs exist when regulating emissions as indicated by the latest traditional wood building product LCAs. Interpretation of these LCA results can guide new product development using biomaterials, future (mass) building systems and policy-making on mitigating climate change. Key challenges include handling of uncertainties in the supply chain and complex interactions of environment, material conversion, resource use for product production and quantifying the emissions released.

Abstract This article is a survey of the theoretical questions arising in the development of a convergence theory and error analysis of synthesis methods for solving neutron diffusion problems. For simplicity, we discuss convergence and the error analysis for spectral synthesis methods, in which the trial functions are functions solely of energy. The diffusion coefficient, the total and scattering cross-section data for the diffusion model are assumed spatially and energy dependent, and interior interfaces (i.e. spatial discontinuities in the diffusion coefficient and cross-section data) are present. The boundary conditions imposed are homogeneous Dirichlet conditions.

The Social-Ecological Systems (SES) framework serves as a valuable framework to explore and understand social and ecological interactions, and pathways in water governance. Yet, it lacks a robust understanding of change. We argue an analytical and methodological approach to engaging global changes in SES is critical to strengthening the scope and relevance of the SES framework. Relying on SES and resilience thinking, we propose an institutional and cognitive model of change that institutions and natural resources systems co-evolve to provide a dynamic understanding of SES that stands on three causal mechanisms: institutional complexity trap, rigidity trap, and learning processes. We illustrate how Data Cube technology could overcome current limitations and offer reliable avenues to test hypothesis about the dynamics of social-ecological systems and water security by offering to combine spatial and time data with no major technical requirements for users.

AbstractMembrane Technology and Research, Inc. has proposed a hybrid system combining amine scrubbing with membrane technology to reduce energy cost. Previous studies of CO2 absorption mainly focused on coal-fired flue gas with 12% CO2. However, in the hybrid process, the CO2 in the flue gas can be enriched to 20%. Natural gas turbines will have flue gas with as little as 3% CO2。 Based on the arrangement, the hybrid amine/membrane system provides a gas to the system that has double the CO2 concentration of normal flue gas, reduces the volume of gas sent to the capture unit, or reduces the removal requirements for the capture unit.The objective of this work is to minimize the total energy use of stripping concentrated piperazine (PZ) at rich loading when treating flue gas from 3 to 20% inlet CO2. The base-case stripping configuration is the advanced flash stripper with warm rich bypass and cold rich exchanger bypass. . This configuration includes two split cross-exchangers in series, a convective steam heater, a smaller stripper column, a low residence time flash tank, and stripping at high temperature to produce CO2 at 5 to 17bar. Rich loading in 5 and 8m PZ was varied from 0.37 to 0.43mol CO2/mol N. For each rich loading, lean loading was optimized to minimize the total equivalent work. The “Independence” model for PZ in Aspen Plus® was used to simulate the stripping performance.Because 5m PZ has a lower viscosity than 8m PZ, it can achieve a reduced approach temperature in the cross exchanger. The total energy performance for 5m PZ is practically the same as 8m PZ, even though the capacity of 5m PZ is lower. Significantly more energy is required to regenerate solvents with lower rich loading. As CO2 rich loading increases, the equivalent work requirement decreases for the same loading difference between rich and lean.Stripping data for 24 cases, including heat duty, equivalent work, CO2 output pressure, and optimal cold and warm rich bypass were used to build a correlation with CO2 rich and lean loading. The Second Law efficiency based on the ratio of stripping minimum work and total ideal work was introduced to make the most of stripping work. The Second Law efficiency has a maximum value at a specific CO2 loading.

The aim of this paper is to contribute to the establishment of a robust framework for the assessment of Sustainable Development Goals (SDGs) in businesses, using the construction industry as an example and with the primary focus on combating climate change (SDG 13). We provide a critical analysis of a selection of relatively widely used SDG impact assessment tools, combined with a case study from the construction industry to explore how a meaningful SDG assessment can be framed with linkages between SDG 13 and other related SDGs. Our analysis points towards the importance of framing SDG assessments in a way that discourages "Greenwashing". Any SDG assessment that relates to climate targets in line with the Paris Agreement should identify the processes and activities that can be expected to be particularly challenging in terms of their abatement. In our road construction work case, we identify four such hard-to-abate activities: 1) introducing biomass for renewable transportation fuels for use in construction equipment and heavy transport; 2) electrification of transport and industrial processes; 3) substitution as part of transitioning from fossil fuel use; and 4) applying carbon capture and storage technologies in the production of basic materials, such as cement and steel. The approach applied will avoid that businesses only focus on SDGs in situations where they are already performing well or can apply low-cost measures or that they only relate to the part of the supply chain that pertains to their own business (Scope 1 emissions). For an SDG assessment to provide basis for informed decisions regarding real change towards more sustainable and equitable corporate practices it should: (i) identify and include concrete measures to align with the terms of the Paris Agreement; (ii) include relevant value chains; and (iii) consider both the short-term and long-term effects of strategic choices.