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In industrialized countries, large amounts of mineral wastes are produced. They are re-used in various ways, particularly in road and earth constructions, substituting primary resources such as gravel. However, they may also contain pollutants, such as heavy metals, which may be leached to the groundwater. The toxic impacts of these emissions are so far often neglected within Life Cycle Assessments (LCA) of products or waste treatment services and thus, potentially large environmental impacts are currently missed. This study aims at closing this gap by assessing the ecotoxic impacts of heavy metal leaching from industrial mineral wastes in road and earth constructions. The flows of metals such as Sb, As, Pb, Cd, Cr, Cu, Mo, Ni, V and Zn originating from three typical constructions to the environment are quantified, their fate in the environment is assessed and potential ecotoxic effects evaluated. For our reference country, Germany, the industrial wastes that are applied as Granular Secondary Construction Material (GSCM) carry more than 45,000 t of diverse heavy metals per year. Depending on the material quality and construction type applied, up to 150 t of heavy metals may leach to the environment within the first 100 years after construction. Heavy metal retardation in subsoil can potentially reduce the fate to groundwater by up to 100%. One major challenge of integrating leaching from constructions into macro-scale LCA frameworks is the high variability in micro-scale technical and geographical factors, such as material qualities, construction types and soil types. In our work, we consider a broad range of parameter values in the modeling of leaching and fate. This allows distinguishing between the impacts of various road constructions, as well as sites with different soil properties. The findings of this study promote the quantitative consideration of environmental impacts of long-term leaching in Life Cycle Assessment, complementing site-specific risk assessment, for the design of waste management strategies, particularly in the construction sector.

Green energy technologies (GETs) are environmentally friendly in nature, making a promising contribution to attaining net-zero carbon goals. Although the Pakistani government has begun using GETs to minimize the adverse effects of carbon emissions, consumers' adoption rate is quite low. There are few studies examining consumers' desire to adopt GETs in the country. This study attempts to fill this research gap and also contributes by adding three novel factors to the theory of planned behavior (i.e., green energy technology awareness, openness to experience, and green energy technology discomfort) to comprehensively analyze the impact of various factors influencing consumers' desire to adopt GETs. For this purpose, the study establishes a systematic research framework. Data were collected from (n = 330) households in the five major cities (Peshawar, Abbottabad, Mardan, Mingora, and Swabi) of Khyber Pakhtunkhwa Province via an inclusive questionnaire survey. The formulated hypotheses are evaluated and scrutinized using structural equation modeling. The results reveal that environmental concern (β = 0.245), green energy technology awareness (β = 0.362), openness to experience (β = 0.256), and green energy technology benefits (β = 0.225) positively affect consumers' desire to adopt GETs. On the other hand, green energy technology costs (β = 0.325) and green energy technology discomfort (β = 0.395) have a negative effect on consumers' adoption of GETs. The research findings emphasize the importance of increasing recognition of GETs, reforming policy frameworks, and providing budget-friendly and user-friendly technologies. Research limitations and future research perspectives are also addressed.

Climate change and rising global temperatures pose significant challenges for natural resource management. While developed economies have made progress in addressing these issues, emerging economies are still striving to achieve carbon neutrality, sustainable resource use, and environmental sustainability. This research aims to identify the factors driving carbon emissions in emerging economies over the past three decades. The study establishes a long-run relationship among the factors under investigation by employing various panel diagnostic methods. Non-parametric approaches are used to account for the non-symmetric distribution of panel data. The findings reveal that natural resource components have asymmetric impacts on carbon emissions, with oil rents reducing emissions and mineral rents increasing them. Economic growth and agricultural value added are identified as significant contributors to carbon emissions in the region. On the other hand, renewable energy consumption plays a crucial role in achieving carbon neutrality targets. Gross capital formation exhibits a mixed influence on carbon emissions, being positive and significant in lower quantiles and significantly negative in upper quantiles. These estimates are robust and align with existing literature. The study recommends sustainable resource abstraction and utilization, renewable energy production and consumption improvements, and enhanced capital formation. By providing empirical evidence and policy recommendations, this research contributes to understanding the relationship between these factors and their impact on carbon emissions, facilitating effective strategies for sustainable development and environmental preservation. Xinyang Normal University

Humic-like substances (HULIS) account for a major redox-active fraction of biomass burning organic aerosols (BBOA). During atmospheric transport, fresh acidic BB-HULIS in droplets and humid aerosols are subject to neutralization and pH-modified aging process. In this study, solutions containing HULIS isolated from wood smoldering emissions were first adjusted with NaOH and NH3 to pH values in the range of 3.6-9.0 and then aged under oxic dark conditions. Evolution of HULIS oxidative potential (OP) and total peroxide content (equivalent H2O2 concentration, H2O2eq) were measured together with the changes in solution absorbance and chemical composition. Notable immediate responses such as peroxide generation, HULIS autoxidation, and an increase in OP and light absorption were observed under alkaline conditions. Initial H2O2eq, OP, and absorption increased exponentially with pH, regardless of the alkaline species added. Dark aging further oxidized the HULIS and led to pH-dependent toxic and chemical changes, exhibiting an alkaline-facilitated initial increase followed by a decrease of OP and H2O2eq. Although highly correlated with HULIS OP, the contributions of H2O2eq to OP are minor but increased both with solution pH and dark aging time. Alkalinity-assisted autoxidation of phenolic compounds and quinoids with concomitant formation of H2O2 and other alkalinity-favored peroxide oxidation reactions are proposed here for explaining the observed HULIS OP and chemical changes in the dark. Our findings suggest that alkaline neutralization of fresh BB-HULIS represents a previously overlooked peroxide source and pathway for modifying aerosol redox-activity and composition. Additionally, these findings imply that the lung fluid neutral environment can modify the OP and peroxide content of inhaled BB-HULIS. The results also suggest that common separation protocols of HULIS using base extraction methods should be treated with caution when evaluating and comparing their composition, absorption, and relative toxicity.

AbstractIn the wake of the growing threats to humanity from climate change, we analyzed the information and communications technology (ICT)/education—environmental nexus from three distinct blocs including BRICS, MINT, and the G7 economies between 1990 and 2020. Two models were examined to reach the study's objectives. The first model evaluates whether education and ICT are essential for environmental sustainability via potential reduction in carbon emission. On the other hand, the second model fills an existing gap in extant studies by examining the prospect of education and ICT in influencing citizens on the importance of transition to renewable energy usage. Driscoll and Kraay estimator was employed as a panacea tool for cross‐sectional dependence and slope homogeneity while the fixed effect approach provides sufficient robustness checks on the findings. While some outcomes vary per bloc, others are relatively similar across the three blocs. Education level in school enrollment perspectives shows a negative significant pollution reduction effect across the three blocs, while only the G7 bloc performed better from human capital perspectives. The combined sample bloc shows that ICT also significantly reduces carbon emission, however, an individual bloc analysis refutes this stance for the MINT bloc. Additionally, while renewable energy cushions emissions in all the blocs, rapid urbanization, shows a positive CO2 emission impact except in the G7 bloc. Last, ICT and education significantly boost renewable energy usage only in the G7. Hence, governments and stakeholders in the blocs should gravitate toward greater investments in quality education and greener ICT infrastructures for a sustainable environment.

Abstract Urban transformation is vital to global sustainable development as humans increasingly come to dwell in cities. Within cities, the mobility sector promises the highest potential of carbon emission reduction. The disruptive business innovation brought about by the advent of app-based smart-sharing systems is emancipating collaborative consumption of mobility at larger and deeper scales, ranging from car-pooling, expanded electric vehicle (EV) use to bike-sharing. Synchronizing the existing yet under-realized low-carbon transport modes in cities, such as public transport, with emerging and diversifying app-based sharing mobility business models, offers huge potential to transform urban mobility toward sustainability. Yet, the rapid business expansion and innovation of the sharing mobility companies have profoundly challenged existing socio-economic relationships, knowledge systems and physical infrastructures in cities. This study explores the synergy between the social-ecological innovation in the sharing economy and the sustainable development of urban systems, using empirical data from three business cases in the emerging sharing mobility sector – in modes of ride-sharing, EV-sharing and bike-sharing - of Shanghai, China. It indicates that there is a strong co-evolution mechanism between the transformation towards more sustainable city at the macro-level and the business ecosystem innovation towards greener and smarter transport at the meso-level. We argue that the two level transformations, triggered by the disruptive innovation of the sharing economy and led by urban transformation towards sustainability, mutually influence each other and re-enforce sustainable values and practices in the fast changing urban context and business innovations in Shanghai.

Abstract With drastic fossil fuel depletion and environmental deterioration concerns, a move towards a more sustainable bioenergy-based economy is essential. Lately, the application of microwave (MW) irradiation for waste processing has been attracting interest globally. MW-assisted heating possesses several advantages such as the provision of high microwave energy into dielectric materials with deeper penetration for internal heat generation, showing beneficial features in improving the heating rate and reducing the reaction time. Consequently, the most recent literature regarding the applications of MW-assisted heating for biomass pretreatment as well as biofuel and bioenergy production was reviewed and consolidated in this study. An impressive increase in the product yield and improvement of the product properties are reported, with the use of MW-assisted heating in several conversion routes to produce biofuels. Despite being a promising technology for biofuel production, some major fundamental data of MW-assisted heating have not been comprehensively identified. Therefore, the feasibility of this technology for large-scale implementation is still subpar. Understanding the interaction between the feedstock and the microwave electromagnetic field, and the optimization of several operational and mechanical parameters are the two main keystones that would propel the industrialization of MW heating in the near future. This provides key insights leading to increased feasibility and more advanced application of MW heating.