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Torrefaction is considered as a method for producing biofuels with improved characteristics compared to those of the “raw” biomass (higher calorific value, moisture resistance, better grindability). The torrefaction process is an endothermic process that is usually carried out in a gaseous atmosphere in the absence of oxygen. To reduce the required heat input, it is proposed to employ the oxidative torrefaction and conduct the process in a fluidized bed agitated with flue gases containing less than 6% oxygen. Preliminary studies of the oxidative torrefaction of sunflower husks, including thermogravimetric analysis of the treated material, have shown that the heat treatment time for the biomass should be at least 5 min. A fluidized bed is a reactor with ideal mixing of the treated material where uniform treatment of raw material particles cannot generally be attained. To overcome this disadvantage of the fluidization technique and achieve the required residence time for biomass in a fluidized bed during a continuous torrefaction process, it was proposed to equip a torrefaction reactor with a series of vertical baffles spaced at 50 mm. These baffles induce a loop-like flow of the processed biomass from the inlet to the outlet of the reactor. To investigate the residence time for husk particles in the reactor, a tracer, which was colored to husk particles' color with a water-soluble dye which did not change the weight and size of the particles, was injected into the bed of uncolored particles. Tracer samples were taken every 30 s at the outlet of the reactor and were analyzed using a special procedure to determine the fraction of colored particles in each sample. This enabled us to gauge the time during which the colored particles injected into the fluidized bed reached the point of their discharge from the bed. Studies performed in a “cold” model of the reactor showed that a series of vertical baffles in the bed can provide the required residence time for biomass in a reactor including commercial reactors. Plates can provide the necessary biomass residence time in the reactor.

Mining and mineral processing industry adversely affects ecosystems and communities in nearby areas, including high freshwater consumption and scarcity. That is why the emerging global trend is to use sea water in flotation to recover valuable minerals from finely disseminated base metals ores. Recent studies investigate sea water flotation of copper, molybdenum, nickel sulphides and pyrite, while flotation of sphalerite, the main valuable mineral for zinc production, remains uncovered. This paper examines the feasibility of sphalerite flotation by conventional collectors in artificial sea water using a bubble-particles technique and frothless flotation tests. Potassium isopropyl xanthate (PIPX) and sodium isopropyl dithiophosphate (SIDTP) were used as collectors, and copper sulphate was introduced as the activator, while zinc sulphate and sodium sulphide were used as depressants. We examined the most common size fractions of sphalerite: medium (−74 + 44 μm) and fines (−44 μm). The findings showed the feasibility of sphalerite flotation in artificial sea water. We also established correlations between the rate of bubble-particle attachment and the sphalerite flotation recovery resulting in the growth of flotation recovery with the increase of the bubble-particle attachment rate. The results can be used as guidelines in choosing flotation reagents for sphalerite flotation in sea water. Another practical application of the results is the potential for sustainable development of the industrial sector, ecosystems and societies due to the replacement of fresh water by sea water, although further technological and environmental studies are required.

Aviation is one of the most significant growth drivers not only for the transportation infrastructure, but also for country’s economy as it contributes to both industrial and social progress of society. The paper focuses on Sheremetyevo International Airport, one of the largest Russian airports and analyzes it in terms of short-term and long-term perspectives. Using real statistical data, the article presents the models for forecasting essential performance indicators of airports, namely, passenger traffic and revenue. By comparing quality characteristics, most suitable models were selected and checked for adequacy. Forecasts of the probable changes in the values of the performance indicators were made under the assumption of maintaining the previously formed development trend.

AbstractNowadays, researchers are focusing on the methods of using recycled industrial/agricultural wastes as raw materials, which are not only economically but also environmentally useful. In the recent years, many scholars have conducted research on the rational use of rice husks (RHs) and found that RHs are rich in inorganic/organic components and used in combination with the certain building materials to produce new green composite building materials. This paper studies the method of using RH processed products and the sodium silicate solution (liquid glass) made from RH ash to produce cheap wood substitute composite materials, which can be improved the insulation performance of the wall greatly. Obtained results are determined by comparing with the properties of standard polymer composite materials such as particleboards, chipboards, and medium‐density fiberboards (MDF). The significance of the work is pointing out by solving the problem of recycling large‐tonnage agricultural waste and reproduce products with the consumer's value.

The object of the study is the water supply and sanitation system of an industrial enterprise. Currently, many enterprises do not use the treated industrial waste water in the water supply cycle. Therefore, the use of treated wastewater is of practical importance. The scheme of thermal treatment of waste water for obtaining pure condensate by evaporation is proposed. The main results of the study are the technical solution for the development of the enterprise's wastewater treatment complex. Pure condensate is obtained in an instant boiling evaporator. The research method is based on the calculation of energy costs in wastewater treatment for different types of waste water. The results of the study allow us to determine the optimal set of energy equipment for obtaining pure condensate and its further use. The specific practical significance lies in the development of a technical solution that helps the treatment of wastewater and the reduction of emissions into the water basin.

The oil production and refining processes are directly dependent on historical and political processes. The world wars of the 20th century were catalysts for the transformation of oil as the main energy resource. The capacity of enterprises in the oil refining industry is important for the development of politics and economies of states because oil products are one of the most sought after goods. Addressing the problem of capacity development for oil resource processing at Russian refineries is a relevant topic to build an effective policy for the distribution of global oil resources. The purpose of this paper is to identify the distribution trends in oil resource refining capacities in Russia. The developed method allows us to determine the dynamics of refining capacities in all regions of the country, establish the contributions of refinery groups to regional and countrywide capacities, and identify trends in the capacity concentrations of refineries and regions. The timeline that was used for the research period is 2009–2019. The results of the study showed increases in processing capacity in all federal districts. By 2019, the Volga Federal District provided the largest annual contribution to the countrywide capacity. The Southern Federal District moved up from the fourth to second position. It was followed by the Siberian, Central, Northwestern, Far Eastern, and Ural Federal Districts. The trends in the distribution capacities across the country indicate the prospect for building additional refineries in the Asian part of Russia. Rosneft was the leader, while Gazprom retained the second position. Independent refiners took the third position in terms of total refinery capacity, with Lukoil in the fourth position. Furthermore, Surgut-NG, Tatneft, Mini refineries, and NOVATEK followed the top four positions. The changes in concentration ratios indicated the increased monopolization of the refinery market. A decisive contribution to this process was due to by Rosneft’s takeover of TNK-BP and Bashneft’s capacities. The changes in regional concentrations were influenced by the changes in processing capacities of the Volga Federal District.

Abstract Mitigating the effects of environmental deterioration requires a focus on not just CO2 emissions from energy consumption, but also environmental pollution from industry sectors. To reach this goal, recent studies have extended ecological footprint (EF) analysis to identify the ecological drivers of various key industry sectors. The role of the phosphorus (P) industry on the EF within the environmental Kuznets curve (EKC) framework for China is the emphasis of this study. Autoregressive distributive lag (ARDL) as well as the impulse response function and robustness analysis were used to consider a time from 1985 to 2018. The study verifies the EKC hypothesis for China in both the long and the short run, and indispensable determinants are proposed to be included to assure the model’s fitness and robustness when conducting EF analysis of industry sectors. Energy consumption–based carbon emissions have been verified as the dominant contributor to EF, but P use and urbanization have a significant lagged positive influence on EF in the short run. P exports, in particular, have been highlighted as a critical driver of the EF of China’s P industry. The conducted frequency domain causality test reinforced the above findings and demonstrated bidirectional causality at different frequencies. This work suggests that formulating plausible P export policies to alleviate the conflict between the output of China’s P industry and the environmental sustainability of this industry are necessary. In this context, “multidisciplinary, multidimensional, and practical solutions” are most desirable for sustainable P management.

Pharmaceutical and personal care products (PPCPs) are discharged into receiving water bodies mainly from sewage treatment plants. Due to the inefficient removal in conventional wastewater treatment facilities, PPCPs have become a major concern to aquatic ecosystems, water quality, and public health worldwide since they cause harmful effects on aquatic life and human even at low doses. Among the PPCPs, carbamazepine (CBZ) is one of the most commonly prescribed anticonvulsant drugs and consumed more than 1,000 tons per year. Due to its structural complexity, CBZ is known as recalcitrant compound highly stable during wastewater treatment. Consequently, it has become one of the most frequently detected pharmaceuticals in waste water, surface water, and even drinking water. In this study, Korean indigenous microalgae strains were tested as eco-friendly and cost-effective solutions for CBZ removal. Based on the preliminary biological CBZ degradation tests, Tetradesmus obliquus KNUA061 demonstrating the best CBZ removal rate was selected for further experiments. In order to increase strain KNUA061's CBZ removal efficiency, NaOCl, which is widely accepted in the water purification process, was used as an additional stimulus to induce stress conditions. At around 20 μg L−1 CBZ, addition of 1.0 mg NaOCl resulted in approximately 20% of removal rate increase without suppressing cells growth. Roughly 90% of CBZ remained its original form and the composition of the transformed secondary metabolites was less than 10% during the biodegradation process by the microalga. Based on the results of the antioxidant enzyme activities, degree of lipid oxidation, and amino acid contents, it was concluded that the redox-defence system in microalgal cells may have been activated by the NaOCl treatment. Biomass analysis results showed that higher heating value (HHV) of strain KNUA061 biomass was higher than those of lignocellulosic energy crops suggesting that it could be utilized as a possible renewable energy source. Even though its biodiesel properties were slightly below the international standards due to the high PUFA contents, the biodiesel produced from T. obliquus KNUA061 could be used as a blending resource for transportation fuels. It was also determined that the microalgal biomass has acceptable feasibility as a sustainable dietary supplement feedstock due to its high essential amino acid contents.