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Torrefaction is considered as a method for producing biofuels with improved characteristics compared to those of the “raw” biomass (higher calorific value, moisture resistance, better grindability). The torrefaction process is an endothermic process that is usually carried out in a gaseous atmosphere in the absence of oxygen. To reduce the required heat input, it is proposed to employ the oxidative torrefaction and conduct the process in a fluidized bed agitated with flue gases containing less than 6% oxygen. Preliminary studies of the oxidative torrefaction of sunflower husks, including thermogravimetric analysis of the treated material, have shown that the heat treatment time for the biomass should be at least 5 min. A fluidized bed is a reactor with ideal mixing of the treated material where uniform treatment of raw material particles cannot generally be attained. To overcome this disadvantage of the fluidization technique and achieve the required residence time for biomass in a fluidized bed during a continuous torrefaction process, it was proposed to equip a torrefaction reactor with a series of vertical baffles spaced at 50 mm. These baffles induce a loop-like flow of the processed biomass from the inlet to the outlet of the reactor. To investigate the residence time for husk particles in the reactor, a tracer, which was colored to husk particles' color with a water-soluble dye which did not change the weight and size of the particles, was injected into the bed of uncolored particles. Tracer samples were taken every 30 s at the outlet of the reactor and were analyzed using a special procedure to determine the fraction of colored particles in each sample. This enabled us to gauge the time during which the colored particles injected into the fluidized bed reached the point of their discharge from the bed. Studies performed in a “cold” model of the reactor showed that a series of vertical baffles in the bed can provide the required residence time for biomass in a reactor including commercial reactors. Plates can provide the necessary biomass residence time in the reactor.

The territorial approach is the basic approach to a region management. At the same time, the “territory” component is the basis of the logistics complex used in Supply Chain Management. In this regard, a need is to clarify and supplement the theory and methodology of the territorial approach to the management of both the region and the supply chains.The subject of this study is the relationship between the regional authorities and the focus enterprise of the supply chain regarding the development of the territories and resources of the region on a mutually beneficial basis.The research methods are methods of analysis and synthesis, induction and deduction, as well as classification, and the tools are binary matrices that provide for the joint use of two classification attributes of the object under study and their dichotomies.The results of this study are the management principles by the competitiveness and sustainability of the management object; classifications of approaches to the management by the region and supply chains; of territories from the point of view of the focus enterprise of the supply chain and the region; the management decisions in the interaction of regions with the links of supply chains; the sequence of the formation of supply chains and the development of territories and resources of the region on the basis of the territorial approach and the relationship between them.The obtained results allow to reduce the costs and time for the development of territories and resources of the region by reducing the lost profits of the supply chain links due to their rational placement and increasing sustainability by achieving a synergistic effect both by the region and by the supply chains.

Abstract An ideal tracker which follows the sun both north-south and east-west is designed and constructed. It is suitable for mounting a linear concentrator, focusing parabolic concentrator or photovoltaic array of aperture area 2 m2. The apparatus is built with two axes equational mount and controlled by a microprocessor system. The tracking is carried out by utilizing the astronomical coordinates of the sun. As such the present system gives improved tracking capability over the conventional sensor controlled tracker systems. The performance of the tracking system was studied with photovoltaic array mounted on it and tracking error of less than one degree was achieved. This tracking error can be reduced further by proper software.

The formation and decay of excited states of light‐harvesting bacteriochlorophyll (BChl) molecules and primary charge separation in reaction centres (RCs) of pigment‐protein complex B890 of the purple bacterium Chromatium minutissimum were studied as a function of excitation wavelength by means of picosecond absorbance difference spectroscopy. Selective excitation in the RC absorption band (at 800 nm) induced rapid bleaching of the absorption band of the RC BChl dimer (τ ∼ 1 ps) without absorption changes due to excited light‐harvesting BChl. It is concluded that excitation energy transfer from the BChl dimer of the RC to light‐harvesting BChl molecules is considerably slower than RC charge separation. Therefore, energy transfer from the light‐harvesting antenna to the RC in bacterial photosynthesis may be described as a ‘migration‐limited model’.

Mining and mineral processing industry adversely affects ecosystems and communities in nearby areas, including high freshwater consumption and scarcity. That is why the emerging global trend is to use sea water in flotation to recover valuable minerals from finely disseminated base metals ores. Recent studies investigate sea water flotation of copper, molybdenum, nickel sulphides and pyrite, while flotation of sphalerite, the main valuable mineral for zinc production, remains uncovered. This paper examines the feasibility of sphalerite flotation by conventional collectors in artificial sea water using a bubble-particles technique and frothless flotation tests. Potassium isopropyl xanthate (PIPX) and sodium isopropyl dithiophosphate (SIDTP) were used as collectors, and copper sulphate was introduced as the activator, while zinc sulphate and sodium sulphide were used as depressants. We examined the most common size fractions of sphalerite: medium (−74 + 44 μm) and fines (−44 μm). The findings showed the feasibility of sphalerite flotation in artificial sea water. We also established correlations between the rate of bubble-particle attachment and the sphalerite flotation recovery resulting in the growth of flotation recovery with the increase of the bubble-particle attachment rate. The results can be used as guidelines in choosing flotation reagents for sphalerite flotation in sea water. Another practical application of the results is the potential for sustainable development of the industrial sector, ecosystems and societies due to the replacement of fresh water by sea water, although further technological and environmental studies are required.

We investigate the effect of slowly-varying parameter on the energy transfer in a system of weakly coupled nonlinear oscillators, with special attention to a mathematical analogy between the classical energy transfer and quantum transitions. For definiteness, we consider a system of two weakly coupled oscillators with cubic nonlinearity, in which the oscillator with constant parameters is excited by an initial impulse, while a coupled oscillator with slowly-varying parameters is initially at rest. It is proved that the equations of the slow passage through resonance in this system are identical to equations of the nonlinear Landau-Zener (LZ) tunneling. Three types of dynamical behavior are distinguished, namely, quasi-linear, moderately nonlinear and strongly nonlinear. The quasi-linear systems exhibit a gradual energy transfer from the excited to the attached oscillator, while the moderately nonlinear systems are characterized by an abrupt transition from the energy localization on the excited oscillator to the localization on the attached oscillator. In the strongly nonlinear systems, the transition from the energy localization to strong energy exchange between the oscillators is revealed. A special case of the rapid irreversible energy transfer in the strongly nonlinear system with slowly-varying parameters is also investigated. The conditions providing different types of the dynamical behavior are derived. Explicit approximate solutions describing the transient processes in moderately and strongly nonlinear systems are suggested. Correctness of the constructed approximations is confirmed by numerical results.

The Internet of Things (IoT) provides opportunities to control interconnected smart devices via pre-designed scenarios with littleor no human involvement. Due to the need for systematic improvement of industrial energy efficiency, the relevance of IoT-based energy management systems (EMS) is constantly increasing. Industrial IoT (IIoT)-enhanced EMS are created to support the digital transformation of enterprises. They increase the transparency of energy consumption statistics, enhance the personnel awareness of energy losses, provide predictive analytics tools for forecasting potential industrial accidents and future energy demand. This paper hence provides a system architecture of the energy management assistant that can be used at enterprises to archive the aforementioned aims. Authors identify the relevance of EMS, list the conditions at modern enterprises that define the requirements for the energy management assistant, demonstrate the identified requirements in the UML diagrams. Specification of energy planning and energy monitoring stages demonstrate the possibilities of the designed system architecture. For demonstration purposes, authors present examples of linear and nonlinear regression models implemented to specify energy consumption target functions based on real data. Finally, future research directions and open energy management problems are presented. The analysis has been carried out within the priority area of scientific development established in the National Research University Higher School of Economics - "Research on control methods in Cyber-Physical Systems".

Both electrical and thermal efficiencies combine in determining and evaluating the performance of a PV/T collector. In this study, two PV/T systems consisting of poly and monocrystalline PV panels were used, which are connected from the bottom by a heat exchanger consisting of a spiral tube through which a nanofluid circulates. In this study, a base fluid, water, and ethylene glycol were used, and iron oxide nanoparticles (nano-Fe2O3) were used as an additive. The mixing was carried out according to the highest specifications adopted by the researchers, and the thermophysical properties of the fluid were carefully examined. The prepared nanofluid properties showed a limited effect of the nanoparticles on the density and viscosity of the resulting fluid. As for the thermal conductivity, it increased by increasing the mass fraction added to reach 140% for the case of adding 2% of nano-Fe2O3. The results of the zeta voltage test showed that the supplied suspensions had high stability. When a mass fraction of 0.5% nano-Fe2O3 was added the zeta potential was 68 mV, while for the case of 2%, it reached 49 mV. Performance tests showed a significant increase in the efficiencies with increased mass flow rate. It was found when analyzing the performance of the two systems for nanofluid flow rates from 0.08 to 0.17 kg/s that there are slight differences between the monocrystalline, and polycrystalline systems operating in the spiral type of exchanger. As for the case of using monocrystalline PV the electrical, thermal, and total PV/T efficiencies with 2% added Fe2O3 ranged between 10% to 13.3%, 43–59%, and 59 to 72%, respectively, compared to a standalone PV system. In the case of using polycrystalline PV, the electrical, thermal, and total PV/T efficiencies ranged from 11% to 13.75%, 40.3% to 63%, and 55.5% to 77.65%, respectively, compared to the standalone PV system. It was found that the PV/T electrical exergy was between 45, and 64 W with thermal exergy ranged from 40 to 166 W, and total exergy from 85 to 280 W, in the case of using a monocrystalline panel. In the case of using polycrystalline, the PV/T electrical, thermal, and total exergy were between 45 and 66 W, 42–172 W, and 85–238 W, respectively. The results showed that both types of PV panels can be used in the harsh weather conditions of the city of Baghdad with acceptable, and efficient productivity.