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Renewable energy has become more popular since it is cost-effective and more efficient than conventional energy sources. Biomass-based renewable energy is primarily used in emerging economies to ensure environmental sustainability. This study examines the asymmetric correlation between biomass energy consumption and CO2 emissions in the top-10 biomass energy consumer countries (Brazil, Canada, Thailand, China, Italy, India, Germany, USA, UK, and Japan). A new approach "Quantile-onQuantile (QQ)" is employed by utilizing the data from 1991 to 2018. Biomass energy consumption, with the exception of Thailand, significantly mitigates CO2 emissions at various quantiles in selected countries. As a robustness check, we used the quantile regression test, whose findings are consistent with the outcomes from the quantile-on-quantile method. However, the degree of asymmetry in the biomass energy-CO2 nexus varies by country, necessitating extra attention and government vigilance when developing biomass energy and environmental policies.

Cette étude examine les caractéristiques des profils de vitesse, de champ thermique et d'entropie pour l'écoulement de nanofluides hybrides traversant une feuille d'amidonnage avec un rayonnement thermique. Les nanotubes de carbone (SWCNT et MWCNT) sont utilisés comme nanoparticules avec flux de chaleur Cattaneo-Christov (CC). L'éthylène glycol est utilisé comme fluide de base dans ce cas. Pour obtenir une solution améliorée, l'écoulement de fluide sur les propriétés géométriques est conçu en utilisant des PDE hautement non linéaires, et les équations gouvernantes doivent être converties en systèmes d'équations non similaires sans dimension en utilisant le schéma de Keller-box bien connu et très efficace dans le logiciel de calcul Matlab. La faisabilité pratique de ces solutions est déterminée par la plage des paramètres de contrôle. La distribution de vitesse diminue à mesure que l'estimation des paramètres magnétiques augmente, cependant, le champ de température et la production d'entropie augmentent à mesure que la fluctuation des paramètres magnétiques diminue. Au fur et à mesure que le paramètre de glissement augmente, le champ de vitesse diminue. Le champ thermique est amélioré pour augmenter le paramètre de rayonnement, et le profil d'entropie est renforcé pour augmenter les valeurs des paramètres de Brinkman. Les résultats de cette recherche pourraient avoir un impact significatif sur les industries où le refroidissement et le chauffage locaux par jets d'impact sont nécessaires dans les appareils électroniques, les dissipateurs thermiques, les technologies de séchage, etc. À la connaissance des auteurs, il s'agit du premier effort visant à utiliser un nanofluide hybride pour analyser la formation d'entropie due au flux magnétohydrodynamique sur une feuille d'amidonnage. Este estudio examina las características de los perfiles de velocidad, campo térmico y entropía para el flujo híbrido de nanofluidos que pasa a través de una lámina de almidón con radiación térmica. Los nanotubos de carbono (SWCNT y MWCNT) se utilizan como nanopartículas con flujo de calor Cattaneo-Christov (CC). El etilenglicol se utiliza como fluido base en este caso. Para lograr una solución mejorada, el flujo de fluido sobre las propiedades geométricas se diseña utilizando PDE altamente no lineales, y las ecuaciones gobernantes deben convertirse en sistemas de ecuaciones no similares adimensionales utilizando el conocido esquema de Keller-box altamente eficiente en el software computacional MATLAB. La viabilidad práctica de estas soluciones está determinada por el rango de los parámetros de control. La distribución de velocidad se reduce a medida que aumenta la estimación del parámetro magnético, sin embargo, el campo de temperatura y la producción de entropía aumentan a medida que la fluctuación del parámetro magnético se aclara. A medida que aumenta el parámetro de deslizamiento, el campo de velocidad disminuye. El campo térmico se mejora para aumentar el parámetro de radiación, y el perfil de entropía se aumenta para aumentar los valores de los parámetros de Brinkman. Los hallazgos de esta investigación podrían tener un impacto significativo en las industrias donde se necesita refrigeración local y calefacción a través de chorros de choque en dispositivos electrónicos, disipadores de calor, tecnologías de secado, etc. Según el conocimiento de los autores, este es el primer esfuerzo para emplear un nanofluido híbrido para analizar la formación de entropía debido al flujo magnetohidrodinámico sobre una lámina de almidón. This study examines the characteristics of the velocity, thermal field and entropy profiles for hybrid nanofluid flow passing through a starching sheet with thermal radiation. The carbon nanotube (SWCNT and MWCNT) are used as a nanoparticles with Cattaneo-Christov (CC) heat flux. Ethylene glycol is utilized as a base fluid in this case. To achieve an improved solution, the fluid flow over the geometric properties is designed using highly non-linear PDEs, and the governing equations must be converted into dimensionless non-similar equation systems using the highly efficient well-known Keller-box scheme in computational software MATLAB. The practical feasibility of these solutions is determined by the range of the controlling parameters. The velocity distribution reduces as the magnetic parameter estimate increases, however, the temperature field and entropy production increase as the magnetic parameter fluctuation esclates. As the slip parameter is increased, the velocity field diminish. The thermal field is enhanced for rising the radiation parameter, and the entropy profile is boosted for increasing Brinkman parameter values. The findings of this research might have a significant impact on industries where local cooling and heating via impingement jets are needed in electronic devices, heat sinks, drying technologies, and so on. To the best of the authors' knowledge, this is the first effort to employ a hybrid nanofluid to analyze entropy formation due to magnetohydrodynamics flow over a starching sheet. تبحث هذه الدراسة في خصائص ملامح السرعة والحقل الحراري والانتروبيا لتدفق السوائل النانوية الهجينة التي تمر عبر ورقة النشا مع الإشعاع الحراري. يتم استخدام الأنبوب النانوي الكربوني (SWCNT و MWCNT) كجسيمات نانوية مع تدفق حراري Cattaneo - Christov (CC). يستخدم جلايكول الإيثيلين كسائل أساسي في هذه الحالة. لتحقيق حل محسّن، تم تصميم تدفق المائع عبر الخصائص الهندسية باستخدام PDEs غير خطية للغاية، ويجب تحويل المعادلات الحاكمة إلى أنظمة معادلات غير متشابهة بلا أبعاد باستخدام مخطط Keller - box المعروف عالي الكفاءة في البرنامج الحاسوبي MATLAB. يتم تحديد الجدوى العملية لهذه الحلول من خلال نطاق معلمات التحكم. ينخفض توزيع السرعة مع زيادة تقدير المعلمة المغناطيسية، ومع ذلك، يزداد مجال درجة الحرارة وإنتاج الإنتروبيا مع تذبذب المعلمة المغناطيسية. مع زيادة معامل الانزلاق، يتناقص مجال السرعة. يتم تعزيز المجال الحراري لرفع معلمة الإشعاع، ويتم تعزيز ملف تعريف الإنتروبيا لزيادة قيم معلمة برينكمان. قد يكون لنتائج هذا البحث تأثير كبير على الصناعات التي تحتاج إلى التبريد والتدفئة المحليين عبر نفاثات الاصطدام في الأجهزة الإلكترونية وأحواض الحرارة وتقنيات التجفيف وما إلى ذلك. على حد علم المؤلفين، هذا هو أول جهد لتوظيف مائع نانوي هجين لتحليل تكوين الإنتروبيا بسبب تدفق الديناميكا المائية المغناطيسية على ورقة النشا.

Abstract The impact of a twisted turbulator in a parabolic solar collector on the improvement of thermal–hydraulic performance (THP), as well as energy and exergy Efficiency of MgO-Cu/water hybrid nanofluid (HNF) is numerically evaluated. The main goal of this study is to use a twisted turbulator with pitch ratios (γ) of 1, 1.5, 2, and 2.5 for Reynolds numbers (Re) of 8000 to 32,000 and volume fractions (ϕ) of 1, 2, and 3% of MgO and Cu nanoparticles. Numerical simulation findings are reported in the form of graphs of average Nusselt number (Nuave), pressure drop (Δp), THP, energy Efficiency ( η c ) , and exergy Efficiency ( η ex ) . It can be concluded that Nuave and Δp depends on ϕ and Re and augments linearly with their values. Moreover, Nuave and Δp increases significantly by increasing the pitch ratio of the turbulator. The results revealed that the maximum values of augmentation of η c and η ex are respectively 23.79% and 21.15% by raising Re from 8000 to 32000. In a SC with a turbulator with γ = 2 and ϕ = 3%, η c is raised by 24.16% by increasing Re from 8000 to 32000; while, in the case of γ = 2.5 and ϕ = 3%, η c is enhanced by 18.2%.

The impact of heavy metal, i.e., cadmium (Cd), on the growth, photosynthetic pigments, gas exchange characteristics, oxidative stress biomarkers, and antioxidants machinery (enzymatic and non-enzymatic antioxidants), ions uptake, organic acids exudation, and ultra-structure of membranous bounded organelles of two rice (Oryza sativa L.) genotypes (Shan 63 and Lu 9803) were investigated with and without the exogenous application of ferrous sulfate (FeSO4). Two O. sativa genotypes were grown under different levels of CdCl2 [0 (no Cd), 50 and 100 µM] and then treated with exogenously supplemented ferrous sulfate (FeSO4) [0 (no Fe), 50 and 100 µM] for 21 days. The results revealed that Cd stress significantly (p < 0.05) affected plant growth and biomass, photosynthetic pigments, gas exchange characteristics, affected antioxidant machinery, sugar contents, and ions uptake/accumulation, and destroy the ultra-structure of many membranous bounded organelles. The findings also showed that Cd toxicity induces oxidative stress biomarkers, i.e., malondialdehyde (MDA) contents, hydrogen peroxide (H2O2) initiation, and electrolyte leakage (%), which was also manifested by increasing the enzymatic antioxidants, i.e., superoxidase dismutase (SOD), peroxidase (POD), catalase (CAT) and ascorbate peroxidase (APX) and non-enzymatic antioxidant compounds (phenolics, flavonoids, ascorbic acid, and anthocyanin) and organic acids exudation pattern in both O. sativa genotypes. At the same time, the results also elucidated that the O. sativa genotypes Lu 9803 are more tolerant to Cd stress than Shan 63. Although, results also illustrated that the exogenous application of ferrous sulfate (FeSO4) also decreased Cd toxicity in both O. sativa genotypes by increasing antioxidant capacity and thus improved the plant growth and biomass, photosynthetic pigments, gas exchange characteristics, and decrease oxidative stress in the roots and shoots of O. sativa genotypes. Here, we conclude that the exogenous supplementation of FeSO4 under short-term exposure of Cd stress significantly improved plant growth and biomass, photosynthetic pigments, gas exchange characteristics, regulate antioxidant defense system, and essential nutrients uptake and maintained the ultra-structure of membranous bounded organelles in O. sativa genotypes.

Abstract Hydrogen is considered a potential game changer for world energy systems and a solution to climate change concerns, as it generates zero waste and it is suited for power generation and transportation. Despite its several advantages, there are significant technical challenges in deploying a stable hydrogen economy including improving its process efficiencies, lowering production costs, maintaining cost-effective transmission and distribution, and exploiting inexpensive and sustainable feedstocks. In this context, a detailed study was conducted to analyze the production sources, technologies, storage and transport systems, and global potential exportable feedstocks to produce hydrogen. A comprehensive analysis of current hydrogen production technologies with their energy efficiencies and hydrogen selling prices was reported in this study. Various hydrogen production technologies with their capital investments and CO2 emissions were also presented. Potential feedstocks for hydrogen production were identified and analyzed through a product space model, which characterizes a network of global exportable products based on their similarities and productive knowledge. It was established that the hydrogen production feedstocks and sources currently used are primarily available in six countries: the United States of America, France, Russia, Sweden, the Netherlands, and Spain. Broadly, the results revealed that the United States of America and Russia shared the highest hydrogen feedstock exports, indicating a higher probability of hydrogen production in these countries. Except for Russia, all the studied countries fell in the most desired quadrant, indicating that they can move in all product space directions to exploit unexplored hydrogen feedstocks for better sustainable economic growth.

Abstract This paper presents a conceptual study of a solar PV integrated refrigeration system for a cold storage facility based on the conventional vapor compression system for banana fruit. In the first stage, the conventional system has been thoroughly analyzed. Mathematical modelling has shown that the condenser is oversized, while the evaporator was undersized. Furthermore, the air-conditioning compressor was also found to be oversized by approximately 12 kW after an evaluation at no-load and full-load conditions. In the second stage, the optimized system with reduced consumption was integrated to a solar PV field. The solar field sizing, and performance optimization of the proposed PV hybrid refrigeration system was accomplished in PV*SOL tool. The simulations demonstrated that with a 170 m2 solar field, an optimized PV hybrid refrigeration system can achieve 58.1% solar fraction at a performance ratio of 59.2%, under given climatic conditions. With net metering, the hybrid system shows a high economic feasibility with the payback period of 5.2 years. The comprehensive methodology and all-inclusive results are valuable to generate explicit recommendations for repowering along with renewable integration of cold storage facilities operating in the region.

Assessing the impacts of climate change and land use/land cover changes on water resources within a catchment is essential because it helps us understand how these dynamic factors affect the quantity, quality, and availability of freshwater. This knowledge is crucial for making informed decisions about water management, conservation, and adaptation strategies, especially in regions facing increasing environmental uncertainties and challenges to water resource sustainability. In Pakistan’s Kunhar River Basin (KRB), this investigation explores the potential effects of shifting land use/land cover (LULC), and climate on stream flows. The SWAT (Soil and Water Assessment Tool), a semi-distributed hydrological model, and the most recent Coupled Model Intercomparison Project phase 6 (CMIP6) dataset from multiple global climate models (GCMs) were used to evaluate these effects. The temperature and precipitation data were downscaled using the CMhyd software; for both shared socioeconomic pathways (SSP2 and SSP5), the top-performing GCM out of four was required to produce downscaled precipitation and temperature predictions while taking future land use characteristics into account. The output from the chosen GCM indicated that by the conclusion of the 21st century, relative to the reference period (1985–2014), the study area’s average monthly precipitation, highest temperature, and lowest temperature will be increasing. Precipitation is anticipated to increase between 2015 and 2100 by 20.5% and 29.1% according to the SSP2 and SSP5 scenarios, respectively. This study’s findings, which emphasize the need for project planners and managers taking into account the effects of climate and land cover changes in their management techniques, show that climate change can have a significant impact on the changing seasons of flows in the Kunhar River basin.