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Although hydrothermal carbonization of biomass components is known to be mainly governed by reaction temperature, consistent reports on the effect and statistical significance of process conditions on hydrochar properties are still lacking. The objective of this research was to determine the importance and significance of reaction temperature, retention time and solid load on the properties of hydrochar produced from an industrial lignocellulosic sludge residue. According to the results, reaction temperature and retention time had a statistically significant effect on hydrochar ash content, solid yield, carbon content, O/C-ratio, energy densification and energy yield as reactor solid load was statistically insignificant for all acquired models within the design range. Although statistically significant, the effect of retention time was 3-7 times lower than that of reaction temperature. Predicted dry ash-free solid yields of attained hydrochar decreased to approximately 40% due to the dissolution of biomass components at higher reaction temperatures, as respective oxygen contents were comparable to subbituminous coal. Significant increases in the carbon contents of hydrochar led to predicted energy densification ratios of 1-1.5 with respective energy yields of 60-100%. Estimated theoretical energy requirements of carbonization were dependent on the literature method used and mainly controlled by reaction temperature and reactor solid load. The attained results enable future prediction of hydrochar properties from this feedstock and help to understand the effect of process conditions on hydrothermal treatment of lignocellulosic biomass.

Although hydrothermal carbonization of biomass components is known to be mainly governed by reaction temperature, consistent reports on the effect and statistical significance of process conditions on hydrochar properties are still lacking. The objective of this research was to determine the importance and significance of reaction temperature, retention time and solid load on the properties of hydrochar produced from an industrial lignocellulosic sludge residue. According to the results, reaction temperature and retention time had a statistically significant effect on hydrochar ash content, solid yield, carbon content, O/C-ratio, energy densification and energy yield as reactor solid load was statistically insignificant for all acquired models within the design range. Although statistically significant, the effect of retention time was 3-7 times lower than that of reaction temperature. Predicted dry ash-free solid yields of attained hydrochar decreased to approximately 40% due to the dissolution of biomass components at higher reaction temperatures, as respective oxygen contents were comparable to subbituminous coal. Significant increases in the carbon contents of hydrochar led to predicted energy densification ratios of 1-1.5 with respective energy yields of 60-100%. Estimated theoretical energy requirements of carbonization were dependent on the literature method used and mainly controlled by reaction temperature and reactor solid load. The attained results enable future prediction of hydrochar properties from this feedstock and help to understand the effect of process conditions on hydrothermal treatment of lignocellulosic biomass.

To mitigate the climate change-induced water shortage and realize the sustainable development of agriculture, drip irrigation, a more efficient water-saving irrigation method, has been intensively implemented in most arid agricultural regions in the world. However, compared to traditional border irrigation, how drip irrigation affects the biophysical conditions in the cropland and how crops physiologically respond to changes in biophysical conditions in terms of water, heat and carbon exchange remain largely unknown. In view of the above situation, to reveal the mechanism of drip irrigation in improving spring wheat water productivity, paired field experiments based on drip irrigation and border irrigation were conducted to extensively monitor water and heat fluxes at a typical spring wheat field (Triticum aestivum L.) in Northwest China during 2017–2020. The results showed that drip irrigation improved yield by 10.3 % and crop water productivity (i.e., yield-to-evapotranspiration-ratio) by 15.6 %, but reduced LAI by 16.9 % in contrast with border irrigation. Under drip irrigation, the lateral development of spring wheat roots was promoted by higher soil temperature combined with frequent dry-wet alternation in the shallow soil layer (0–20 cm), which was the basis for efficient absorption of water and fertilizer, as well as efficient formation of photosynthate. Meanwhile, drip irrigation increased net radiation and decreased latent heat flux by inhibiting leaf growth, thereby increased sensible heat, causing a higher soil temperature (+1.10 ℃) and canopy temperature (+1.11 ℃). Further analysis proved that soil temperature was the key factor affecting yield formation. Based on the above conditions, the decrease in leaf distribution coefficient (−0.030) led to the decrease in evapotranspiration (−5.7 %) and the increase in ear distribution coefficient (+0.029). Therefore, drip irrigation emphasized the role of soil moisture in the soil-plant-atmosphere continuum, enhanced crop activity by increasing field temperature, especially soil temperature, and finally improved yield and water productivity via carbon reallocation. The study revealed the mechanism of drip irrigation for improving spring wheat yield, and would contribute to improving Earth system models in representing agricultural cropland ecosystems with drip irrigation and predicting the subsequent biophysical and biogeochemical feedbacks to climate change.

To mitigate the climate change-induced water shortage and realize the sustainable development of agriculture, drip irrigation, a more efficient water-saving irrigation method, has been intensively implemented in most arid agricultural regions in the world. However, compared to traditional border irrigation, how drip irrigation affects the biophysical conditions in the cropland and how crops physiologically respond to changes in biophysical conditions in terms of water, heat and carbon exchange remain largely unknown. In view of the above situation, to reveal the mechanism of drip irrigation in improving spring wheat water productivity, paired field experiments based on drip irrigation and border irrigation were conducted to extensively monitor water and heat fluxes at a typical spring wheat field (Triticum aestivum L.) in Northwest China during 2017–2020. The results showed that drip irrigation improved yield by 10.3 % and crop water productivity (i.e., yield-to-evapotranspiration-ratio) by 15.6 %, but reduced LAI by 16.9 % in contrast with border irrigation. Under drip irrigation, the lateral development of spring wheat roots was promoted by higher soil temperature combined with frequent dry-wet alternation in the shallow soil layer (0–20 cm), which was the basis for efficient absorption of water and fertilizer, as well as efficient formation of photosynthate. Meanwhile, drip irrigation increased net radiation and decreased latent heat flux by inhibiting leaf growth, thereby increased sensible heat, causing a higher soil temperature (+1.10 ℃) and canopy temperature (+1.11 ℃). Further analysis proved that soil temperature was the key factor affecting yield formation. Based on the above conditions, the decrease in leaf distribution coefficient (−0.030) led to the decrease in evapotranspiration (−5.7 %) and the increase in ear distribution coefficient (+0.029). Therefore, drip irrigation emphasized the role of soil moisture in the soil-plant-atmosphere continuum, enhanced crop activity by increasing field temperature, especially soil temperature, and finally improved yield and water productivity via carbon reallocation. The study revealed the mechanism of drip irrigation for improving spring wheat yield, and would contribute to improving Earth system models in representing agricultural cropland ecosystems with drip irrigation and predicting the subsequent biophysical and biogeochemical feedbacks to climate change.

AbstractExtreme weather events can have strong negative impacts on species survival and community structure when surpassing lethal thresholds. Extreme, short‐lived, winter warming events in the Arctic rapidly melt snow and expose ecosystems to unseasonably warm air (for instance, 2–10 °C for 2–14 days) but upon return to normal winter climate exposes the ecosystem to much colder temperatures due to the loss of insulating snow. Single events have been shown to reduce plant reproduction and increase shoot mortality, but impacts of multiple events are little understood as are the broader impacts on community structure, growth, carbon balance, and nutrient cycling. To address these issues, we simulated week‐long extreme winter warming events – using infrared heating lamps and soil warming cables – for 3 consecutive years in a sub‐Arctic heathland dominated by the dwarf shrubsEmpetrum hermaphroditum, Vaccinium vitis‐idaea(both evergreen) andVaccinium myrtillus(deciduous). During the growing seasons after the second and third winter event, spring bud burst was delayed by up to a week forE. hermaphroditumandV. myrtillus, and berry production reduced by 11–75% and 52–95% forE. hermaphroditumandV. myrtillus, respectively. Greater shoot mortality occurred inE. hermaphroditum(up to 52%),V. vitis‐idaea(51%), andV. myrtillus(80%). Root growth was reduced by more than 25% but soil nutrient availability remained unaffected. Gross primary productivity was reduced by more than 50% in the summer following the third simulation. Overall, the extent of damage was considerable, and critically plant responses were opposite in direction to the increased growth seen in long‐term summer warming simulations and the ‘greening’ seen for some arctic regions. Given the Arctic is warming more in winter than summer, and extreme events are predicted to become more frequent, this generates large uncertainty in our current understanding of arctic ecosystem responses to climate change.

AbstractExtreme weather events can have strong negative impacts on species survival and community structure when surpassing lethal thresholds. Extreme, short‐lived, winter warming events in the Arctic rapidly melt snow and expose ecosystems to unseasonably warm air (for instance, 2–10 °C for 2–14 days) but upon return to normal winter climate exposes the ecosystem to much colder temperatures due to the loss of insulating snow. Single events have been shown to reduce plant reproduction and increase shoot mortality, but impacts of multiple events are little understood as are the broader impacts on community structure, growth, carbon balance, and nutrient cycling. To address these issues, we simulated week‐long extreme winter warming events – using infrared heating lamps and soil warming cables – for 3 consecutive years in a sub‐Arctic heathland dominated by the dwarf shrubsEmpetrum hermaphroditum, Vaccinium vitis‐idaea(both evergreen) andVaccinium myrtillus(deciduous). During the growing seasons after the second and third winter event, spring bud burst was delayed by up to a week forE. hermaphroditumandV. myrtillus, and berry production reduced by 11–75% and 52–95% forE. hermaphroditumandV. myrtillus, respectively. Greater shoot mortality occurred inE. hermaphroditum(up to 52%),V. vitis‐idaea(51%), andV. myrtillus(80%). Root growth was reduced by more than 25% but soil nutrient availability remained unaffected. Gross primary productivity was reduced by more than 50% in the summer following the third simulation. Overall, the extent of damage was considerable, and critically plant responses were opposite in direction to the increased growth seen in long‐term summer warming simulations and the ‘greening’ seen for some arctic regions. Given the Arctic is warming more in winter than summer, and extreme events are predicted to become more frequent, this generates large uncertainty in our current understanding of arctic ecosystem responses to climate change.

A design of experiments analysis was performed to investigate the effects of pilot quantity, combustion phasing and exhaust gas recirculation on performance and emissions in a gasoline partially premixed combustion to find out the optimal combination of the all varied parameters. The experimental activities were performed on a light-duty Volvo Euro 6 diesel engine. The test was performed under steady-state operating conditions, nine test points were chosen inside the operating area of the New European Driving Cycle and the Worldwide Harmonized Light vehicles Test Cycles. A fractional factorial analysis in partially premixed combustion on the single and combined effect of the main engine calibration parameters and a global comparison between partially premixed combustion and conventional diesel combustion on the engine performance and emissions adopting the optimal calibration parameters obtained from design of experiments analysis for both combustion modes analysed were presented. The purpose was to obtain the calibration parameters setting that permits to achieve high efficiency and low emissions as well. The partially premixed combustion results show the highest efficiency and lowest NOx emissions adopting a high exhaust gas recirculation rate combined with advanced combustion phasing and lower pilot quantity. Higher efficiency, up to 2.0% units, was obtained in partially premixed combustion with respect to the conventional diesel combustion due to the lower heat transfer loss. Lower soot (about two times) and NOx (about -0.5 g/kWh) levels with partially premixed combustion were obtained and compared to conventional diesel combustion at the same exhaust gas recirculation level. A reduction of about 5% of CO2 and fuel consumption with a 50% of reduction on NOx and soot simultaneously were obtained for partially premixed combustion on the New European Driving Cycle estimation results with respect to the diesel combustion. The information derived from this work are useful to develop and calibrate a light-duty engine that operate in gasoline partially premixed combustion mode achieving NOx close to the Euro 6 limit without adopting any after treatment system.