• Energy Research
• 2021-2025close
• IT close
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• Applied Energy close

Abstract Economically harvesting energy from a microbial fuel cell (MFC), increasing its electrical power production, and developing its role as a practical energy supply, needs a low-cost and high-performance design of the MFC compartments. According to this strategy, a novel monolithic membrane electrode assembly (MEA) was fabricated and evaluated as an air–cathode in a single-chamber MFC (SCMFC). The MEA was made of bacterial cellulose (BC), conductive multi-walled carbon nanotubes (CNT), and nano-zycosil (NZ). BC, as a nano-celluloses with oxygen barrier property, can maintain anaerobic conditions for the anode compartment. Binder-less CNT coating on BC avoids costly binders such as poly-tetra fluoro ethylene (PTFE) and Nafion and decreases the MEA charge transfer resistance. NZ, as a very cheap modifier, not only prevents the anolyte leakage but also provides more MEA’s active sites for the oxygen reduction reaction (ORR). The electrochemical performance of the MEA was compared to a PTFE- based gas diffusion electrode (GDE) in the SCMFC. The MEA cell provided a pulse power density of 1790 mW/m2, roughly twice as high as the pulse power density of GDE (920 mW/m2). SCMFC’s internal resistance decreased from 1.84 KΩ (with GDE) to 0.8 KΩ (with MEA). Also, the cell’s columbic efficiency increased from 4.2% (with GDE) to11.7% (with MEA). Additionally, the capacitance of the MEA (65 mF) was much higher than the value for GDE (0.73 mF). Thus, the MEA compared to the GDE showed higher performance in the SCMFC for electricity generation and wastewater treatment at a lower cost.

Abstract The methodology, the site and the dataset as well as the emissions scenario considered in the weather file definition influence the numerical evaluation of efficiency measures resilience. With a complete statistical and critical approach, the paper analyzes the importance of these aspects by means of a residential case study simulated in Benevento, a city of south Italy. Using data monitored from 2015 to 2020, a current weather file is built with different methodologies. The comparison indicates that there is not repeatability of the year chosen as a reference for the various months and thus the resolution of the building energy balance could bring different results. Some future climate projections are also generated on medium (2050 s) and long (2080 s) term considering different emission scenarios. With long term projection, the heating degree days are reduced also of − 21% meanwhile the cooling degree days are more than double compared with the current condition. This suggests a remarked transition towards a dominant cooling climate for Benevento. Moreover, when the climate change is considered, the insulation intervention and the installation of double glazed low emissive window is not resilient because the heating energy need decreases also of −56%, but the cooling energy need increases of + 62% (2080 s). If the efficiency measures include also the cool roof and the external shadings, the cooling demand could be reduced until –33% in some scenarios (e.g. RCP 4.5-50th percentile) and increased (+31%) in some others (e.g. 2080 s).