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Torrefaction is considered as a method for producing biofuels with improved characteristics compared to those of the “raw” biomass (higher calorific value, moisture resistance, better grindability). The torrefaction process is an endothermic process that is usually carried out in a gaseous atmosphere in the absence of oxygen. To reduce the required heat input, it is proposed to employ the oxidative torrefaction and conduct the process in a fluidized bed agitated with flue gases containing less than 6% oxygen. Preliminary studies of the oxidative torrefaction of sunflower husks, including thermogravimetric analysis of the treated material, have shown that the heat treatment time for the biomass should be at least 5 min. A fluidized bed is a reactor with ideal mixing of the treated material where uniform treatment of raw material particles cannot generally be attained. To overcome this disadvantage of the fluidization technique and achieve the required residence time for biomass in a fluidized bed during a continuous torrefaction process, it was proposed to equip a torrefaction reactor with a series of vertical baffles spaced at 50 mm. These baffles induce a loop-like flow of the processed biomass from the inlet to the outlet of the reactor. To investigate the residence time for husk particles in the reactor, a tracer, which was colored to husk particles' color with a water-soluble dye which did not change the weight and size of the particles, was injected into the bed of uncolored particles. Tracer samples were taken every 30 s at the outlet of the reactor and were analyzed using a special procedure to determine the fraction of colored particles in each sample. This enabled us to gauge the time during which the colored particles injected into the fluidized bed reached the point of their discharge from the bed. Studies performed in a “cold” model of the reactor showed that a series of vertical baffles in the bed can provide the required residence time for biomass in a reactor including commercial reactors. Plates can provide the necessary biomass residence time in the reactor.

AbstractNowadays, researchers are focusing on the methods of using recycled industrial/agricultural wastes as raw materials, which are not only economically but also environmentally useful. In the recent years, many scholars have conducted research on the rational use of rice husks (RHs) and found that RHs are rich in inorganic/organic components and used in combination with the certain building materials to produce new green composite building materials. This paper studies the method of using RH processed products and the sodium silicate solution (liquid glass) made from RH ash to produce cheap wood substitute composite materials, which can be improved the insulation performance of the wall greatly. Obtained results are determined by comparing with the properties of standard polymer composite materials such as particleboards, chipboards, and medium‐density fiberboards (MDF). The significance of the work is pointing out by solving the problem of recycling large‐tonnage agricultural waste and reproduce products with the consumer's value.

Abstract This study presents and evaluates the feasibility of a novel hybridization of modified Kalina cycle, reverse osmosis desalination, and low-temperature water electrolysis utilizing geothermal energy to yield power, distilled water, and hydrogen, respectively. The scientific impact of the current work has been improved considering the features of Sabalan flash-binary geothermal wells in Iran as a real model through a case study. In addition to designing a novel setup, the smart use of multi-heat recovery technique, modifying the base cycle, and utilizing a part of generated distilled water to produce hydrogen by the electrolyzer are the other structural originalities, distinguishing the current work from the previous studies. The suggested system is scrutinized via a parametric study and optimized based on a genetic algorithm. The parametric study demonstrated that the highest sensitivity of varying the performance criteria of the whole system is attributed to the change in flash tank pressure. Moreover, the multi-objective optimization led to achieving the exergy efficiency and trigeneration gain output ratio as 51.3% and 1.7 for the system, respectively. Furthermore, the system was able to produce 4795 kW of power, 5.3 kg/h of hydrogen, and 19.9 kg/s of distilled water.

This study examined the potential use of macroalgae epiphytic on mangrove aerial roots as indicators of estuarine contamination. The distribution and abundance of macroalgae was investigated in four estuaries in the vicinity of Sydney, Australia, and compared to water and sediment metal concentrations, nutrient concentrations and physicochemical parameters over four seasonal surveys. Macroalgal diversity and distribution appeared to be highly influenced by the ambient contaminant concentrations, while biomass appeared to be linked with nutrient concentrations. The distribution of the Rhodophyta species, Catenella nipae Zanardini significantly decreased as metal concentrations increased among the estuaries during all seasonal surveys. This species showed strong potential for use as a bioindicator of estuarine contamination.

Over the last few decades, environmental deterioration has accelerated significantly. Environmental degradation has been a subject of research across the world because of its impact on billions of people. However, there has been no international agreement on lowering the utilization of energy and CO2 emissions (CO2), while demand for fossil fuels grows in emerging economies. On the other hand, the recent COP26 summit brought all parties together to accelerate action toward reaching the goals of the Paris Agreement and the UN Framework Convention on Climate Change. Although previous research shows that international trade promotes positive socioeconomic outcomes, other experts argue that it contributes to natural resource shortages and ecological deterioration. Thus, the current research considers the effect of international trade, renewable energy use and technological innovation on consumption-based carbon emissions (CCO2), coupled with the role of financial development and economic growth in the BRICS economies between 1990 and 2018. Moreover, this research utilizes the common correlated effects mean group (CCEMG), augmented mean group (AMG) and Dumitrescu and Hurlin (2012) causality methods to assess these interrelationships. The study findings reveal that renewable energy use, exports and technological innovation mitigate CCO2, whereas economic growth and imports trigger CCO2 in the BRICS economies. The panel causality outcomes also reveal that all the variables except financial development can predict CCO2 emissions. Based on the study findings, we recommend the adoption of policies, regulations and the development of legislative frameworks that promote technological innovation and the shift toward sustainable energy.

Reduction in concentration of mechanical impurities is evaluated in the circulating flow of cleaned water, some of which has been passed through a hydrocyclone. A procedure for calculating the extent to which the solid phase is extracted into a slime-receiving bin is proposed for development of the hydrocyclone plant.

The Atominstitute of the Austrian Universities has conducted various space research missions in the last 12 years in cooperation with the Institute for Biomedical Problems in Moscow. They dealt with the exact determination of the radiation hazards for cosmonauts and the development of precise measurement devices. Special emphasis will be laid on the last experiment on space station MIR the goal of which was the determination of the depth distribution of absorbed dose and dose equivalent in a water filled Phantom. The first results from dose measurements onboard the International Space Station (ISS) will also be discussed. The spherical Phantom with a diameter of 35 cm was developed at the Institute for Biomedical Problems and had 4 channels where dosimeters can be exposed in different depths. The exposure period covered the timeframe from May 1997 to February 1999. Thermoluminescent dosimeters (TLDs) were exposed inside the Phantom, either parallel or perpendicular to the hull of the spacecraft. For the evaluation of the linear energy transfer (LET), the high temperature ratio (HTR) method was applied. Based on this method a mean quality factor and, subsequently, the dose equivalent is calculated according to the Q(LET infinity) relationship proposed in ICRP 26. An increased contribution of neutrons could be detected inside the Phantom. However the total dose equivalent did not increase over the depth of the Phantom. As the first Austrian measurements on the ISS dosimeter packages were exposed for 248 days, starting in February 2001 at six different locations onboard the ISS. The Austrian dosimeter sets for this first exposure on the ISS contained five different kinds of passive thermoluminescent dosimeters. First results showed a position dependent absorbed dose rate at the ISS.

The addition of ZnO, depleted in the Zn-64 isotope, to the water of boiling water nuclear reactors lessens the accumulation of Co-60 on the reactor interior surfaces, reduces radioactive wastes and increases the reactor service-life because of the inhibitory action of zinc on inter-granular stress corrosion cracking. To the same effect depleted zinc in the form of acetate dihydrate is used in pressurized water reactors. Gas centrifuge isotope separation method is applied for production of depleted zinc on the industrial scale. More than 20 years of depleted zinc application history demonstrates its benefits for reduction of NPP personnel radiation exposure and combating construction materials corrosion.

The sorption isotherms of copper(II) ions on natural calcium heulandite at a pH of 1.7 and temperature of 298–318 K have been obtained. The exchange sorption capacity with respect to Cu(II) ions at 298 K was 0.47 mg-eqv/g. The equilibrium constants of the ion exchange and thermodynamic functions including Gibbs energy and entropy and enthalpy of sorption have been calculated. The possibility of using calcium heulandite for purification of the wastewaters of the electroplating industry from ions of heavy metals has been assessed.