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This paper presents the design of an extended Kalman filter (EKF) as a state-of-charge (SoC) estimator for a lithium–titanate (LTO) battery cell. The design is based on a Thevenin model of the equivalent battery electrical circuit with two parallel resistive-capacitive (RC) elements for the emulation of electrolyte polarization effects. The effectiveness of the proposed SoC estimator is verified through computer simulations on the comprehensive nonlinear battery simulation model featuring battery parameter vs. SoC variations, which is subject to highly dynamic loading regimes.

This paper presents the design of an extended Kalman filter (EKF) as a state-of-charge (SoC) estimator for a lithium–titanate (LTO) battery cell. The design is based on a Thevenin model of the equivalent battery electrical circuit with two parallel resistive-capacitive (RC) elements for the emulation of electrolyte polarization effects. The effectiveness of the proposed SoC estimator is verified through computer simulations on the comprehensive nonlinear battery simulation model featuring battery parameter vs. SoC variations, which is subject to highly dynamic loading regimes.

The concept and a new method for the shielded development of bottom gas hydrates have been proposed, the technological phases and constructive elements of their implementation have been substantiated. The research provides for the realization of the idea suggesting the simultaneous dissociation of the vast areas of a gas hydrate deposit, management of the targeted process of the penetration of methane recovered from gas hydrates into water space and its accumulation under the extensive gas-collecting shield wherefrom it is removed by bottom pipe transportation facilities. To do hydraulic fracturing, a well is drilled into the plane of the junction of the surface of a gas hydrate deposit and the rocks of a roof, the open system of fissures in the rocks of a roof is made through which produced gas is released to a gas-collecting blanket in a water.

The concept and a new method for the shielded development of bottom gas hydrates have been proposed, the technological phases and constructive elements of their implementation have been substantiated. The research provides for the realization of the idea suggesting the simultaneous dissociation of the vast areas of a gas hydrate deposit, management of the targeted process of the penetration of methane recovered from gas hydrates into water space and its accumulation under the extensive gas-collecting shield wherefrom it is removed by bottom pipe transportation facilities. To do hydraulic fracturing, a well is drilled into the plane of the junction of the surface of a gas hydrate deposit and the rocks of a roof, the open system of fissures in the rocks of a roof is made through which produced gas is released to a gas-collecting blanket in a water.

Theoretical and experimental data on the concentrations of methane in different phase states in the porous structure of coals from the Donets Basin are reported. On the saturation of coal samples with methane, the natural conditions of the occurrence of methane in coal beds were simulated for the equilibrium coal–gas system. The amounts of methane dissolved in a solid matrix and adsorbed on the pore surfaces of coal matter were measured by broad-band NMR spectroscopy. The values obtained did not exceed 20% of the total methane absorbed by the sample in an equilibrium state at a pressure of 10 MPa. Sorbed methane was the predominant phase state only upon the opening of a high-pressure chamber after the emission of methane from filtration channels.

Theoretical and experimental data on the concentrations of methane in different phase states in the porous structure of coals from the Donets Basin are reported. On the saturation of coal samples with methane, the natural conditions of the occurrence of methane in coal beds were simulated for the equilibrium coal–gas system. The amounts of methane dissolved in a solid matrix and adsorbed on the pore surfaces of coal matter were measured by broad-band NMR spectroscopy. The values obtained did not exceed 20% of the total methane absorbed by the sample in an equilibrium state at a pressure of 10 MPa. Sorbed methane was the predominant phase state only upon the opening of a high-pressure chamber after the emission of methane from filtration channels.

Abstract Some new structures of thin-film solar converters (SC) based on heterojunctions (HJ) with intermediate semiconductor layers are suggested. Thin protective layers and a quasi-electric field incorporated into the space charge region (SCR) prevent cross-diffusion of HJ components and increase efficiency of charge carrier separation. They also decrease the diode dark current and provide high stability of the converter parameters. Thin (∼ 0.1 μ M) (CdSe) x (ZnTe) 1− x or Zn x Cd 1− x Se layers were used as graded band-gap layers. They were places between a photosensitive II-VI-compound (CdTe, CdSe, CdSe x Te 1− x ) base layer and the transparent Cu 1.8 S layer. The above structures were prepared by vacuum closed space sublimation. The properties of these compounds were studied by electron microscopy and X-ray photoelectron spectroscopy (XPS) with ion etching. The photoelectron properties of structures such as Cu 1.8 S/(CdSe) x )(ZnTe) 1− x /CdSe are presented in detail. The manufacturing technology for the integrated solar batteries based on CdTe, CdSe, and CdSe x Te 1− x compounds was developed. The solar cell parameters under low illumination intensities are comparable to those of solar batteries based on c-Si and a-Si. The competitiveness of the polycrystalline thin-film SC is due to ease and low cost of fabrication (as compared with c-Si and a-Si) and also to the extended photosensitivity range (as compared to a-Si).

Abstract Some new structures of thin-film solar converters (SC) based on heterojunctions (HJ) with intermediate semiconductor layers are suggested. Thin protective layers and a quasi-electric field incorporated into the space charge region (SCR) prevent cross-diffusion of HJ components and increase efficiency of charge carrier separation. They also decrease the diode dark current and provide high stability of the converter parameters. Thin (∼ 0.1 μ M) (CdSe) x (ZnTe) 1− x or Zn x Cd 1− x Se layers were used as graded band-gap layers. They were places between a photosensitive II-VI-compound (CdTe, CdSe, CdSe x Te 1− x ) base layer and the transparent Cu 1.8 S layer. The above structures were prepared by vacuum closed space sublimation. The properties of these compounds were studied by electron microscopy and X-ray photoelectron spectroscopy (XPS) with ion etching. The photoelectron properties of structures such as Cu 1.8 S/(CdSe) x )(ZnTe) 1− x /CdSe are presented in detail. The manufacturing technology for the integrated solar batteries based on CdTe, CdSe, and CdSe x Te 1− x compounds was developed. The solar cell parameters under low illumination intensities are comparable to those of solar batteries based on c-Si and a-Si. The competitiveness of the polycrystalline thin-film SC is due to ease and low cost of fabrication (as compared with c-Si and a-Si) and also to the extended photosensitivity range (as compared to a-Si).