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A template‐agent can affect defect formation as well as influence interface properties, due to the rapid growth of perovskite film from the solution. Herein, diethylammonium iodide (DAI) is used as an effective template‐agent to control the perovskite crystallization during preparation. It is found that a very small amount of DAI in chlorobenzene (CB) can slow down the perovskite growth of the CH3NH3PbI3 (MAPbI3) film with more large grain size and compacted crystal‐grains resulting in the lesser grain boundaries (GBs) in favor of carrier transport in perovskite solar cells (PSCs). Moreover, some redundant PbI2 can be digested to form DA2PbI4. One part of DA2PbI4 can form the sub‐grains with the composition of (DA2PbI4)0.2(PbI2)0.8 to passivate the GB defects, and other part can cover the surface to passivate the surface defects in large MAPbI3 grains. Using an optimized DAI concentration of 0.5 mg mL−1 in CB solution, the corrsponding MAPbI3 PSC achieves an increased power conversion efficiency of 20.31% with suppressed current–voltage hysteresis. This DAI passivation strategy provides a simple approach to effectively assist the grain‐growth for improved device performance.

The rapid development of advanced metering infrastructure provides a new data source—building electrical load profiles with high temporal resolution. Electric load profile characterization can generate useful information to enhance building energy modeling and provide metrics to represent patterns and variability of load profiles. Such characterizations can be used to identify changes to building electricity demand due to operations or faulty equipment and controls. In this study, we proposed a two-path approach to analyze high temporal resolution building electrical load profiles: (1) time-domain analysis and (2) frequency-domain analysis. The commonly adopted time-domain analysis can extract and quantify the distribution of key parameters characterizing load shape such as peak-base load ratio and morning rise time, while a frequency-domain analysis can identify major periodic fluctuations and quantify load variability. We implemented and evaluated both paths using whole-year 15-minute interval smart meter data of 188 commercial office building in Northern California. The results from these two paths are consistent with each other and complementary to represent full dynamics of load profiles. The time- and frequency-domain analyses can be used to enhance building energy modeling by: (1) providing more realistic assumptions about building operation schedules, and (2) validating the simulated electric load profiles using the developed variability metrics against the real building load data.

Abstract The prime purpose of this work is to prepare a novel kind of Pickering interfacial solid catalysts for biodiesel production to meet the requirements of highly efficiency and environmental benign. To achieve this goal, the core–shell P[xSPA-yDABCO]@SiO2@Fe3O4 composite materials with a shell of photo-responsive and base catalytic sites were manufactured by means of layer-by-layer fabrication method. The modified materials, entirely characterized by transmission electron microscopy (TEM), scanning electron microscope (SEM), Fourier transform infrared (FT-IR) spectra, X-ray powder diffraction (XRD) and magnetization versus magnetic (VSM) techniques, demonstrated sufficient catalytic active sites and photo-responsive sites. Among all the so-prepared catalysts, P[3SPA-2DABCO]@SiO2@Fe3O4 performs extremely well and can stabilize soybean oil-in-methanol Pickering emulsion for 24 h, achieving a biodiesel yield up to 98.2% at a catalyst dosage of 5 wt% after the reaction time of 5 h at 60 °C. Furthermore, the double responsive solid catalyst can be readily separated from the mixture of reaction by an external magnet and UV irradiation, and still presented superior catalytic activity after 6 cycles.

Building, bridge or wind turbine maintenance requires manual dexterity tasks by a specialist rope-access trained workforce via two principal means: harness suspension of individual workers from above, or deployment of a suspended platform or cradle from which workers access the structure to be maintained. Currently no published research compares accuracy and efficiency of simulated maintenance tasks between these modalities. This study investigated manual dexterity task performance of peg placement and shape delineation in seated, standing and suspended environments in 16 healthy controls and 26 professional rope-access trained individuals. Both seated and standing assessments were superior to those suspended, and height of suspension, total mass and years of experience had no influence on the task outcome. These findings suggest that, where feasible, cradle suspension mechanisms which permit standing maintenance are favourable in terms of task efficacy and where feasible, should be considered for deployment in wind energy and other engineering applications.

The electro-hydraulic servo pump control system (EHSPCS) is a volume control system that uses a permanent magnet synchronous motor (PMSM) with a fixed displacement pump to directly drive and control the hydraulic cylinder. The energy transmission law of the system is very complicated due to the transformation of electrical, mechanical and hydraulic energy as well as other energy fields, and qualitative analysis of the energy transfer efficiency is difficult. Energy transfer analysis of the EHSPCS under different working conditions and loads is proposed in this paper. First, the energy flow transfer mechanism was analyzed, and the mathematical and energy transfer models of the key components of the system were established to explore the energy characteristic state transition rule. Second, a power bond diagram model was built, its state equation and state matrix were deduced, and a system simulation model was built. Finally, combined with the EHSPCS experimental platform, simulation experiments were carried out on the dynamic position following and steady-state position holding conditions of the system, and the variation rules of the power of each energy characteristic state and the system energy transfer efficiency under different loads were obtained. The research results provide a foundation for the study of power matching and energy-saving mechanism of the EHSPCS.

Abstract In this paper, we analyze the rationale for an energy policy mix when the European Emissions Trading Scheme (ETS) is considered from a public choice perspective. That is, we argue that the economic textbook model of the ETS implausibly assumes (1) efficient policy design and (2) climate protection as the single objective of policy intervention. Contrary to these assumptions, we propose that the ETS originates from a political bargaining game within a context of multiple policy objectives. In particular, the emissions cap is negotiated between regulators and emitters with the emitters' abatement costs as crucial bargaining variable. This public choice view yields striking implications for an optimal policy mix comprising RES supporting policies. Whereas the textbook model implies that the ETS alone provides sufficient climate protection, our analysis suggests that support for renewable energies (1) contributes to a more effective ETS-design and (2) may even increase the overall efficiency of climate and energy policy if other externalities and policy objectives besides climate protection are considered. Thus, our analysis also shows that a public choice view not necessarily entails negative evaluations concerning efficiency and effectiveness of a policy mix.

AbstractRevolutionary changes in energy storage technology have put forward higher requirements on next‐generation anode materials for lithium‐ion battery. Recently, a new class of materials with complex stoichiometric ratios, high‐entropy oxide (HEO), has gradually emerging into sight and embracing the prosperity. The ideal elemental adjustability and attractive synergistic effect make HEO promising to break through the integrated performance bottleneck of conventional anodes and provide new impetus for the design and development of electrochemical energy storage materials. Here, the research progress of HEO anodes is comprehensively reviewed. The driving force behind phase stability, the role of individual cations, potential mechanisms for controlling properties, as well as state‐of‐the‐art synthetic strategies and modification approaches are critically evaluated. Finally, we envision the future prospects and related challenges in this field, which will bring some enlightening guidance and criteria for researchers to further unlock the mysteries of HEO anodes.image

ASHRAE Standard 62-1989 (Standard 62-89) Ventilation for Acceptable Indoor Air Quality'' is the new heating, ventilating, and air-conditioning (HVAC) industry consensus for ventilation air in commercial buildings. Bonneville Power Administration (Bonneville) references ASHRAE Standard 62-81 (the predecessor to Standard 62-89) in their current environmental documents for required ventilation rates. Through its use, it had become evident to Bonneville that Standard 62-81 needed interpretation. Now that the revised Standard (Standard 62-89) is available, its usefulness needs to be evaluated. Based on current information and public comment, the American Society of Heating, Refrigeration, and Air-Conditioning Engineers (ASHRAE) revised Standard 62-1981 to Standard 62-89. Bonneville's study estimated the energy and cost implications of ASHRAE Standard 62-89 using simulations based on DOE-2.1D, a computer simulation program which estimates building use hourly as a function of building characteristics and climatic location. Ten types of prototypical commercial buildings used by Bonneville for load forecasting purposes were examined: Large and Small Office, Large and Small Retail, Restaurant, Warehouse, Hospital, Hotel, School, and Grocery. These building characterizations are based on survey and energy metering data and represent average or typical construction and operation practices and mechanical system types. Prototypical building ventilation rates were varied in five steps to estimate the impacts of outside air on building energy use. 11 refs., 14 tabs.