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In this study, levulinic acid (LA) was produced from rice straw biomass in co-solvent biphasic reactor system consisting of hydrochloric acid and dichloromethane organic solvent. The modified protocol achieved a 15% wt LA yield through the synergistic effect of acid and acidic products (auto-catalysis) and the designed system allowed facile recovery of LA to the organic phase. Further purification of the resulting extractant was achieved through traditional column chromatography, which yielded a high purity LA product while recovering ∼85% wt. Upon charcoal treatment of the resultant fraction generated an industrial grade target molecule of ∼99% purity with ∼95% wt recovery. The system allows the solvent to be easily recovered, in excess of 90%, which was shown to be able to be recycled up to 5 runs without significant loss of final product concentrations. Overall, this system points to a method to significantly reduce manufacturing cost during large-scale LA preparation.

Abstract: The dynamics of reformation and replacement of gas hydrates were studied under nonequilibrium conditions. It was found that the reformation of gas hydrates is largely affected by the state of the gas‐water system and the restarting temperature. This suggests that the effects are caused by changes in the structure of the aqueous solution at a molecular level. Pure samples of CH4 gas hydrate were synthesized from ice crystals and the dissociated solution using the reformation method. Replacement of CO2 gas hydrate is achieved within a short duration in the solid‐phase sample of CH4 gas hydrate, if the pressure and temperature is precisely controlled in a pressure vessel.

Abstract The 2013/2017 Nankai Trough (Japan) and 2017 Shenhu Area (China) offshore methane hydrate production tests showed the world the possibility and feasibility of the oceanic methane hydrate production by depressurization. However, the relatively low gas production rate still remained as one of the critical bottlenecks for the economical utilization. This study chose the Nankai Trough as a target area, and aimed at the gas recovery enhancement from the methane hydrate reservoir using vertical wells. A traditional single-vertical-well system and a new dual-vertical-well system were proposed, and special production strategies of the aggressive depressurization and permeability improvement were applied to these two systems for the effectiveness verification. Based on the 15-year simulation results, it was found that the middle low-permeability silt-dominated layers in the reservoir held the key to the gas recovery enhancement, and for the single-vertical-well system, the permeability improvement in this sublayer seemed more reliable and feasible than the aggressive depressurization. On the other hand, the dual-vertical-well system significantly exceeded the single-vertical-well system due to the synergistic effect of the two wellbores, and could raise the average gas production rate (9.5 × 103 m3/day) by one order of magnitude (to 7.9 × 104 m3/day). Moreover, if this new system was combined with the aggressive depressurization, the average gas production rate could be further raised by one order of magnitude (to 3.4 × 105 m3/day).

Abstract Synthetic hyperaccumulator biomass (SHB) impregnated with Ni, Zn, Cu, Co or Cr was used to conduct 11 experiments in a lab-scale fluidized bed reactor. Two runs with blank corn stover, with no metal added, were also conducted. The reactor was operated in an entrained mode in a oxygen-free (N2) environment at 873 K and 1 atm . The apparent gas residence time through the lab-scale reactor was 0.6 s at 873 K . The material balance for the lab-scale experiments on N2-free basis varied between 81% and 98%. The presence of a heavy metal in the SHB decreased the char yield and increased the tar yield, compared to the blank. The char and gas yields appeared to depend on the form of the metal salt used to prepare the SHB. However, the metal distribution in the product streams did not seem to be influenced by the chemical form of the metal salt used to prepare the SHB. Greater than 98.5% of the metal in the product stream was concentrated in the char formed by pyrolyzing and gasifying the SHB in the reactor. The metal concentration in the char varied between 0.7 and 15.3% depending on the type of metal in the SHB. However, the metal concentration was increased 4 to 6 times in the char compared to the feed.

Microbial fuel cell (MFC) is an emerging biotechnology to convert the organic substrates in wastewater to electricity by anaerobic electrogenic bacteria. The main challenge for MFC research is to elucidate the fundamental mechanisms of electron generation and transfer and to apply these mechanisms to improve the power production in the engineering operation. This study extensively investigated the effects of three inocula (Geobacter sulfurreducens, soil, and wastewater) on the power production and electrochemical characteristics (i.e., internal resistances, Coulombic Efficiency) of MFCs. The results showed that the extents of bacterial adhesion varied between mixed cultures (soil) and pure cultures (G. sulfurreducens). The voltage output increased 30% when bacterial adhesion was well-developed in the soil inocula. Meanwhile, the inoculum types clearly affected the internal resistance (R(in)) and power production of MFCs. Pure culture inoculum (G. sulfurreducens) had the lowest R(in) (165 Omega) and the highest Coulombic Efficiency (CE, 25.8%) and Energy Conversion Efficiency (ECE, 7.2%), while the mixed culture inocula (soil) with the high concentration of nonelectrogenic bacteria, exhibited the highest R(in) (620 Omega), lowest CE (9.2%) and lowest ECE (2.4%). Additionally, a second-order correlation was established between the anode potential (P(A)) and power output while an exponential correlation was established between the difference between anode and cathode potentials (DeltaP(C-A)) and power output.

In this study, pyrolysis of microalgal remnants was investigated for recovery of energy and nutrients. Chlorella vulgaris biomass was first solvent-extracted for lipid recovery then the remnants were used as the feedstock for fast pyrolysis experiments using a fluidized bed reactor at 500 °C. Yields of bio-oil, biochar, and gas were 53, 31, and 10 wt.%, respectively. Bio-oil from C. vulgaris remnants was a complex mixture of aromatics and straight-chain hydrocarbons, amides, amines, carboxylic acids, phenols, and other compounds with molecular weights ranging from 70 to 1200 Da. Structure and surface topography of the biochar were analyzed. The high inorganic content (potassium, phosphorous, and nitrogen) of the biochar suggests it may be suitable to provide nutrients for crop production. The bio-oil and biochar represented 57% and 36% of the energy content of the microalgae remnant feedstock, respectively.

Abstract There are instances in remote areas where heat is being wasted, e.g., in internal combustion, engines, etc. Some of this heat can be recovered to produce distilled water in solar stills. The solar still replaces the cooling tower, ponds, or radiators normally used to control the engine temperature. The diesel cooling water in such a system remains separate from the saline water in the solar still. The advantages of using such a system compared with a conventional solar still are: 1. (a) water costs are very much reduced 2. (b) the area occupied is much less, i.e., about 1 5 th 3. (c) production has much less seasonal variation 4. (d) the efficiency of the solar still is improved due to the higher operating temperatures. From experiments conducted at Highett using a Mk VI solar still fitted with a simple heat exchanger and a separate electrically-heated source of hot water to simulate the waste heat, design data are not available for application to working systems. The information required to match a solar still to a diesel's cooling requirement is: 1. (a) engine efficiency 2. (b) hourly fuel consumption 3. (c) hourly solar radiation 4. (d) hourly ambient temperatures. A by-product of this work has been the production of a “solar water heater” which costs less than that of the cheapest conventional system. This “solar” hot water system uses a heat exchanger similar to what is used to transfer the waste heat to the saline water. It is envisaged to have hot water productions approximately the same as the distilled water productions. The influence of hot water production on the output of the waste heat solar still is discussed.

Abstract A dynamic model of vapour compression refrigeration system is developed. The overall model consists of the following basic components: a compressor, a condenser, an expansion valve, an evaporator, an evaporative cooler and a cool storage. The integrated system is referred to as chilled water cooling system with storage (CWCS). The mathematical modelling of the CWC system undertaken in this study predicts the change in state of refrigerant in the system with respect to time. A computer program is developed to solve the dynamic equations along with empirical correlations describing refrigerant properties. Open-loop tests are carried out to study the performance characteristics of the system under varied cooling load and compressor speed. The model is intended to serve as an analytical design tool and to provide a basis for control analysis. Based on a heuristic method, ‘sub-optimal on–off control’ strategies for the chilled water cool storage system are developed using a reduced order model. The methodology of generating such control profiles is illustrated and the tests for optimality show that the control profiles are near optimal. The on–off control scheme is simulated on the full order CWC system. The operating performance of the system is described under several simulated cases. The results show that the control scheme is capable of maintaining the chilled water temperature in the chosen range.

Abstract Bioproducts from biomass feedstocks and organic wastes have shown great potential to address challenges across food-energy-water systems. However, bioproducts production is at an early, nascent stage that requires new inventions and cost-reducing approaches to meet market needs. Biochar, a byproduct of the pyrolysis process, derived from nutrient-rich biomass feedstocks (e.g., cattle manure and poultry litter) is one of these bioproducts that has numerous applications, such as improving soil fertility and crop productivity. This study investigates the market opportunity and sustainability benefits of converting manure to biochar on-site, using a portable refinery unit. Techno-economic and environmental impact assessments are conducted on a real case study in Twin Falls, Idaho, USA. The techno-economic analysis includes a stochastic optimization model to calculate the total cost of biochar production and distribution. The environmental study employs a life cycle assessment method to evaluate the global warming potential of manure-to-biochar production and distribution network. The total cost of biochar production from cattle manure near the feedlots is approximately $237 per metric ton, and total emission is 951 kg CO2 eq. per metric ton. The on-site operation and manure moisture content are two key parameters that can reduce biochar unit price and carbon footprint of manure management. It is concluded that converting cattle manure, using the presented strategy and process near the collection sites can address upstream and midstream sustainability challenges and stimulate the biochar industry.