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© 2020 Elsevier Ltd Free cooling of buildings uses the nocturnal outdoor air as a heat sink via a ventilation process. This could be performed by storing the night coolness for use during the daytime as appropriate. Due to the latent heat capacity, phase change material (PCM) could play anessential role in the effective operation of the free cooling systems by shifting the daytime peak load to the night. However, there is a scarceness on the technology application in hot climates. This paper presents results of a parametric investigation into the application of PCMs as thermal energy storage (TES) to provide sustainable cooling to buildings in hot arid climate by making use of the night-time free cooling. The proposed TES medium comprises an arrangement of metallic modules filled with RT28HC PCM. Numerous geometrical configurations and operational parameters have been assessed. A transient CFD simulation has been employed using ANSYS Fluent software. Validation of the numerical results with experimental data has shown a good agreement. The results have demonstrated that the temperature difference between the PCM and the air, at appropriate air flow rate would have a significant impact on the performance of the system. A free cooling system based on the proposed arrangement has the potential to meet around 42% of a typical building cooling load and has the ability to save up to 67% of building cooling energy load in summer season compared to conventional air-conditioning systems in hot arid climates.

Decarbonizing the building sector is extremely important to mitigating climate change as the sector contributes 40% of the overall energy consumption and 36% of the total greenhouse gas emissions in the world. Net-zero energy buildings are one of the promising decarbonization attempts due to their potential of decreasing the use of energy and increasing the total share of renewable energy. To achieve a net-zero energy building, it is necessary to decrease the energy demand by applying efficiency enhancement measures and using renewable energy sources. Net-zero energy buildings can be classified into four models (Net-Zero Site Energy buildings, Net-Zero Emissions buildings, Net-Zero Source Energy buildings, and Net-Zero Cost Energy buildings). A variety of technical, financial, and environmental factors should be considered during the decision-making process of net-zero energy building development, justifying the use of multi-criteria decision analysis methods for the design of net-zero energy buildings. This paper also discussed the contributions of renewable energy generation (hydropower, wind energy, solar, heat pumps, and bioenergy) to the development of net-zero energy buildings and reviewed its role in tackling the decarbonization challenge. Cost-benefit analysis and life cycle assessment of building designs were reviewed to shape the priorities of future development. It is important to develop a universal decision instrument for optimum design and operation of net-zero energy buildings.

White sweet clover found voluntarily growing on a deep bed of soft coal fly ash was found to contain high concentrations of a number of elements including selenium, bromine, and molybdenum, rubidium, strontium, and others. The clover was harvested and fed as 23.5% of a dry pelleted ration to lambs and pregnant goats for up to 173 days. High concentrations of selenium were found in 11 tissues, blood, goats' milk, and excreta of lambs, goats, and newborn kids. Molybdenum in liver, strontium in bone, and bromine and rubidium in animal tissues were also elevated over those in the corresponding tissues of animals fed an identical ration containing control clover grown on soil. No gross or histologic lesions were present in any of the animals.

In this study, levulinic acid (LA) was produced from rice straw biomass in co-solvent biphasic reactor system consisting of hydrochloric acid and dichloromethane organic solvent. The modified protocol achieved a 15% wt LA yield through the synergistic effect of acid and acidic products (auto-catalysis) and the designed system allowed facile recovery of LA to the organic phase. Further purification of the resulting extractant was achieved through traditional column chromatography, which yielded a high purity LA product while recovering ∼85% wt. Upon charcoal treatment of the resultant fraction generated an industrial grade target molecule of ∼99% purity with ∼95% wt recovery. The system allows the solvent to be easily recovered, in excess of 90%, which was shown to be able to be recycled up to 5 runs without significant loss of final product concentrations. Overall, this system points to a method to significantly reduce manufacturing cost during large-scale LA preparation.

This article examines land-use, market and welfare implications of lignocellulosic bioethanol production in Hawaii to satisfy 10% and 20% of the State's gasoline demand in line with the State's ethanol blending mandate and Alternative Fuels Standard (AFS). A static computable general equilibrium (CGE) model is used to evaluate four alternative support mechanisms for bioethanol. Namely: (i) a federal blending tax credit, (ii) a long-term purchase contract, (iii) a state production subsidy financed by a lump-sum tax and (iv) a state production subsidy financed by an ad valorem gasoline tax. We find that because Hawaii-produced bioethanol is relatively costly, all scenarios are welfare reducing for Hawaii residents: estimated between -0.14% and -0.32%. Unsurprisingly, Hawaii.s economy and its residents fair best under the federal blending tax credit scenario, with a positive impact to gross state product of $49 million. Otherwise, impacts to gross state product are negative (up to -$63 million). We additionally find that Hawaii-based bioethanol is not likely to offer substantial greenhouse gas emissions savings in comparison to imported biofuel, and as such the policy cost per tonne of emissions displaced ranges between $130 to $2,100/tonne of CO2e. The policies serve to increase the value of agricultural lands, where we estimate that the value of pasture land could increase as much as 150% in the 20% AFS scenario.

As the concern with global warming increases causing the need for CO2 reduction, renewable energy is of great interest as it has lower carbon footprint when compared to conventional sources (natural gas, coal, oil and nuclear). Solar energy has been drawing worldwide attention since it can transform sunlight directly into electricity with the use of photovoltaic (PV) cells. However, this technology has some drawbacks that need to be addressed including dust deposition on solar panels, also known as soiling. Soiling can decrease PV panel's efficiency thereby resulting in less energy production. The soiling rates are very site specific and depend on the geographic location of the panels and the climate in that area. The solar panels can be cleaned naturally (by rainfall, snow or wind) or mechanically washed. This thesis addresses the impact of solar panel soiling and washing on the energy production of solar PV plants located at the UNLV campus. The objectives of this project were (a) to evaluate whether rainfall alone, in the desert environment with low rainfall, is sufficient to clean up the solar panels, and, if possible, determine the minimum amount of rainfall necessary to clean up panels.; (b) to examine the efficiency loss caused by soiling using different methods of analyses and (c) to evaluate if panel washing is worthwhile given the cost and the efficiency gain that is obtained by washing. To calculate the efficiency of the panels, a model was developed to generate parameters that were not measured at the site. Panel efficiencies before and after rainfall events were compared to determine the minimum amount of rain necessary to clean the panels. It was found that at least 0.2 inches of rain was needed to partially restore clean-panel efficiency. In Las Vegas, the recurrence periods of different depths rainfall were calculated using data from the past 29 years. It was observed that the 50th percentile recurrence period of a rainfall event with depth of 0.2 inches or higher was approximately 52 days. Student Union: -0.0044%/day, CBC-C: -0.00099%/day, and Dayton Hall: -0.0034%/day The amount of efficiency lost during the dry intervals (periods between rainfall events) was analyzed in three different ways. The average efficiency loss per day during the dry periods varied from -0.000171 % to -0.00533 %, depending on the method used and the building where the panels were located. However, there were some limitations to the calculations. It was not possible to completely isolate the effects of only soiling on the efficiency of the panels. The rate of decline seemed to be also impacted by seasonal effects. To better evaluate the effect of washing, a professional company was hired to wash a set of solar panels located on UNLV's Student Union building. The panels were washed with water with a low concentration of TDS. The power output and the efficiency of those panels were analyzed from before and after the washing. There was a very small efficiency and power increase due to the washing. Therefore, it was concluded that washing in this area is not worthwhile, and that rainfall events in excess of 0.2 inches can adequately restore the efficiency of the panels. If there is a change in cost of energy, washing, water or a great increase in the efficiency of the solar panels, it would be necessary to reevaluate the analysis.

AbstractClimate change poses new and unique challenges that threaten lives and livelihoods. Given the increasing risks and looming uncertainty of climate change, increasing attention has been directed towards adaptation, or the strategies that enable humanity to persist and thrive through climate change the best it can. Though climate change is a global problem often discussed at the national scale, urban areas are increasingly seen as having a distinct role, and distinctive motivation and capacity, for adaptation. The 12 articles in this special issue explore ways of understanding and addressing climate change impacts on urban areas. Together they reveal young but rapidly growing scholarship on how to measure, and then overcome, challenges of climate change. Two key themes emerge in this issue: 1) that we must identify and then overcome current barriers to urban adaptation and 2) frameworks/metrics are necessary to identify and track adaptation progress in urban settings. Both of these themes point to the power of indicators and other quantitative information to inform priorities and illuminate the pathway forward for adaptation. As climate change is an entirely new challenge, careful measurement that enables investment by private and public parties is necessary to provide efficient outcomes that benefit the greatest number of people.

Recycled polylactic acid (PLAr) was reinforced with treated nanocellulosic hemp fibers for biocomposite fabrication. Cellulosic fibers were extracted from hemp fibers chemically and treated enzymatically. Treated nanocellulosic fibers (NCF) were analyzed by Fourier-transform infrared spectroscopy, X-ray diffraction, and scanning electron microscopy. Biocomposite fabrication was done with PLAr and three concentrations of treated NCF (0.1%, 0.25%, and 1% (v/v)) and then studied for thermal stability and mechanical properties. Increased thermal stability was observed with increasing NCF concentrations. The highest value for Young’s modulus was for PLAr + 0.25% (v/v) NCF (250.28 ± 5.47 MPa), which was significantly increased compared to PLAr (p = 0.022). There was a significant decrease in the tensile stress at break point for PLAr + 0.25% (v/v) NCF and PLAr + 1% (v/v) NCF as compared to control (p = 0.006 and 0.002, respectively). No significant difference was observed between treatments for tensile stress at yield.