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Abstract Heat pipes and two-phase thermosyphons are highly efficient heat transfer devices utilizing continuous evaporation and condensation of working fluid for two-phase heat transport in closed systems. Because of the nearly isothermal and fully passive phase-change heat transfer mechanism, heat pipes and thermosyphons have found many applications in nuclear engineering, space technologies, and other energy systems. High-temperature heat pipes are used in nuclear microreactors to remove fission power from the primary system and are coupled with power conversion systems or process heat applications. Modeling of the two-phase flow phenomena inside a heat pipe is essential to its design and safety analysis. In this study, a comprehensive one-dimensional two-phase three-field flow model has been developed for the analysis of heat pipes in normal operation conditions and transients. The conservation or field equations of mass, momentum, and energy were developed for the liquid film, vapor, and droplet. In addition, constitutive models or correlations were reviewed thoroughly and provided for the closure of the three-field equations. Specific constitutive equations regarding interfacial mass and heat transfer at two interfaces, namely film-gas interface and gas-droplet interface, were reviewed for droplet entrainment and deposition rates as well as film and droplet evaporation rates. Additionally, mechanistic correlations of annular flow film thickness were recommended for the modeling of the thermosyphons without a wick as a critical constitutive correlation. Furthermore, experimental data needs from new experiments using a prototype working fluid or surrogate fluids for the model validation of high-temperature heat pipes in microreactors were recommended for future research.

Accurate predictions of fuel spray behavior and mixture formation in simulations of direct-injection spark-ignition (DISI) engines are fundamental to ensure proper description of all subsequent processes including ignition, combustion, and emissions. In this work, the spray evolution in a single-cylinder optical DISI engine was studied experimentally and numerically with the goal of enabling predictive computational fluid dynamics (CFD) modeling of in-cylinder sprays. The authors explored a wide range of operating conditions characterized by several fuel injection temperatures and engine speeds, using a well-characterized nine-component gasoline surrogate known as PACE-20. The effect of flash boiling and intake crossflow on the spray is discussed, with a focus on evaluating the ability of the spray models to capture highly transient spray behavior. In the experiments, the fuel temperature was varied between 20°C and 80°C, allowing for non-flash- to flash-boiling transition to emerge with enhanced flashing intensity at the highest temperatures. Spray collapse resulted in vapor-rich regions, owing to the locally lower inertia of the fluid. Varying the engine speed from 650 to 1950 rpm promoted increasingly more turbulent in-cylinder crossflow which interacted with the spray during the injection event and resulted in enhanced spray dispersion. The CFD model was able to capture the spray morphology transition at different fuel temperatures and engine speeds adequately. It is shown that the spray breakup model could capture the transitional spray behavior induced by flash boiling atomization and intake flow via proper initialization of the spray cone angle and calibration of the spray models’ constants.

Sustainable electricity generation is one of the major current challenges for our society. In this context, the evolution of nanomaterials and nanotechnologies has enabled the fabrication of microscopic devices to produce clean energy from a great variety of renewable sources. To expand the possibilities of energy generation, we have designed and fabricated bioinorganic generators capable to produce electricity by conversion of chemical energy from renewable fuel sources. Unlike traditional generators, the systems described herein produce mechanical energy through enzyme-driven gas production which generates vibration and pressure that are thus converted into electricity by the action of a piezoelectric component properly integrated into the device. Our generators are able to produce an electric ernergy from different renewable sources like glucose, ethanol, and amino acids, attaining energy outputs around 250 nJ cm–2 and reaching maximum open-circuit voltages of up to 1 V. In addition, the produced energy can be easily regulated by adjusting both enzyme and fuel concentration which can tune the electrical output according to the application. The systems described herein propose a new concept for self-sufficient energy harvesting that bridges biocatalysis and piezoelectricity, where the energy production is based on the piezoelectric effect triggered by enzymatic action rather than on the enzyme-driven electron transfer that governs biofuel cells. Although the electric output is too low yet to be considered an alternative for energy production, this technology opens the door to power small devices. We envision the utilization of this technology in such remote locations where mechanical energy is lacking but there are chemical energy reservoirs. We would like to acknowledge Marie-Curie Actions (NANOBIENER project), IKERBASQUE foundation for funding F.L.-G., and the support of COST Action CM1303 Systems Biocatalysis. We also acknowledge HERGAR foundation for the funding. Peer reviewed

Abstract Fractures along interfaces between host rock and wellbore cement have long been identified as potential CO2 leakage pathways from subsurface CO2 storage sites. As a consequence, cement alteration due to exposure to CO2 has been studied extensively to assess wellbore integrity. Previous studies have focused on the changes to either chemical or mechanical properties of cement upon exposure to CO2-enriched brine, but not on the effects of loading conditions. This paper aims to correct this deficit by considering the combined effects of the fracture pathway and changing effective stress on chemical and mechanical degradation at conditions relevant to geologic carbon storage. Flow-through experiments on fractured cores composed of cement and tight sandstone caprock halves were conducted to study the alteration of cement due to exposure to CO2-enriched brine at 3, 7, 9, and 12 MPa effective stress. We characterized relevant reactions via solution chemistry; fracture permeability via changes to differential pressure; mechanical changes via micro-hardness testing, and pore structure changes via x-ray tomography. This study showed that the nature and the rates of the chemical reactions between cement and CO2 were not affected by the effective stress. The differences in the permeability responses of the fractures were attributed to interactions among the geometry of the flow path, the porosity increase of the reacted cement, and the mechanical deformation of reacted asperities. The suite of observed chemical reactions contributed to change in cement mechanical properties. Compared to the unreacted cement, the average hardness of the amorphous silica and depleted layers was decreased while the hardness of the calcite layer was increased. Tomographic imaging showed that preferential flow paths formed in some of the core-flood experiments, which had a significant impact on the permeability response of the fractured samples. We interpreted the observed permeability responses in terms of competition between dissolution of cement phases (leading to enhanced permeability) and mechanical deformation of reacted regions (leading to reduced permeability).

Abstract This paper uses research-quality, ground measurements of irradiance and temperature that are accurate to ±2% to estimate the electric energy yield of fixed solar modules for utility-scale solar power plants at 18 sites in Saudi Arabia. The calculation is performed for a range of tilt and azimuth angles and the orientation that gives the optimum annual energy yield is determined. A detailed analysis is presented for Riyadh including the impact of non-optimal tilt and azimuth angles on annual energy yield. It is also found that energy yield in March and October are higher than in April and September, due to milder operating temperatures of the modules. A similar optimization of tilt and azimuth is performed each month separately. Adjusting the orientation each month increases energy yield by 4.01% compared to the annual optimum, but requires considerable labour cost. Further analysis shows that an increase in energy yield of 3.63% can be obtained by adjusting the orientation at five selected times during the year, thus significantly reducing the labour requirement. The optimal orientation and corresponding energy yield for all 18 sites is combined with a site suitability analysis taking into account climate, topography and proximity to roads, transmission lines and protected areas. Six sites are selected as having high suitability and high energy yield: Albaha, Arar, Hail, Riyadh, Tabuk and Taif. For these cities the optimal tilt is only slightly higher than the latitude, however the optimum azimuth is from 20° to 53° west of south due to an asymmetrical daily irradiance profile.

The need for an improved control strategy for the operation of a wind-powered refrigeration system for the storage of apples was investigated. The results are applicable to other systems which employ intermittently available power sources, battery and thermal storage, and an auxiliary, direct current power supply. Tests were conducted on the wind-powered refrigeration system at the Virginia Polytechnic Institute and State University Horticulture Research Farm in Blacksburg, Virginia. Tests were conducted on the individual components of the system. In situ windmill performance were also conducted. The results of these tests have been presented. An improved control strategy was developed to improve the utilization of available wind energy and to reduce the need for electrical energy from an external source while maintaining an adequate apple storage environment. Ph. D.

As the concern with global warming increases causing the need for CO2 reduction, renewable energy is of great interest as it has lower carbon footprint when compared to conventional sources (natural gas, coal, oil and nuclear). Solar energy has been drawing worldwide attention since it can transform sunlight directly into electricity with the use of photovoltaic (PV) cells. However, this technology has some drawbacks that need to be addressed including dust deposition on solar panels, also known as soiling. Soiling can decrease PV panel's efficiency thereby resulting in less energy production. The soiling rates are very site specific and depend on the geographic location of the panels and the climate in that area. The solar panels can be cleaned naturally (by rainfall, snow or wind) or mechanically washed. This thesis addresses the impact of solar panel soiling and washing on the energy production of solar PV plants located at the UNLV campus. The objectives of this project were (a) to evaluate whether rainfall alone, in the desert environment with low rainfall, is sufficient to clean up the solar panels, and, if possible, determine the minimum amount of rainfall necessary to clean up panels.; (b) to examine the efficiency loss caused by soiling using different methods of analyses and (c) to evaluate if panel washing is worthwhile given the cost and the efficiency gain that is obtained by washing. To calculate the efficiency of the panels, a model was developed to generate parameters that were not measured at the site. Panel efficiencies before and after rainfall events were compared to determine the minimum amount of rain necessary to clean the panels. It was found that at least 0.2 inches of rain was needed to partially restore clean-panel efficiency. In Las Vegas, the recurrence periods of different depths rainfall were calculated using data from the past 29 years. It was observed that the 50th percentile recurrence period of a rainfall event with depth of 0.2 inches or higher was approximately 52 days. Student Union: -0.0044%/day, CBC-C: -0.00099%/day, and Dayton Hall: -0.0034%/day The amount of efficiency lost during the dry intervals (periods between rainfall events) was analyzed in three different ways. The average efficiency loss per day during the dry periods varied from -0.000171 % to -0.00533 %, depending on the method used and the building where the panels were located. However, there were some limitations to the calculations. It was not possible to completely isolate the effects of only soiling on the efficiency of the panels. The rate of decline seemed to be also impacted by seasonal effects. To better evaluate the effect of washing, a professional company was hired to wash a set of solar panels located on UNLV's Student Union building. The panels were washed with water with a low concentration of TDS. The power output and the efficiency of those panels were analyzed from before and after the washing. There was a very small efficiency and power increase due to the washing. Therefore, it was concluded that washing in this area is not worthwhile, and that rainfall events in excess of 0.2 inches can adequately restore the efficiency of the panels. If there is a change in cost of energy, washing, water or a great increase in the efficiency of the solar panels, it would be necessary to reevaluate the analysis.