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Abstract This paper aims to present a feasibility study of the innovative plant for methanol synthesis from carbon dioxide-sequestered by fossil fuel power plant and hydrogen, which is produced by water electrolyzer employing the over-production on the electrical grid. The thermo-economic analysis is performed in the framework of the MefCO2 H2020 EU project and it is referred to the German economic scenario, properly taking into account the real market costs and cost functions for different components of the plant. Three different plant capacities for methanol production (4000 10,000 and 50,000 ton/year) have been investigated, assuming an average cost for electrical energy to feed electrolysers and analyzing the influence of the most significant parameters (oxygen selling option, methanol selling price and electrolysers’ capital cost) on the profitability of the plant. The analysis has been performed in W-ECoMP, software for the thermo-economic analysis and plant optimization developed by the University of Genoa.

Abstract The price effect of the rising share of renewable electricity, which is called ‘merit-order-effect’, leads to noticeable changes in the German power industry and debates about the electricity market design. This paper estimates the merit-order-effect induced by variable renewable energy in the German-Austrian electricity sector with a multivariate regression model. The research focus lies on the impact of the estimated effects on the marketability of variable renewable electricity generation. The results show a systematic decline of the average market revenues for wind and photovoltaic plants in the period from January 2011 to December 2013. Current market data shows a continuation of this trend into 2016. According to the German long term goals for the use of renewables, wind and solar power will play a crucial role in the future electricity generation mix. If investments in these technologies will be profitable without any regulatory remuneration mechanisms in addition to the market revenues, depends on the further cost degression and the development of the merit-order-effect.

Lithium-ion batteries exhibit a dynamic voltage behaviour depending nonlinearly on current and state of charge. The modelling of lithium-ion batteries is therefore complicated and model parametrisation is often time demanding. Grey-box models combine physical and data-driven modelling to benefit from their respective advantages. Neural ordinary differential equations (NODEs) offer new possibilities for grey-box modelling. Differential equations given by physical laws and NODEs can be combined in a single modelling framework. Here we demonstrate the use of NODEs for grey-box modelling of lithium-ion batteries. A simple equivalent circuit model serves as a basis and represents the physical part of the model. The voltage drop over the resistor–capacitor circuit, including its dependency on current and state of charge, is implemented as a NODE. After training, the grey-box model shows good agreement with experimental full-cycle data and pulse tests on a lithium iron phosphate cell. We test the model against two dynamic load profiles: one consisting of half cycles and one dynamic load profile representing a home-storage system. The dynamic response of the battery is well captured by the model.

Abstract Electricity markets in Europe become increasingly interconnected due to new grid connections and market coupling regulations. This paper examines the interdependencies between the Swiss electricity market and those of neighbouring countries. The Swiss market serves as a good example for a smaller electricity market which is increasingly affected by developments in the large neighbouring countries. To study these cross-border effects, especially those on Swiss electricity prices, we apply two different methodologies, an econometric and a Nash-Cournot equilibrium model. The analyses show that the Swiss electricity price correlates strongly with the German electricity price in the summer, but tends to follow the French electricity price in the winter. Another finding is that gas prices and the electricity load of neighbouring countries have a significant influence on prices. In particular, the load of France and Italy is driving up Swiss prices in the winter, while the German electricity demand and renewable energy generation have a larger influence on Swiss prices in the summer.

Accelerators for heavy-ion inertial fusion energy (HIF) have an economic incentive to fit beam tubes tightly to beams, putting them at risk from electron clouds produced by emission of electrons and gas from walls. Theory and PIC simulations suggest that the electrons will be radially trapped in the /spl ges/1 kV ion-beam potential. We are beginning studies on the High-Current Experiment (HCX) with unique capabilities to characterize electron production and trapping, the effects on ion beams, and mitigation techniques. We are measuring the flux of electrons and gas evolved from a target, whose angle to the beam can be varied between 78/spl deg/ and 88/spl deg/ from normal incidence. Quadrupole magnets are operating with a variety of internal charged particle diagnostics to measure the beam halo loss, net charge, electron ionization rate, and gas density.

In response to the pressing need for transportation decarbonization, this paper examines the often overlooked domain of inland waterway transport and seeks to answer which alternative fuel or power source is the most promising for that sector. As the shipping industry significantly contributes to global carbon emissions, it has been shifting towards alternative fuels and decarbonization measures in the effort to reduce them, whereas the inland waterways, operating predominantly on diesel engines, have not achieved equivalent substantial progress. Employing a systematic literature review and regional analysis, this study identifies notable trends. LNG initially emerged as a favored alternative fuel, but recent studies emphasize a shift towards “greener” solutions like batteries and hydrogen. Europe and Asia lead in these developments. This investigation uncovers critical gaps in research and development, particularly in the Northern European countries that have extensive inland waterway networks. It also calls for future studies to explore the performance of vessels that have adopted LNG compared to other emerging alternatives and emphasizes the importance of considering the time lag between technology development and research publication.

Owing to their high luminous efficiency and tunable emission in both red light and far-red light regions, Mn4+ ion-activated phosphors have appealed significant interest in photoelectric and energy conversion devices such as white light emitting diode (W-LED), plant cultivation LED, and temperature thermometer. Up to now, Mn4+ has been widely introduced into the lattices of various inorganic hosts for brightly red-emitting phosphors. However, how to correlate the structure-activity relationship between host framework, luminescence property, and photoelectric device is urgently demanded. In this review, we thoroughly summarize the recent advances of Mn4+ doped phosphors. Meanwhile, several strategies like co-doping and defect passivation for improving Mn4+ emission are also discussed. Most importantly, the relationship between the protocols for tailoring the structures of Mn4+ doped phosphors, increased luminescence performance, and the targeted devices with efficient photoelectric and energy conversion efficiency is deeply correlated. Finally, the challenges and perspectives of Mn4+ doped phosphors for practical applications are anticipated. We cordially anticipate that this review can deliver a deep comprehension of not only Mn4+ luminescence mechanism but also the crystal structure tailoring strategy of phosphors, so as to spur innovative thoughts in designing advanced phosphors and deepening the applications.

We study the role of technology subsidies in climate policies, using a simple dynamic equilibrium model with learning-by-doing. The optimal subsidy rate of a carbon-free technology is high when the technology is first adopted, but falls significantly over the next decades. However, the efficiency costs of uniform instead of optimal subsidies, may be low if there are introduction or expansion constraints for a new technology. Finally, supporting existing energy technologies only, may lead to technology lock-in, and the impacts of lock-in increase with the learning potential of new technologies as well as the possibilities for early entry and thight carbon constraints.