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AbstractLichtablenkungseffekte können bei der interferometrischen Beobachtung von Grenzschichten zu großen Fehlern bei der Ableitung der Konzentrationsprofile führen, sofern nicht Korrekturen bei der Interpretation vorgenommen werden.

Abstract. The impact of multiphase reactions involving nitrogen dioxide (NO2) and aromatic compounds was simulated in this study. A mechanism (CAPRAM 2.4, MODAC Mechanism) was applied for the aqueous phase reactions, whereas RACM was applied for the gas phase chemistry. Liquid droplets were considered as monodispersed with a mean radius of 0.1 µm and a liquid content (LC) of 50 µg m-3. The multiphase mechanism has been further extended to the chemistry of aromatics, i.e. reactions involving benzene, toluene, xylene, phenol and cresol have been added. In addition, reaction of NO2 with dissociated hydroxyl substituted aromatic compounds has also been implemented. These reactions proceed through charge exchange leading to nitrite ions and therefore to nitrous acid formation. The strength of this source was explored under urban polluted conditions. It was shown that it may increase gas phase HONO levels under some conditions and that the extent of this effect is strongly pH dependent. Especially under moderate acidic conditions (i.e. pH above 4) this source may represent more than 75% of the total HONO/NO2 - production rate, but this contribution drops down close to zero in acidic droplets (as those often encountered in urban environments).

Abstract In this paper I present findings and insights from an empirical study of two case study solar farm developments from rural areas of the South West, UK. Drawing on a Habermasian theoretical frame, I examine local resident narratives that emerged through the local public sphere and how these formed discursive meanings that provided shared background social norms for residents towards the solar farm developments. The paper begins by operationalising Habermas's theoretical ideas for empirical research and situating the research within existing literature. The theoretical and methodological sections are followed by the examination of three local narratives that emerged: idealised rural land use, farming and income generation, and money making and the pursuit of profit. Such narratives are considered in view of public opportunities for robust dialogue and debate to judge the normative democratic character of the solar farm developments. The paper concludes that the community development offered significantly more discursive space for debate than the commercial development and increased the developments' overall democratic legitimacy. It is maintained that such a Habermasian theoretical frame adapted for empirical analysis is valuable for normatively assessing democratic processes which are needed in view of conceptually weak accounts of ‘energy democracy’.

A promising technology for renewable energy is energy piles used to heat and cool buildings. In this research, the effects of bio-cementation via microbially induced calcite precipitation (MICP) using mixed calcium and magnesium sources and the addition of fibres on the thermal conductivity of soil were investigated. Firstly, silica sand specimens were treated with cementation solutions containing different ratios of calcium chloride and magnesium chloride to achieve maximum thermal conductivity improvement. Three treatment cycles were provided, and the corresponding thermal conductivity was measured after each cycle. It was found that using 100% calcium chloride resulted in the highest thermal conductivity. This cementation solution was then used to treat bio-cemented soil samples containing fibres, including polyethylene, steel and glass fibres. The fibre contents used included 0.5%, 1.0% and 1.5% of the dry sand mass. The results show that the glass fibre samples yielded the highest thermal conductivity after three treatment cycles, and SEM imaging was used to support the findings. This research suggests that using MICP as a soil improvement technique can also improve the thermal conductivity of soil surrounding energy piles, which has high potential to effectively improve the efficiency of energy piles.

We have investigated the microelectrical properties of CdTe thin films using scanning Kelvin probe force microscopy (SKPFM) and scanning spreading resistance microscopy (SSRM). Two films with the configurations of substrate and superstrate were subjected to the characterization studies. The electrical potential and resistance were properly mapped with the substrate film but not with the superstrate film because the underlying CdS/CdTe junction largely impacted the characterizations. The higher SKPFM potential on grain boundaries (GBs) of the substrate film than on the grain surface indicates positively charged GBs and upward band bending around the GB; therefore, the GBs are either depleted or inverted. The SSRM resistance mapping on this film shows nonuniformities and features that are associated with the grain structure and facets. However, the GBs do not exhibit distinct characteristic resistance. Comparing the low resistance channel along the GBs of high-performance CIGS films, the SSRM mapping of CdTe supports depletion of the GBs. In SSRM measurement, it is critical to adequately indent the probe to the film, and to apply a bias voltage larger than the onset voltage of the probe/film barrier, so that the contact resistance is minimized and that the local spreading resistance of CdTe film beneath the probe is measured.

Chromium (Cr) exposure during gestation causes malformations in animal experiments. In this multicenter case-control study, we initially involved 130 orofacial clefts (OFCs) and 260 controls to assess the association between Cr concentration and risk for OFCs. Then, umbilical cord serum (49 vs. 119) and cord tissue (84 vs. 142) were used to validate the association between Cr and OFCs. We found that maternal serum Cr concentrations in OFC cases were significantly higher than those in controls. Compared with the lowest tertile of maternal serum Cr concentration, the highest tertile of Cr increased the risk for OFCs [OR = 2.14 (1.14-4.05)]. In the validation cohort of umbilical cord serum and tissue, higher concentrations of Cr were associated with increased risks for OFCs in a dose-dependent manner (all Ps for trends <0.05). Cr concentrations in maternal serum and cord serum showed a positive correlation. The Cr concentration in cord serum was inversely correlated with egg and milk consumption frequencies, and the Cr concentration in cord tissue was positively associated with indoor coal burning. In conclusion, prenatal Cr exposure is a risk factor for OFCs, and indoor coal burning during pregnancy may be one of the sources of Cr exposure.