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The need for an improved control strategy for the operation of a wind-powered refrigeration system for the storage of apples was investigated. The results are applicable to other systems which employ intermittently available power sources, battery and thermal storage, and an auxiliary, direct current power supply. Tests were conducted on the wind-powered refrigeration system at the Virginia Polytechnic Institute and State University Horticulture Research Farm in Blacksburg, Virginia. Tests were conducted on the individual components of the system. In situ windmill performance were also conducted. The results of these tests have been presented. An improved control strategy was developed to improve the utilization of available wind energy and to reduce the need for electrical energy from an external source while maintaining an adequate apple storage environment. Ph. D.

The need for an improved control strategy for the operation of a wind-powered refrigeration system for the storage of apples was investigated. The results are applicable to other systems which employ intermittently available power sources, battery and thermal storage, and an auxiliary, direct current power supply. Tests were conducted on the wind-powered refrigeration system at the Virginia Polytechnic Institute and State University Horticulture Research Farm in Blacksburg, Virginia. Tests were conducted on the individual components of the system. In situ windmill performance were also conducted. The results of these tests have been presented. An improved control strategy was developed to improve the utilization of available wind energy and to reduce the need for electrical energy from an external source while maintaining an adequate apple storage environment. Ph. D.

Green ammonia is gaining momentum as a globally significant technology for deep decarbonisation. In this thesis, several models are developed across chemical, techno-economic, and energy system modelling disciplines to explore the future role of green ammonia. First, standalone models of production (i.e., power-to-ammonia) and re-electrification (i.e., ammonia-to-power) are developed and compared to competing technologies. Second, these models are integrated into a planning and dispatch energy system model (ESM) of India to 2050. The ESM has several novel additions including the sector coupling of hydrogen and ammonia, multiple years of granular weather data, and learning-curve-based technology cost forecasts. India is chosen as an ideal case study given its globally unmatched demand growth in all three relevant sectors: electricity, green hydrogen, and green ammonia. The projected electricity demands for green hydrogen and ammonia production account for 25% of the total Indian electricity demand in 2050, underscoring the transformational potential that green hydrogen and ammonia sector coupling can have on the Indian energy system. The results of the state-of-the-art ESM highlight synergistic effects of hydrogen and ammonia sector coupling with the power system. The least-cost system employs seasonal green ammonia production paired with up to 40 million tonnes (i.e., 200 TWh) of ammonia storage, as well as some re-electrification via gas turbines. Sector coupling reduces system curtailment, addresses challenges of long-duration storage, and improves system resilience to interannual weather variations. While India is a crucial case study from a global decarbonisation perspective, the methodology and findings are generally applicable, and it is the aim of this work to motivate and accelerate the wider research community into considering the potential impacts of green ammonia sector coupling on electricity grid design. Finally, this work highlights strategic technology development direction for ammonia producers and gas turbine manufacturers, as well as implications for policymakers.

Green ammonia is gaining momentum as a globally significant technology for deep decarbonisation. In this thesis, several models are developed across chemical, techno-economic, and energy system modelling disciplines to explore the future role of green ammonia. First, standalone models of production (i.e., power-to-ammonia) and re-electrification (i.e., ammonia-to-power) are developed and compared to competing technologies. Second, these models are integrated into a planning and dispatch energy system model (ESM) of India to 2050. The ESM has several novel additions including the sector coupling of hydrogen and ammonia, multiple years of granular weather data, and learning-curve-based technology cost forecasts. India is chosen as an ideal case study given its globally unmatched demand growth in all three relevant sectors: electricity, green hydrogen, and green ammonia. The projected electricity demands for green hydrogen and ammonia production account for 25% of the total Indian electricity demand in 2050, underscoring the transformational potential that green hydrogen and ammonia sector coupling can have on the Indian energy system. The results of the state-of-the-art ESM highlight synergistic effects of hydrogen and ammonia sector coupling with the power system. The least-cost system employs seasonal green ammonia production paired with up to 40 million tonnes (i.e., 200 TWh) of ammonia storage, as well as some re-electrification via gas turbines. Sector coupling reduces system curtailment, addresses challenges of long-duration storage, and improves system resilience to interannual weather variations. While India is a crucial case study from a global decarbonisation perspective, the methodology and findings are generally applicable, and it is the aim of this work to motivate and accelerate the wider research community into considering the potential impacts of green ammonia sector coupling on electricity grid design. Finally, this work highlights strategic technology development direction for ammonia producers and gas turbine manufacturers, as well as implications for policymakers.

The 2022 World Cup organised by the International Association Football Federation (International Olympic Committee, 2021) and hosted by Qatar was billed to be the tournament that would completely revolutionise football, both on and off the field. It garnered acclaim in being the first World Cup held outside its customary months of June-July as well as in pioneering net zero carbon emissions in the sport - an assertion that ultimately proved largely unfounded(Ralston, 2022) with high reputational consequences for the country and the game. Non-governmental organisations (NGOs), like the Carbon Market Watch that works with the European Union amongst others, claimed that “carbon emissions created by the new stadiums could be as much as eight times higher than the figures contained in Qatar’s analysis” (MacInnes, 2022). Against the backdrop of mounting sustainability concerns expressed by policymakers and enthusiasts alike, this essay examines the environmental hazards associated with major sporting events, like the 2022 FIFA World Cup whilst delving into adaptations that organisers could make for future sporting bonanzas that would give their green aspirations wings that could fly without getting burned like the fabled Icarus whose own pride and arrogance led him to ignore the rising temperatures and ultimately cause his demise. Essex Student Journal Volume 14 Issue S1 2023

The 2022 World Cup organised by the International Association Football Federation (International Olympic Committee, 2021) and hosted by Qatar was billed to be the tournament that would completely revolutionise football, both on and off the field. It garnered acclaim in being the first World Cup held outside its customary months of June-July as well as in pioneering net zero carbon emissions in the sport - an assertion that ultimately proved largely unfounded(Ralston, 2022) with high reputational consequences for the country and the game. Non-governmental organisations (NGOs), like the Carbon Market Watch that works with the European Union amongst others, claimed that “carbon emissions created by the new stadiums could be as much as eight times higher than the figures contained in Qatar’s analysis” (MacInnes, 2022). Against the backdrop of mounting sustainability concerns expressed by policymakers and enthusiasts alike, this essay examines the environmental hazards associated with major sporting events, like the 2022 FIFA World Cup whilst delving into adaptations that organisers could make for future sporting bonanzas that would give their green aspirations wings that could fly without getting burned like the fabled Icarus whose own pride and arrogance led him to ignore the rising temperatures and ultimately cause his demise. Essex Student Journal Volume 14 Issue S1 2023

In the pursuit of creating efficient CdTe p-n homojunctions, we developed iodine (I) n-type doped CdTe using Cadmium Iodide (CdI2) as a dopant in varying concentrations (1018 cm-3, 1019 cm-3 and 1020 atoms·cm-3 target concentrations) in CdTe. Iodide doped crystals were grown using a Modified Vertical Bridgman furnace (MVB). Single crystals were characterized using XRD (X-Ray Diffraction), Hall effect, IR (Infrared) Microscopy, UV-VIS-NIR (Ultraviolet-Visible-Near infrared Spectroscopy) and FTIR (Fourier Transform Infrared Spectroscopy). Partners at the National Renewable Energy Laboratory (NREL) also provided data for Hall Effect and Two Photon Excitation Time Resolved Photoluminescence (2PE TRPL) of wafers and films. Photoluminescence mapping (PL mapping) was obtained from Klar scientific, and glow discharge mass spectrometry (GDMS) for purity and final doping concentration was obtained from the National Research Council Canada. Due to poor carrier properties in the crystals as-grown, two annealing treatments were explored, in either tellurium or cadmium vapor. Homojunctions were made at NREL by depositing n-type films from these crystals on p-type single crystals, CdTe:P grown and WSU. The n-type films were created using the close-space sublimation epitaxy (CSSE) process. Herein is reported the results of the grown CdTe:I crystals and, to a lesser extent, the properties of the CdTe:I thin films formed by CSSE.

In the pursuit of creating efficient CdTe p-n homojunctions, we developed iodine (I) n-type doped CdTe using Cadmium Iodide (CdI2) as a dopant in varying concentrations (1018 cm-3, 1019 cm-3 and 1020 atoms·cm-3 target concentrations) in CdTe. Iodide doped crystals were grown using a Modified Vertical Bridgman furnace (MVB). Single crystals were characterized using XRD (X-Ray Diffraction), Hall effect, IR (Infrared) Microscopy, UV-VIS-NIR (Ultraviolet-Visible-Near infrared Spectroscopy) and FTIR (Fourier Transform Infrared Spectroscopy). Partners at the National Renewable Energy Laboratory (NREL) also provided data for Hall Effect and Two Photon Excitation Time Resolved Photoluminescence (2PE TRPL) of wafers and films. Photoluminescence mapping (PL mapping) was obtained from Klar scientific, and glow discharge mass spectrometry (GDMS) for purity and final doping concentration was obtained from the National Research Council Canada. Due to poor carrier properties in the crystals as-grown, two annealing treatments were explored, in either tellurium or cadmium vapor. Homojunctions were made at NREL by depositing n-type films from these crystals on p-type single crystals, CdTe:P grown and WSU. The n-type films were created using the close-space sublimation epitaxy (CSSE) process. Herein is reported the results of the grown CdTe:I crystals and, to a lesser extent, the properties of the CdTe:I thin films formed by CSSE.

{"references": ["U.S. Energy Information Administration. \"How much energy is\nconsumed in residential and commercial buildings in the United States?\"\nAvailable at: http://www.eia.gov/tools/faqs/faq.cfm?id=86&t=1", "S. Darby, \"The effectiveness of feedback on energy consumption.\"\nEnvironmental Change Institute, University of Oxford, 2006. Available\nat: http://www.globalwarmingisreal.com/energyconsump-feedback.pdf.\nVisited: September 2015", "J. S. John, \"Putting energy disaggregation tech to the test,\" November,\n2013. Greentech Media. Available at:\nhttp://www.greentechmedia.com/articles/read/putting-energydisaggregation-tech-to-the-test.\nVisited: September 2015", "A. Zoha, A. Gluhak, M. A. Imran, S. Rajasegarar, \"Non-intrusive load\nmonitoring approaches for disaggregated energy sensing: a survey,\"\nSensors, vol. 12, no. 12, pp. 16838-16866, December 2012.", "G. W. Hart, \"Nonintrusive appliance load monitoring,\" in Proc. of the\nIEEE, vol. 80, pp. 1870-1891, December 1992.", "M. Baranski, J. Voss, \"Non-intrusive appliance load monitoring based\non Optical Sensor,\" IEEE Bologna PowerTech Conference, Bologna,\nItaly, June 2003. Available at:\nhttp://ieeexplore.ieee.org/stamp/stamp.jsp?tp=&arnumber=1304732", "L. Farinaccio, R. Zmeureanu, \"Using a pattern recognition approach to\ndisaggregate the total electricity consumption in a house into the major\nen-uses,\" Elsevier, Energy and Buildings, vol. 30, no. 3, pp. 245-259,\nAugust 1999.", "J. M. Abreu, F. C. Pereira, P. Ferr\u00e3o, \"Using pattern recognition to\nidentify habitual behavior in residential electricity consumption,\"\nElsevier, Energy and Buildings, vol. 49, pp. 479-487, June 2012.", "C. Beckel, L. Sadamori, S. Santini, \"Automatic socio-economic\nclassification of households using electricity consumption data,\" in\nProc. of the 4th international conference on future energy systems, New\nYork, 2013, pp. 75-86.\n[10] H. Zhao, F. Magoul\u00e8s, \"A review on the prediction of building energy\nconsumption,\" Elsevier, Renewable and Sustainable Energy Reviews,\nvol. 16, no. 6, pp. 3586-3592, August 2012.\n[11] G. K. F. Tso, K. K. W. Yau, \"Predicting electricity energy consumption:\nA comparison of regression analysis, decision tree and neural networks,\"\nElsevier, Energy, vol. 32, no. 9, pp. 1761-1768, September 2007.\n[12] F. Farzan, S. A. Vaghefi, K. Mahani, M. A. Jafari, J. Gong, \"Operational\nplanning for multi-building portfolio in an uncertain energy market,\"\nElsevier, Energy and Buildings, vol. 103, pp. 271-283, September 2015."]} Energy disaggregation has been focused by many energy companies since energy efficiency can be achieved when the breakdown of energy consumption is known. Companies have been investing in technologies to come up with software and/or hardware solutions that can provide this type of information to the consumer. On the other hand, not all people can afford to have these technologies. Therefore, in this paper, we present a methodology for breaking down the aggregate consumption and identifying the highdemanding end-uses profiles. These energy profiles will be used to build the forecast model for optimal control purpose. A facility with high cooling load is used as an illustrative case study to demonstrate the results of proposed methodology. We apply a high level energy disaggregation through a pattern recognition approach in order to extract the consumption profile of its rooftop packaged units (RTUs) and present a forecast model for the energy consumption.