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Abstract Adsorbent-based carbon capture is only feasible if adsorption-desorption cycles are both fully regenerating and efficient. This work proposes a regenerative pH swing process and a pH swing regenerative adsorbent that are inspired by natural CO2 conversion by carbonic anhydrase biocatalysts found in mammalian red blood cells. The main objective is to develop, test and analyze a synthetic pH Swing Adsorption (pHSA) system as well as a pHSA compatible solid adsorbent to capture CO2 from a simulated ambient air gas stream. The lead developed adsorbent is a carbon black co-activated with potassium carbonate and nitrogenous copolymer that is impregnated with immobilized bovine carbonic anhydrase and thereby deemed “BCA/KN-CB”. BCA/KN-CB has preliminarily demonstrated both competitive CO2 adsorption capacity and limited regenerative ability under experimental pHSA conditions. In addition, BCA-based adsorbents achieved higher adsorption capacities than non-BCA adsorbent counterparts. The BCA/KN-CB adsorbent displayed both large point of zero charge (PZC) swings and regenerative stability. The proposed pHSA system requires essentially zero energy expenditure to achieve intended environments for capture and regeneration. With 1 kg of adsorbent, pHSA has the ability to capture 1 kg CO2 in less than 4 h of cycling. The tested pHSA adsorbent can also capture more than 96% of total CO2 in a given raw gas stream flowing through the capture chamber. This proof-of-concept study of a pH swing adsorption/biocatalytic adsorbent system suggests the potential to effectively operate under ambient conditions and exhibit advantageous operational efficiencies to other high-profile CO2 capture systems.

The use of hydrogen gas as a means of decoupling supply from demand is crucial for the transition to carbon-neutral energy sources and a greener, more distributed energy landscape. This work shows how simple commercially available titanium nitride coatings can be used to extend the lifetime of 316 grade stainless-steel electrodes for use as the cathode in an alkaline electrolysis cell. The material was subjected to accelerated ageing, with the specific aim of assessing the coating’s suitability for use with intermittent renewable energy sources. Over 2000 cycles lasting 5.5 days, an electrolytic cell featuring the coating outperformed a control cell by 250 mV, and a reduction of overpotential at the cathode of 400 mV was observed. This work also confirms that the coating is solely suitable for cathodic use and presents an analysis of the surface changes that occur if it is used anodically.

AbstractA novel multifunctional conjugated polymer (RCP‐1) composed of an electron‐donating backbone (carbazole) and an electron‐accepting side chain (cyanoacetic acid) connected through conjugated vinylene and terthiophene has been synthesized and tested as a photosensitizer in two major molecule‐based solar cells, namely dye sensitized solar cells (DSSCs) and organic photovoltaic cells (OPVs). Promising initial results on overall power conversion efficiencies of 4.11% and 1.04% are obtained from the basic structure of DSSCs and OPVs based on RCP‐1, respectively. The well‐defined donor (D)‐acceptor (A) structure of RCP‐1 has made it possible, for the first time, to reach over 4% of power conversion efficiency in DSSCs with an organic polymer sensitizer and good operation stability.

Abstract Specification by central government of the heating levels which are to be maintained in British school buildings has recently been altered. This paper is concerned with examining the nature of changes that have been made by comparing present requirements with their counterparts during the preceding one hundred years. Attention is focused on the apparently contradictory implications of these changes for those charged with responsibility for maintaining heating levels in school buildings while, at the same time, conserving fuel. It is suggested that the new statutory requirements present those who are responsible with a duty which may, in practical terms, prove difficult or costly to discharge. Although discussion is specifically restricted to British school buildings, issues are raised which are pertinent to attempts to integrate regulation of heating with control of fuel consumption in other types of non-domestic buildings both in Britain and abroad.

Abstract The need to increase energy system flexibility, alongside the need to lower fossil fuel use in the food sector, and the importance of refrigeration infrastructure presents an opportunity for Liquid Air Energy Storage (LAES) integrated with refrigerated warehouses. To quantify this opportunity in Europe we analyse energy scenarios and existing refrigeration infrastructure for four countries with diverse energy systems (UK, Spain, Bulgaria and Germany). We find that with growing levels of electricity generation from variable renewable sources and numerous refrigerated warehouses, LAES has the potential to provide value in many areas of the EU through the 2020s. However, LAES is still pre-commercial, and with the proportion of electricity from variable renewable sources still low in many countries it is likely that LAES will not be deployed widely alongside refrigerated warehouses under current market conditions. Countries such as the UK and Spain, which have the greatest need for additional energy system flexibility and the most refrigerated warehouses are likely to gain the most value initially.

Abstract The residual biomass of Cupriavidus necator , a biopolyester-producing bacterium, was liquefied in subcritical water at 300 °C. The hydrophobic organic compounds, accounting for about 45% carbon of the original biomass, were recovered with methylene dichloride for analysis. The organic compounds included hydrocarbons such as long chain alkane and benzene, and nitrogen-containing heterocycles such as pyrroles and indoles. The liquid had the similar elemental composition (C, H, O, N) and high heating value (34 MJ kg −1 HHV) of the bio-oils derived from microalgae biomass.

In order to reliably simulate the energy yield of photovoltaic (PV) systems, it is necessary to have an accurate model of how the PV modules perform with respect to irradiance and cell temperature. Building on previous work that addresses the irradiance dependence, two approaches to fit the temperature dependence of module power in PVsyst have been developed and are applied here to recent multi-irradiance and -temperature data for a standard Yingli Solar PV module type. The results demonstrate that it is possible to match the measured irradiance and temperature dependence of PV modules in PVsyst. As a result, improvements in energy yield prediction using the optimized models relative to the PVsyst standard model are considered significant for decisions about project financing.

Abstract In the last decade, there has been a growing trend towards flexible body wave energy converters (WECs) enabled by rubber-like elastomeric composite membrane structures that can simplify all aspects of WEC design. Currently, there are few literature studies detailing the implementations of membranes into WEC design. This paper aims to overcome this by reviewing the developments, material selection and modelling procedures for novel membrane based wave energy converters (mWECs), providing the reader with a comprehensive overview of the current state of the technology. In the first half of this paper, all of the possible WEC implementation areas are reviewed which include the primary mover, power take-off (PTO) and other sub-assembly systems. For the primary mover, the review has identified three main working surface approaches using membranes, these are: air-filled cells, water filled tubes and tethered carpets; which aim to reduce peak loads for enhanced reliability and survivability. In other areas, the PTO of WECs can benefit from using soft dielectric elastomer generators (DEGs) which offer a simpler designs compared with conventional mechanical turbomachinery. These have been implemented into the membrane working surface as well as replacing the PTO in existing WEC architectures. In the second half of the paper, a discussion is made on the material selection requirements with a few possible compositions presented. Following this, the potential modelling procedures for these devices is detailed. The device numerical models have altered existing procedures to take into account the non-linearities caused by the membrane interface and membrane PTO damping.