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Abstract Levee systems are an important part of California’s water infrastructure, engineered to provide resilience against flooding and reduce flood losses. The growth in California is partly associated with costly infrastructure developments that led to population expansion in the levee protected areas. Therefore, potential changes in the flood hazard could have significant socioeconomic consequences over levee protected areas, especially in the face of a changing climate. In this study, we examine the possible impacts of a warming climate on flood hazard over levee protected land in California. We use gridded maximum daily runoff from global circulation models (GCMs) that represent a wide range of variability among the climate projections, and are recommended by the California’s Fourth Climate Change Assessment Report, to investigate possible climate-induced changes. We also quantify the exposure of several critical infrastructure protected by the levee systems (e.g. roads, electric power transmission lines, natural gas pipelines, petroleum pipelines, and railroads) to flooding. Our results provide a detailed picture of change in flood risk for different levees and the potential societal consequences (e.g. exposure of people and critical infrastructure). Levee systems in the northern part of the Central Valley and coastal counties of Southern California are likely to observe the highest increase in flood hazard relative to the past. The most evident change is projected for the northern region of the Central Valley, including Butte, Glenn, Yuba, Sutter, Sacramento, and San Joaquin counties. In the leveed regions of these counties, based on the model simulations of the future, the historical 100-year runoff can potentially increase up to threefold under RCP8.5. We argue that levee operation and maintenance along with emergency preparation plans should take into account the changes in frequencies and intensities of flood hazard in a changing climate to ensure safety of levee systems and their protected infrastructure.

In this study, levulinic acid (LA) was produced from rice straw biomass in co-solvent biphasic reactor system consisting of hydrochloric acid and dichloromethane organic solvent. The modified protocol achieved a 15% wt LA yield through the synergistic effect of acid and acidic products (auto-catalysis) and the designed system allowed facile recovery of LA to the organic phase. Further purification of the resulting extractant was achieved through traditional column chromatography, which yielded a high purity LA product while recovering ∼85% wt. Upon charcoal treatment of the resultant fraction generated an industrial grade target molecule of ∼99% purity with ∼95% wt recovery. The system allows the solvent to be easily recovered, in excess of 90%, which was shown to be able to be recycled up to 5 runs without significant loss of final product concentrations. Overall, this system points to a method to significantly reduce manufacturing cost during large-scale LA preparation.

This article examines land-use, market and welfare implications of lignocellulosic bioethanol production in Hawaii to satisfy 10% and 20% of the State's gasoline demand in line with the State's ethanol blending mandate and Alternative Fuels Standard (AFS). A static computable general equilibrium (CGE) model is used to evaluate four alternative support mechanisms for bioethanol. Namely: (i) a federal blending tax credit, (ii) a long-term purchase contract, (iii) a state production subsidy financed by a lump-sum tax and (iv) a state production subsidy financed by an ad valorem gasoline tax. We find that because Hawaii-produced bioethanol is relatively costly, all scenarios are welfare reducing for Hawaii residents: estimated between -0.14% and -0.32%. Unsurprisingly, Hawaii.s economy and its residents fair best under the federal blending tax credit scenario, with a positive impact to gross state product of $49 million. Otherwise, impacts to gross state product are negative (up to -$63 million). We additionally find that Hawaii-based bioethanol is not likely to offer substantial greenhouse gas emissions savings in comparison to imported biofuel, and as such the policy cost per tonne of emissions displaced ranges between $130 to $2,100/tonne of CO2e. The policies serve to increase the value of agricultural lands, where we estimate that the value of pasture land could increase as much as 150% in the 20% AFS scenario.

The focus of this research lies on fundamental research to provide guidelines for the design of new nanocatalyst toward improvement of the performance of proton exchange membrane fuel cells (PEMFCs). To achieve this overarching goal, several specific steps were taken with aims to: (1) provide guidelines for the design of new catalysts; (2) promote nanocatalyst applications towards alternative energy applications; and (3) integrate advanced instrumentation into nanocharacterization and fuel cell (FC) electrochemical behavior. In tandem with these goals, the cathode catalysts were extensively refined to improve the performance of PEMFCs and minimize noble metal usage. In this study, the major accomplishment was producing aligned carbon nanotubes (ACNTs), which were then modified by platinum (Pt) nanoparticles via a post-functionalization colloidal chemistry approach. The Pt-ACNTs demonstrated improved cathodic catalycity, by building better device endurance and decreased Pt loading. It was also determined that surface mechanical properties, such as elastic modulus and hardness were increased. Collectively, these enhancements provided an improved FC device. The electrochemical analyses indicated that the power density of the PEMFCs was increased to 900 mW/cm2 and current density to 3000 mA/cm2, respectively. The Pt loading was controlled at lower than 0.2 mg/cm2 to decrease the manufacturing expenses.

Abstract Heat pipes and two-phase thermosyphons are highly efficient heat transfer devices utilizing continuous evaporation and condensation of working fluid for two-phase heat transport in closed systems. Because of the nearly isothermal and fully passive phase-change heat transfer mechanism, heat pipes and thermosyphons have found many applications in nuclear engineering, space technologies, and other energy systems. High-temperature heat pipes are used in nuclear microreactors to remove fission power from the primary system and are coupled with power conversion systems or process heat applications. Modeling of the two-phase flow phenomena inside a heat pipe is essential to its design and safety analysis. In this study, a comprehensive one-dimensional two-phase three-field flow model has been developed for the analysis of heat pipes in normal operation conditions and transients. The conservation or field equations of mass, momentum, and energy were developed for the liquid film, vapor, and droplet. In addition, constitutive models or correlations were reviewed thoroughly and provided for the closure of the three-field equations. Specific constitutive equations regarding interfacial mass and heat transfer at two interfaces, namely film-gas interface and gas-droplet interface, were reviewed for droplet entrainment and deposition rates as well as film and droplet evaporation rates. Additionally, mechanistic correlations of annular flow film thickness were recommended for the modeling of the thermosyphons without a wick as a critical constitutive correlation. Furthermore, experimental data needs from new experiments using a prototype working fluid or surrogate fluids for the model validation of high-temperature heat pipes in microreactors were recommended for future research.

The coupling of water-splitting catalysts to silicon photovoltaics enables direct solar-to-fuel conversion. Critical to the performance of such devices is the use of interfaces to protect silicon from the oxygen-evolving reaction (OER) and at the same time to provide Ohmic contact between the buried silicon junction and the immobilised OER catalyst. Presented herein are guidelines for constructing the Si|catalyst interface, which is a crucial building block for efficient direct solar-to-fuel conversion devices. We show that fluorinated-tin-oxide is an especially attractive interface for buried-junction devices.

Global wind resources greatly exceed current electricity demand and the levelized cost of energy from wind turbines has shown precipitous declines. Accordingly, the installed capacity of wind turbines grew at an annualized rate of about 14% during the last two decades and wind turbines now provide ~6–7% of the global electricity supply. This renewable electricity generation source is thus already playing a role in reducing greenhouse gas emissions from the energy sector. Here we document trends within the industry, examine projections of future installed capacity increases and compute the associated climate change mitigation potential at the global and regional levels. Key countries (the USA, UK and China) and regions (e.g., EU27) have developed ambitious plans to expand wind energy penetration as core aspects of their net-zero emissions strategies. The projected climate change mitigation from wind energy by 2100 ranges from 0.3–0.8 °C depending on the precise socio-economic pathway and wind energy expansion scenario followed. The rapid expansion of annual increments to wind energy installed capacity by approximately two times current rates can greatly delay the passing of the 2 °C warming threshold relative to pre-industrial levels. To achieve the required expansion of this cost-effective, low-carbon energy source, there is a need for electrification of the energy system and for expansion of manufacturing and installation capacity.

AbstractA novel multifunctional conjugated polymer (RCP‐1) composed of an electron‐donating backbone (carbazole) and an electron‐accepting side chain (cyanoacetic acid) connected through conjugated vinylene and terthiophene has been synthesized and tested as a photosensitizer in two major molecule‐based solar cells, namely dye sensitized solar cells (DSSCs) and organic photovoltaic cells (OPVs). Promising initial results on overall power conversion efficiencies of 4.11% and 1.04% are obtained from the basic structure of DSSCs and OPVs based on RCP‐1, respectively. The well‐defined donor (D)‐acceptor (A) structure of RCP‐1 has made it possible, for the first time, to reach over 4% of power conversion efficiency in DSSCs with an organic polymer sensitizer and good operation stability.