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The diffusivity and solubility of fluorine in solid nickel were determined using the following solid-state electrochemical cells: Co + CoF2| BaF2| Ni | BaF2| Co + CoF2 Co + CoF2| CaF2| BaF2| Ni | BaF2| CaF2| Co + CoF2 In the temperature range 1023 to 1223 K, the diffusion coefficient of fluorine in solid nickel is given by: 1 $$D_F (cm^2 /s) = (2.13_{ - 1.54}^{ + 5.54} ) \times 10^{ - 3} \exp (( - 118,600 \pm 12,000J/mol)/RT)$$ The dissolution of atomic fluorine in solid nickel obeys Sieverts’ law; however, the solubility results showed considerable scatter. In the temperature range 1073 to 1223 K, the mean solubility of fluorine in solid nickel, corresponding to the equilibrium Ni + NiF2, follows the relationship: N -F S (at. pct) = 5.73 x 10-3 exp((10,850 J/mol)/RT)

Abstract Flow behavior of particles in a two-dimensional spouted bed with a draft tube is studied using a continuous kinetic-friction stresses model. The kinetic stress of particles is predicted from kinetic theory of granular flow, while the friction stress is computed from a model proposed by Johnson et al. (1990) . A stitching function is used to smooth from the rapid shearing viscous regime to the slow shearing plastic regime. The distributions of concentration and velocities of particles are predicted in the spouted bed with a draft tube. Simulated results compare with the vertical velocity of particles ( Zhao et al., 2008 ) measured and in the spout bed with draft plates and solid circulation rate ( Ishikura et al., 2003 ) measured in the spouted bed with a draft tube. The impact of the friction stress of particles on the spout, annulus, fountain and entrancement regions is analyzed in gas–solid spouted bed with a draft tube. Numerical results show that the gas flow rate through the annulus increases with the increase of the entrainment zone. The solids circulation rate decreases with the decrease of inlet gas velocity and the height of the entrainment zone. The effect of spouting gas velocity on distributions of concentration, velocity and particle circulation is discussed.

Abstract With promising benefits such as traffic emission reduction, traffic congestion alleviation, and parking problem solving, Electric Vehicle (EV)-sharing systems have attracted large attentions in recent years. Different from other business modes, customers in sharing economy systems are usually price sensitive. Therefore, it is possible to shift the usage of shared EVs through a well-designed Dynamic Pricing Scheme (DPS), with the objective of maximizing the system operator's total profit. In this study, we propose a novel DPS for a large-scale EV-sharing network to address the EV unbalancing issue and satisfy the vehicle-grid-integration (VGI) service based on accurate station-level demand prediction. The proposed DPS is formulated as a complex optimization problem, which includes two Price Adjustment Level (PAL) decision variables for every origin-destination pair of stations. The two PALs are employed to affect the EV-sharing demand and travel time between each station pair, respectively. Physical and operational constraints from both EV demand and VGI service aspects are also included in the proposed model. Two case study are conducted to validate the effectiveness of the proposed method.

Abstract The combination of biomass gasification with fuel cells, especially high temperature Solid Oxide Fuel Cells (SOFCs) promises sustainable and highly efficient (decentralized and modular) energy conversion systems. This review encompasses the components of biomass integrated gasification–SOFC technology including biomass characteristics, the thermochemical conversion in gasifiers and the factors affecting the gasification process, the cleaning technologies for raw producer gas and its conditioning and finally the integration of gasifier with SOFCs. The influence of impurities present in biomass producer gas such as particulates, tar, H 2 S, HCl and alkali compounds based on recent experimental studies and their tolerance limits towards SOFCs are presented. Even though analysis based on the probable tolerance limits of impurities towards SOFCs and a comprehensive overview of the cleaning technologies for producer gas impurities indicate that producer gas cleaning at various temperatures using current technologies to meet SOFC requirements is possible, more experimental studies are still needed to acquire the detailed information on the tolerance limits of impurities for SOFCs. The recent theoretical modeling and experimental studies of biomass integrated gasification–SOFC systems are also presented.

With the integration of a high penetration of wind power into distribution system, the ability to cope with the voltage fluctuation issue arising from the intensified uncertainty should be improved. Energy storage system (ESS) with effective control strategies keeps a key role in smoothing the voltage fluctuation caused by the uncertainty of wind turbine generators (WTGs). Considering the constraints of state of charge (SOC), charge-discharge efficiency and continuous operation of ESS, this paper proposes a novel approach to determine the minimum capacity of ESS to satisfy the voltage fluctuation limit based on unbalanced three-phase interval power flow. An unbalanced forward-backward sweep interval power flow considering the constraints of ESS and the voltage fluctuation limit is proposed. The interval model of uncertain WTG output is established on basis of wind speed fluctuation curve. The interval model of the practical ESS output is obtained on basis of the present SOC, nominal capacity and comprehensive efficiency. The output voltages of power flow can directly demonstrate the voltage fluctuation rate due to their interval forms. Therefore, a feedback mechanism is established between the output voltage fluctuation rate and the input ESS practical power, which is used to determine the minimum capacity of ESS to satisfy the fluctuation limit. A modified IEEE 33-bus system with high penetration of WTGs is implemented to test the proposed method. Results demonstrate the validity and effectiveness of the proposed approach.

Dynamic loading of transformers is the term used when the loading capacity is calculated using an appropriate thermal model while taking into account the load magnitude, load shape, thermal limits and external cooling conditions. For transformer dynamic loading, the aim is to estimate the transformer's maximum dynamic loading capacity without violating the hottest-spot temperature (HST) and top-oil temperature (TOT) thermal limits. These two temperatures are proxy measures of insulation temperature, which can be used to estimate the loss of service life. The accuracy of the TOT and HST predictions is dependent on many things, central to which is the accuracy of the thermal model. This paper introduces metrics that can be used to differentiate between reliable and unreliable transformer thermal models. The two models discussed in this paper for HST and TOT are the non-linear IEEE model and the model developed by the authors using linear regression methods.

We present the first calculations to follow the evolution of all stable isotopes (and their abundant radioactive progenitors) in a finely zoned stellar model computed from the onset of central hydrogen burning through explosion as a Type II supernova. The calculations were performed for a 15 solar mass Pop I star using the most recently available set of experimental and theoretical nuclear data, revised opacity tables, and taking into account mass loss due to stellar winds. We find the approximately solar production of proton-rich isotopes above a mass number of A=120 due to the gamma-process. We also find a weak s-process, which along with the gamma-process and explosive helium and carbon burning, produces nearly solar abundances of almost all nuclei from A=60 to 85. A few modifications of the abundances of heavy nuclei above mass 90 by the s-process are also noted and discussed. New weak rates lead to significant alteration of the properties of the presupernova core. 10 pages, 4 figures, Nuclear Astrophysics X Workshop proceedings

Abstract This review article places in perspective the new work devoted both to the analysis of the thermodynamic irreversibility of heat and mass transfer components and systems and to the design of these devices on the basis of entropy generation minimization. The review focuses on the fundamental mechanisms responsible for the generation of entropy in heat and fluid flow and on the design tradeoff of balancing the heat transfer irreversibility against the fluid flow irreversibility. Applications are selected from the fields of heat exchanger design, thermal energy storage, and mass exchanger design. This article provides a comprehensive, up-to-date review of second-daw analyses published in the heat and mass transfer literature during the last decade.