• Energy Research
• other engineering and technologies close
• US close
• IN close

Summary Monitoring of microbial corrosion is always difficult because of the sessile nature of bacteria and the lack of meaningful correlation between routine bacteria counts and bacterial activity. This problem is further aggravated in a large oilfield water system because of size and sampling difficulties. This paper discusses some monitoring techniques currently used in the oil industry, their limitations, and possible areas for improvement. These improved techniques are in use or will be implemented in the Aramco systems. Introduction Microbial corrosion has caused some failures in seawater injection systems. Whether or not microbial corrosion represents a major corrosion mechanism in the oilfield water system is a controversial question. However, it has certainly become a major concern in recent years. There are two approaches in dealing with microbial corrosion problems in a large oilfield water system. One approach is to start treating the system with bactericide in conjunction with regular scraping when the system is commissioned. The other is to treat the system only when an impending microbial-related problem is clearly defined. in either case, monitoring of microbial corrosion is essential. The first approach is more or less a precautionary measure. The treatment and selection of bactericides is usually based on past experience and laboratory evaluation tests. While the treatment is being implemented, a reliable monitoring program could assess the effectiveness of the current program of microbial corrosion control. In the second case, monitoring of microbial corrosion is even more important. it would provide timely information toward implementation of a treatment program before the system could get out of control. The industry's awareness of microbial corrosion has been indicated by the number of papers published in recent years on this subject. These articles cover a wide spectrum of interest from fundamental corrosion mechanisms to case studies, detection methods, control measures, etc. Although it is not clear to what extent microorganisms are responsible for the observed field corrosion failures, the general consensus still favors early establishment of a routine microbial corrosion monitoring program. The best approach seems to he the establishment of solid baseline data for the system after which any significant future deviation can be interpreted as a sign of a potential problem. The following sections describe the current methods used for routine monitoring, specifically for Aramco's large oilfield water systems. The limitations of these methods, the difficulties encountered, and some suggested studies for modification and improvement are discussed also. Current Monitoring Methods The methods currently used by Aramco can be categorized as (l) cell counts in water, (2) metal surface examination, (3) scraping solids analysis, (4) water quality analysis, and (5) evaluation of current bactericide treatment. Cell Counts in Water. These are used to detect bacterial organisms and their concentrations. it is recognized that confirmation of free-flowing bacteria in the water does not automatically mean trouble. However, if bacteria counts demonstrate a definite increase across the system, or over a period of time, the odds are that bacteria are active and working on the metal somewhere in the system. Cell counts routinely monitored include sulfate-reducing bacteria (SRB), general aerobic bacteria (OAB), iron bacteria, and others. SRB are widely recognized to he primarily responsible for bacteria-induced corrosion in an anaerobic environment. Depending on the nature of the sample to be tested and the types of problems encountered (or expected) in the field, one or several different enumeration techniques are employed. For field work, the method generally used by Aramco is culturing of samples in liquid growth media specifically designed for detecting a certain group of organisms. These laboratory media are prepared using the appropriate field water as a base, with addition of general growth nutrients for the organisms. The use of field water to prepare the media provides a water composition similar to that in which the bacteria originated. The media are supplemented with other ingredients to create an environment conducive to growth of certain bacteria (e.g., certain reducing agents have to he added into the SRB media). The media then are dispensed into serum vials at exactly 9 mL [9 cm3] each and sealed with rubber stoppers and aluminum seals. JPT P. 1171

An experimental study on the flow and heat transfer in open vertical enclosures, representing elevator shafts, warehouses, and atriums, due to a building fire is carried out, using a scale model. Smoke and hot gases are injected into the enclosure at a lower opening and the resulting downstream flow and temperature fields are studied. The inlet temperature and flow rate of the hot gases are varied over wide ranges to simulate the flow due to fire in multi-leveled buildings with vertical open shafts or atriums under natural ventilation. The conditions at the outlet, which is located on the same wall as the inlet, are also monitored to determine the effects of entrainment into the flow and heat transfer to the walls. Typical values of the operating conditions have been investigated, ranging from high buoyancy levels, for which the flow stays close to the vertical wall of the enclosure, to much lower levels, at which the flow enters the enclosure with a significant flow velocity and spreads outward very quickly. With increasing temperature at the inlet, the buoyancy effect is larger, resulting in higher velocities and shorter time to reach the top. The measured temperature at the outlet depends on heat transfer to the walls as well as on the flow velocity. Detailed measurements of the velocity and temperature fields have also been taken. It is found that a wall plume is generated which conveys the hot fluid rapidly along the vertical wall containing the inlet and the outlet. A recirculating flow arises away from this wall and this flow affects the heat transfer and flow in the wall plume. This feature, in turn, affects the entrainment into the flow, decay of the temperature level and the evolution of mean flow. Therefore, horizontally uniform conditions cannot be assumed here, as employed in several studies of tall enclosures. The wall plume has to be modeled in this case, considering the entrainment into the boundary layer flow and the effect of the recirculating flow.

Low-salinity water injection emerges to be a cost-effective and environmentally friendly enhanced oil recovery technique. Furthermore, additives, such as the surfactant and nanoparticles in combina...

Abstract This paper aims to present a feasibility study of the innovative plant for methanol synthesis from carbon dioxide-sequestered by fossil fuel power plant and hydrogen, which is produced by water electrolyzer employing the over-production on the electrical grid. The thermo-economic analysis is performed in the framework of the MefCO2 H2020 EU project and it is referred to the German economic scenario, properly taking into account the real market costs and cost functions for different components of the plant. Three different plant capacities for methanol production (4000 10,000 and 50,000 ton/year) have been investigated, assuming an average cost for electrical energy to feed electrolysers and analyzing the influence of the most significant parameters (oxygen selling option, methanol selling price and electrolysers’ capital cost) on the profitability of the plant. The analysis has been performed in W-ECoMP, software for the thermo-economic analysis and plant optimization developed by the University of Genoa.

The cover of a disposal cell is an important element in the long-term stability of a reclaimed uranium tailings site. The cover is generally comprised of a radon barrier, filter, and surface erosion barrier. A study is conducted to investigate the drainage and erosion potential between the filter and radon barrier layer in response to surface water flows over a layer of riprap. A cover system is physically modeled in a hydraulics laboratory. The experimental program evaluated the interstitial velocity potential through four filters, the erosion and sediment transport potential from the radon barrier, and the filter drainage rate after passage of the surface runoff hydrograph. The results indicated that the use of traditional filter criteria to bed riprap is extremely conservative and restricts drainage. The grain size of the filter materials should be increased to enhance drainage when placed on flat (\IS\N ≤\N 5%) slopes. A relationship is presented for estimating the drainage velocity potential through a filter layer as a function of slope and gradation. A new filter criteria should be developed for overtopping flow conditions.

The main problem involved in utilization of solar energy is low efficiency of photovoltaic conversion and high cost. The objectives of the paper are to increase the efficiency of photovoltaic cells and to reduce the cost of the photovoltaic module. A novel method is presented in this paper to increase the efficiency of photovoltaic modules and reduce the cost by the use of specially designed solar concentrators. The efficiency of photovoltaic module is increased by covering an angle of nearly 180° so that the sun's radiation converges through out the day from all angles on to a fixed flat plate module. The cost is reduced by use of cheaper glass for module and covering a wider area for the radiation. The above objectives are achieved by the use of a special arrangement of three lenses for the concentrators.

Vegetable oil and animal fat derived fatty acid methyl esters are commonly known as biodiesel and provide an environment friendly and renewable substitute for the conventional diesel fuel. The present work demonstrates an easy preparation of potassium ion impregnated calcium oxide in nano crystalline form (supported by powder X-ray diffraction and transmission electron microscopic studies) and its application as a solid catalyst for the transesterification of waste cottonseed oil with methanol. The catalyst prepared by impregnating 3.5 wt% of potassium in CaO support was found to show the best catalytic activity among the prepared catalysts. The same catalyst was found to be effective for the complete transesterification of less expensive feedstock, waste cotton seed oil, even in the presence of 10.26 wt% moisture and 4.35 wt% free fatty acid contents. The selected catalyst has also been reused successfully for three catalytic cycles. Few physicochemical properties of the prepared biodiesel sample have been studied and found to be within the acceptable limits of EN 14214 standards.