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This work focuses on the development of ternary and quaternary chalcogenide compounds featuring transition metal cations through careful engineering of the electronic and thermal transport as well as magnetic properties by traditional solid-state doping techniques and novel template structure synthesis methods for improvements in thermoelectric performance, diluted magnetic semiconductors, and photovoltaic conversion. Presented here is an innovative low-temperature batch synthesis that was developed to create hexagonal nanoplatelets of thermoelectrically interesting CuAgSe. This process utilized room temperature ion exchange reactions to convert cubic Cu2-xSe nanoplatelets into CuAgSe by replacing a portion of the Cu+ ions with Ag+ while maintaining the morphology of the nanoplatelet. This simple reaction process offers an energy efficient and versatile strategy to create interesting materials with superior thermoelectric performance. An investigation of the thermal and electronic transport of CuAl(SxSe1-x)2 solid solutions was also conducted. While these compounds yielded low thermal conductivity, they also exhibited low electronic conductivity. Doping with transition metals Ag, Hf, and Ti further reduced the thermal conductivity below 1 W/mK; however, most exciting was the determination that the thermal transport of the system could be modified by doping at the Al3+ site without affecting the electronic structure of the system, potentially leading to the use of CuAl(SxSe1-x)2 as a heavily doped thermoelectric material. The effect of local carrier concentration in the diluted magnetic semiconductor FeSb2Se4 was studied by substitution of In3+ for Sb3+. Using systematic Rietveld refinement, it was determined that In3+ resides in the semiconducting layer of the structure for concentrations of x ≤ 0.1, and the magnetic layer for x > 0.1. The increase in local carrier concentration has an appreciable effect on the electronic and magnetic properties of the material in a predictable manner based on the ...

University of Minnesota M.S. thesis. 2022. Major: Water Resources Science. Advisor: David Mulla. 1 computer file (PDF); 260 pages. ; In the past several decades, soil water erosion and runoff in agricultural regions across the Midwestern United States have contributed to significant A-horizon soil losses, declining soil productivity, and the widespread impairment of water resources. Rising temperatures and changes in precipitation trends have the potential to significantly impact future soil water erosion and runoff in the Midwest, yet relatively few studies have attempted to quantify these impacts. To help expand this area of research, the Water Erosion Prediction Project (WEPP) Model was used to quantify growing season soil water erosion and runoff for a baseline period (1965-2019) and two future periods (2020-2059 & 2060-2099) in agricultural hillslopes across three Minnesota HUC12 watersheds. Future daily weather inputs were generated for WEPP using downscaled daily climate projections from two CMIP5 climate models (HadGEM2-CC and GFDL-ESM2G) and three emissions scenarios (RCP 4.5, RCP 6.0, and RCP 8.5). The climate scenarios were combined with varying adoption rates of perennial crops, conservation tillage systems, and cover crops in order to determine the effectiveness of these mitigation strategies in reducing future soil loss and runoff. When the baseline management scenario was used, most future climate scenarios showed decreases in runoff (34-58%), soil loss (3.3-40%), and the number of hillslopes with unsustainable soil loss (1-8%). However, there were also moderate to significant increases in runoff (17-38%), soil loss (4.2-40%), and the number of hillslopes with unsustainable soil loss (+3%) in several of the moderate emissions scenarios (RCP 4.5 and RCP 6.0). Watersheds with steep slopes and widespread conventional row crop systems had a significantly greater number of hillslopes with unsustainable soil losses, even if runoff and soil loss were projected to decrease in the future. Additionally, ...

To reduce reliance on fossil fuels, sustainable biofuels are being pursued, especially advanced biofuels like 1-butanol that have higher energy content and greater compatibility with existing infrastructure than ethanol. A persistent challenge is the yield-limiting toxicity of biofuels and process solvents, such as tetrahydrofuran, to the microbes that ferment biomass into biofuel. The cell membrane is a focal point of toxicity, and understanding how it interacts with fuels and solvents is key to improving yield. Phospholipid bilayers are the core of biomembranes, and model biomembranes of defined composition provide the ideal platform for biophysical studies. To this end, glycerophospholipids characteristic of Bacillus subtilis, a model producer organism, were synthesized. Two fatty acids (iso- and anteisopentadecanoic acids) characteristic of Bacilli were synthesized and incorporated into representative phosphatidic acid, phosphatidylethanolamine and phosphatidylglycerol lipids. The validated synthetic approach opens the door to future studies on the interaction of biofuels and solvents with biomembranes.

In any country of the world, the issues of the development of the energy industry today are very resonant, since all subjects of society - from households to huge industrial corporations - are dependent on it. In order to objectively assess the current state of energy and determine the directions for optimizing the use of energy resources, it is necessary to regularly monitor the structure of their production and consumption. An analysis of the implementation of regional policy in the Russian Federation aimed at improving energy efficiency and energy intensity, in particular in the North-Western region, allows us to conclude that it is insufficiently elaborated. To a greater extent, it is implemented only formally and is fragmentary. The author focuses on the problem of regulation of the construction industry on issues of energy intensity. The author also states that the involvement of renewable sources in the Northwestern Federal District in electricity generation is too low, namely wind and solar power plants, the share of which in Europe is about 20%.

Sea level rise and changing storm frequency and intensity resulting from climate change create tremendous amounts of uncertainty for coastal species. Intertidal species may be especially affected since they are dependent on daily inundation and exposure. The eastern oyster Crassostrea virginica is an economically and biologically important sessile intertidal species ranging from Canada to the Gulf of Mexico. Declines and changes in distribution of oyster populations has forced commercial harvesting to spread from subtidal to intertidal reefs. We investigated the potential responses of intertidal C. virginica to sea level rise, and the response of larval settlement to sedimentation which is likely to increase with higher water levels and storm frequency. Inundation was used as a proxy for sea level rise. We hypothesized four possible outcomes for intertidal oyster reefs as a result of changes in inundation due to sea level rise: (a) intertidal reefs become subtidal and remain in place, (b) intertidal reefs will be lost, (c) intertidal reefs migrate shoreward upslope and remain intertidal, and (d) intertidal reefs will grow in elevation and remain intertidal. To test the plausibility of these four outcomes, oyster ladders were placed at two sites within Apalachicola Bay, Florida, USA. Ladders supported oyster recruitment mats at five heights within the range of intertidal elevations. The bottom-most mat was placed near mean low tide, and the top mat near mean high tide to investigate the effect of tidal inundation time on C. virginica. Sediment traps were attached to ladders with openings at equal elevation to the oyster mats. Ladders were deployed for one year starting in June 2012, and again in June 2013, during peak oyster recruitment season. Monthly for six months during year one, sediment was collected from traps, dried to constant weight and weighed to obtain a monthly average for total sediment at each elevation. At the end of one year, oyster mats were collected from the field and examined for the ...

The uniformity of different nuclear regions as a function of the number of valence protons and neutrons (counted from the nearest closed shell) has been exploited for the parameterization of calculations for nuclei far from stability within the IBA model. Predictions are given for low lying levels, E2 transition rates, and binding energies for nuclei in the r-process path in the A = 150 and A = 190 mass regions. 6 refs., 6 figs.

{"references": ["U.S. Energy Information Administration. \"How much energy is\nconsumed in residential and commercial buildings in the United States?\"\nAvailable at: http://www.eia.gov/tools/faqs/faq.cfm?id=86&t=1", "S. Darby, \"The effectiveness of feedback on energy consumption.\"\nEnvironmental Change Institute, University of Oxford, 2006. Available\nat: http://www.globalwarmingisreal.com/energyconsump-feedback.pdf.\nVisited: September 2015", "J. S. John, \"Putting energy disaggregation tech to the test,\" November,\n2013. Greentech Media. Available at:\nhttp://www.greentechmedia.com/articles/read/putting-energydisaggregation-tech-to-the-test.\nVisited: September 2015", "A. Zoha, A. Gluhak, M. A. Imran, S. Rajasegarar, \"Non-intrusive load\nmonitoring approaches for disaggregated energy sensing: a survey,\"\nSensors, vol. 12, no. 12, pp. 16838-16866, December 2012.", "G. W. Hart, \"Nonintrusive appliance load monitoring,\" in Proc. of the\nIEEE, vol. 80, pp. 1870-1891, December 1992.", "M. Baranski, J. Voss, \"Non-intrusive appliance load monitoring based\non Optical Sensor,\" IEEE Bologna PowerTech Conference, Bologna,\nItaly, June 2003. Available at:\nhttp://ieeexplore.ieee.org/stamp/stamp.jsp?tp=&arnumber=1304732", "L. Farinaccio, R. Zmeureanu, \"Using a pattern recognition approach to\ndisaggregate the total electricity consumption in a house into the major\nen-uses,\" Elsevier, Energy and Buildings, vol. 30, no. 3, pp. 245-259,\nAugust 1999.", "J. M. Abreu, F. C. Pereira, P. Ferr\u00e3o, \"Using pattern recognition to\nidentify habitual behavior in residential electricity consumption,\"\nElsevier, Energy and Buildings, vol. 49, pp. 479-487, June 2012.", "C. Beckel, L. Sadamori, S. Santini, \"Automatic socio-economic\nclassification of households using electricity consumption data,\" in\nProc. of the 4th international conference on future energy systems, New\nYork, 2013, pp. 75-86.\n[10] H. Zhao, F. Magoul\u00e8s, \"A review on the prediction of building energy\nconsumption,\" Elsevier, Renewable and Sustainable Energy Reviews,\nvol. 16, no. 6, pp. 3586-3592, August 2012.\n[11] G. K. F. Tso, K. K. W. Yau, \"Predicting electricity energy consumption:\nA comparison of regression analysis, decision tree and neural networks,\"\nElsevier, Energy, vol. 32, no. 9, pp. 1761-1768, September 2007.\n[12] F. Farzan, S. A. Vaghefi, K. Mahani, M. A. Jafari, J. Gong, \"Operational\nplanning for multi-building portfolio in an uncertain energy market,\"\nElsevier, Energy and Buildings, vol. 103, pp. 271-283, September 2015."]} Energy disaggregation has been focused by many energy companies since energy efficiency can be achieved when the breakdown of energy consumption is known. Companies have been investing in technologies to come up with software and/or hardware solutions that can provide this type of information to the consumer. On the other hand, not all people can afford to have these technologies. Therefore, in this paper, we present a methodology for breaking down the aggregate consumption and identifying the highdemanding end-uses profiles. These energy profiles will be used to build the forecast model for optimal control purpose. A facility with high cooling load is used as an illustrative case study to demonstrate the results of proposed methodology. We apply a high level energy disaggregation through a pattern recognition approach in order to extract the consumption profile of its rooftop packaged units (RTUs) and present a forecast model for the energy consumption.

I derive and test predictions from the classic Mussa and Rosen (1978) second-degree price discrimination model using data from the United States clothes washer market. I find evidence consistent with price discrimination in the market response to energy efficiency policy changes. Concurrent with the effective dates of both the new 2004 and 2007 federal minimum efficiency and ENERGY STAR standards, within-model clothes washer prices dropped on average. The heterogeneous pattern of price reduction across market segments, and adjustments in the menu of products, were consistent with predictions from the price-discrimination model, and not with a perfectly competitive market.

Issued as part of Scientific Papers of the Bureau of Standards, Volume 15, 1919-20. ; Running title: Computation of radiation data. ; Includes bibliographical references. ; Mode of access: Internet.

Thesis. 1977. M.Arch.A.S.--Massachusetts Institute of Technology. Dept. of Architecture. ; MICROFICHE COPY AVAILABLE IN ARCHIVES AND ROTCH. ; Bibliography : leaves 174-178. ; by Conrad Heeschen. ; M.Arch.A.S.