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Rice husk has the potential to be used as a source of alternative energy e.g. as biofuel. Its high lignin content, however, poses difficulty to this use. This study investigates the use of microwave assisted acidic and alkaline pretreatment methods to improve the characteristics of rice husk for energy production. The use of microwave assisted 3.5% NaOH provided optimum pretreatment of rice husk; the lignin content was reduced from 17.8 to 10.2%, the cellulose content increased from 38.6 to 59.3% and the C/N ratio was within the optimum range of 25-35. The results showed enhanced potential of biofuel production from rice husk by this pretreatment.

Abstract This literature review was built upon recently published articles on Life Cycle Assessments (LCAs) of agricultural biogas plants, to: enhance understanding of the relevant literature in the field and the related question by readers worldwide. It was designed to highlight methodological issues and impact indicators, which best represent this research field; consequently, they should be considered in performing environmental assessments of agro-biogas derived energy systems. The literature review highlighted the wide variability of environmental results due to the ways the feedstock mixtures were produced, managed, and supplied; and due to the regions in which the anaerobic digesters were located and operated. Differences were found to be related to the aim and function of the study and to the methodological approach used, especially for the development of the environmental impact assessments. Other differences resulted from the ways the energy produced was utilised, whether it was used as an input to the natural gas national grid, and/or if it was used within the production system. The authors of this review concluded that, although much progress has been made, many unsolved challenges and methodological choices must be addressed to further improve the robustness of LCA in relation to AD and to related approaches.

<abstract> <p>Fish is a key component of Nigeria's protein supply, making up about 40% of the nation's protein intake and considerably aiding in the achievement of the second Sustainable Development Goal of feeding the expanding population. Despite its importance, Nigeria's fish production and supply cannot keep up with demand. While total fish output has increased from 1,073,059 tonnes in 2014 to 1,169,000 tonnes in 2018 and is expected to reach 1,275,000 tonnes by 2030, there is a great supply gap. Fish production not only affects food security but also the national economy and employment. Notwithstanding, the fisheries sub-sector suffers several difficulties, such as poor management, a deficient fisheries policy, overfishing, diminishing catch, and a lack of technical know-how among fish growers and fishermen. Thus, exploring untapped aquaculture potential and managing small-scale fisheries effectively are necessary to close the gap between the demand for and supply of fish. The fish output situation can be improved by enforcing fisheries policy and regulations, increasing investments in ethical fisheries and aquaculture, and providing sufficient training for fish farmers and fisherfolk. To reduce waste associated with the limited number of fish now produced, post-harvest losses must also be addressed. By solving these issues and putting in place the necessary actions, Nigeria can increase its fish production, strengthen its food security, and accomplish the sustainable development goals in its evolving blue economy.</p> </abstract>

From the comparison of regulations and/or standards for the organic, conventional and/or integrated citrus production method and a voluntary certification, it emerges that farms certified with voluntary non-regulated certification systems, such as the IFA FV GLOBALG.A.P, are obliged to take into account the highest number of aspects, reported in a more complete register, than the organic ones. Moreover, this is also supported by a continuous-time planned process of revision and updating of the applicable versions of the standard. The environmental impact of the food production, the safety aspects of food products, as well as the health, ethics, and safety aspects of workers, are largely considered and inspected in the GLOBALG.A.P., while the organic system, despite the IFOAM suggestions and indications, is only considered partially. This means that, from a practical point of view, the organic product can be considered “clean and safe”, but not more environmentally friendly than the GLOBALG.A.P. products.

Featured paper: See Editorial p553

Abstract Fouling is one of the most significant problems for internally enhanced tubes installed in the shell and tube condensers. Due to the lack of long-term test data, current fouling models are developed based on accelerated particulate fouling tests that have the low precision and hence are inapplicable for predicting combined fouling in most practical cooling tower systems. In addition, the constant values of fouling resistance (factor) recommended by the Air-Conditioning, Heating, and Refrigeration Institute (AHRI) are extremely limited under different operating conditions. To overcome these challenges, this research developed and validated two fouling prediction models based on experimental long-term tests. One of the models was in the form of a ratio of asymptotic fouling resistance of the enhanced tube to that of the plain tube ( R f ∗ / R f , p ∗ ), and the other one was in the form of the asymptotic fouling resistance of the directly enhanced tube ( R f ∗ ). Both models considered water quality, water velocity, and the tube geometries as the variables with the acceptable accuracy for prediction. 1) For the water quality, the parameter of valid concentration ( C com ) of cooling water was defined in this study, which reflected the potential amount of valid components to form the fouling. 2) For the water velocity, its impacts on the two critical parameters of the fouling process: sticking probability ( P ) and deposit bond strength ( ξ ) were investigated using experimental studies. Test results showed that in enhanced tubes with the increased water velocity the sticking probability ( P ) decreased continuously while the deposit bond strength (ξ) initially increased, and then, decreased. 3) For the tube geometries, by taking the parameters of tube geometries as variables the multi-variable correlations of the sticking probability ( P ) and deposit bond strength ( ξ ) were developed. From the results the generalized fouling prediction model as a ratio of asymptotic fouling resistance ( R f ∗ / R f , p ∗ ) was recommended for the application in HVAC&R industry due to its suitability and accuracy in practical project applications.

This study evaluated the efficacy of enzyme induced calcite precipitation (EICP) in restricting the mobility of heavy metals in soils. EICP is an environmentally friendly method that has wide ranging applications in the sustainable development of civil infrastructure. The study examined the desorption of three heavy metals from treated and untreated soils using ethylene diamine tetra-acetic acid (EDTA) and citric acid (C6H8O7) extractants under harsh conditions. Two natural soils spiked with cadmium (Cd), nickel (Ni), and lead (Pb) were studied in this research. The soils were treated with three types of enzyme solutions (ESs) to achieve EICP. A combination of urea of one molarity (M), 0.67 M calcium chloride, and urease enzyme (3 g/L) was mixed in deionized (DI) water to prepare enzyme solution 1 (ES1); non-fat milk powder (4 g/L) was added to ES1 to prepare enzyme solution 2 (ES2); and 0.37 M urea, 0.25 M calcium chloride, 0.85 g/L urease enzyme, and 4 g/L non-fat milk powder were mixed in DI water to prepare enzyme solution 3 (ES3). Ni, Cd, and Pb were added with load ratios of 50 and 100 mg/kg to both untreated and treated soils to study the effect of EICP on desorption rates of the heavy metals from soil. Desorption studies were performed after a curing period of 40 days. The curing period started after the soil samples were spiked with heavy metals. Soils treated with ESs were spiked with heavy metals after a curing period of 21 days and then further cured for 40 days. The amount of CaCO3 precipitated in the soil by the ESs was quantified using a gravimetric acid digestion test, which related the desorption of heavy metals to the amount of precipitated CaCO3. The order of desorption was as follows: Cd > Ni > Pb. It was observed that the average maximum removal efficiency of the untreated soil samples (irrespective of the load ratio and contaminants) was approximately 48% when extracted by EDTA and 46% when extracted by citric acid. The soil samples treated with ES2 exhibited average maximum removal efficiencies of 19% and 10% when extracted by EDTA and citric acid, respectively. It was observed that ES2 precipitated a maximum amount of calcium carbonate (CaCO3) when compared to ES1 and ES3 and retained the maximum amount of heavy metals in the soil by forming a CaCO3 shield on the heavy metals, thus decreasing their mobility. An approximate improvement of 30% in the retention of heavy metal ions was observed in soils treated with ESs when compared to untreated soil samples. Therefore, the study suggests that ESs can be an effective alternative in the remediation of soils contaminated with heavy metal ions.

ABSTRACT Playa wetlands in the Great Plains, USA support a wide variety of plant species not found elsewhere in this agriculturally-dominated region due to the ephemeral presence of standing water and hydric soils within playas. If longer dry periods occur due to climate change or if changes in surrounding land use alter sediment accumulation rates and water storage capacity in playas, plant communities could experience decreased diversity, with lasting effects on ecosystem services provided by playas in the Great Plains and at a continental-level in North America. We quantified potential changes in playa wetland plant community composition associated with predicted changes in precipitation and land use in the Great Plains through the end of the 21st century. We conducted two six-month greenhouse experiments mimicking field conditions using intact mesocosms collected from playas in Nebraska and Texas. In the precipitation experiment, treatments derived from historical precipitation observations and three future moderate emissions (CMIP5 RCP4.5) downscaled climate projections were applied to mesocosms. For the land use experiment, treatments were simulated by nitrogen (N) applications to soil ranging from 0 to 100 mg-N L-1 with each precipitation event under historical rainfall patterns, representing increasing and decreasing area in agricultural use in playa watersheds. Plant communities tended to shift toward more native species under projected future climate conditions, but as N runoff increased, native species richness decreased. Agricultural land-use surrounding playas may have a greater effect on wetland plant communities than future alterations to hydrology based on climate change in the Great Plains; thus, efforts to reduce nutrient runoff into playas would likely mitigate loss in ecosystem function in the coming decades.