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description Publicationkeyboard_double_arrow_right Article , Journal 2017 United KingdomPublisher:Royal Society of Chemistry (RSC) Mzamo L. Shozi; Venkata D. B. C. Dasireddy; Sooboo Singh; Pheladi Mohlala; David J. Morgan; Sarwat Iqbal; Holger B. Friedrich;doi: 10.1039/c7se00199a
Rhenium is an effective promoter for ZnO catalysts in glycerol hydrogenolysis by enhancing catalytic activity and producing lower alcohols in good yields.
Sustainable Energy &... arrow_drop_down University of Lincoln: Lincoln RepositoryArticle . 2017Data sources: Bielefeld Academic Search Engine (BASE)add ClaimPlease grant OpenAIRE to access and update your ORCID works.This Research product is the result of merged Research products in OpenAIRE.
You have already added works in your ORCID record related to the merged Research product.This Research product is the result of merged Research products in OpenAIRE.
You have already added works in your ORCID record related to the merged Research product.All Research productsarrow_drop_down <script type="text/javascript"> <!-- document.write('<div id="oa_widget"></div>'); document.write('<script type="text/javascript" src="https://beta.openaire.eu/index.php?option=com_openaire&view=widget&format=raw&projectId=10.1039/c7se00199a&type=result"></script>'); --> </script>For further information contact us at helpdesk@openaire.eumore_vert Sustainable Energy &... arrow_drop_down University of Lincoln: Lincoln RepositoryArticle . 2017Data sources: Bielefeld Academic Search Engine (BASE)add ClaimPlease grant OpenAIRE to access and update your ORCID works.This Research product is the result of merged Research products in OpenAIRE.
You have already added works in your ORCID record related to the merged Research product.This Research product is the result of merged Research products in OpenAIRE.
You have already added works in your ORCID record related to the merged Research product.All Research productsarrow_drop_down <script type="text/javascript"> <!-- document.write('<div id="oa_widget"></div>'); document.write('<script type="text/javascript" src="https://beta.openaire.eu/index.php?option=com_openaire&view=widget&format=raw&projectId=10.1039/c7se00199a&type=result"></script>'); --> </script>For further information contact us at helpdesk@openaire.eudescription Publicationkeyboard_double_arrow_right Article , Journal 2020Publisher:Elsevier BV Authors: Ziyaad Mohamed; Venkata D.B.C. Dasireddy; Sooboo Singh; Holger B. Friedrich;Abstract Pt supported on TiO2 and ZrO2 catalysts were synthesized via wet impregnation and deposition precipitation methods. The catalysts were tested for CO removal from reformate gas following the water-gas shift reaction for on-board fuel processors. Tests included oxidation of CO to CO2, preferential oxidation of CO to CO2 in the presence of H2 (PROX), and hydrogenation of CO to CH4 (selective methanation, SMET). The Pt–ZrO2 catalysts showed better metal dispersions, particle sizes, lower degrees of reduction and higher oxygen storage capacities than the TiO2 supported catalysts. All catalysts showed low activity for the oxidation of CO in the PROX reaction, due to H2 and O2 spillover effects. ZrO2, with its high reducing properties and strong metal-support interactions, was found to be the best support for hydrogenation of CO. ZrO2 induced small well-dispersed Pt particles that were key parameters in this reaction. Both Pt–ZrO2 catalysts showed CO conversions over 99% above 350 °C with high CH4 selectivities (99%). The study shows advantageous effects of strong metal to support interactions, like participation of MOx (support) species in activating the CO molecule. The CO concentration was effectively reduced to the desired ppm levels (
add ClaimPlease grant OpenAIRE to access and update your ORCID works.This Research product is the result of merged Research products in OpenAIRE.
You have already added works in your ORCID record related to the merged Research product.This Research product is the result of merged Research products in OpenAIRE.
You have already added works in your ORCID record related to the merged Research product.All Research productsarrow_drop_down <script type="text/javascript"> <!-- document.write('<div id="oa_widget"></div>'); document.write('<script type="text/javascript" src="https://beta.openaire.eu/index.php?option=com_openaire&view=widget&format=raw&projectId=10.1016/j.renene.2019.10.088&type=result"></script>'); --> </script>For further information contact us at helpdesk@openaire.eumore_vert add ClaimPlease grant OpenAIRE to access and update your ORCID works.This Research product is the result of merged Research products in OpenAIRE.
You have already added works in your ORCID record related to the merged Research product.This Research product is the result of merged Research products in OpenAIRE.
You have already added works in your ORCID record related to the merged Research product.All Research productsarrow_drop_down <script type="text/javascript"> <!-- document.write('<div id="oa_widget"></div>'); document.write('<script type="text/javascript" src="https://beta.openaire.eu/index.php?option=com_openaire&view=widget&format=raw&projectId=10.1016/j.renene.2019.10.088&type=result"></script>'); --> </script>For further information contact us at helpdesk@openaire.eudescription Publicationkeyboard_double_arrow_right Article , Journal 2019Publisher:Royal Society of Chemistry (RSC) Mzamo L. Shozi; Venkata D. B. C. Dasireddy; Sooboo Singh; Alisa Govender; Pheladi Mohlala; Holger B. Friedrich;doi: 10.1039/c9se00045c
Incorporation of Re in supported Ni catalysts greatly improves hydrogenolysis of glycerol to mono-alcohols via increased acidity, dispersion and metal–support interaction.
Sustainable Energy &... arrow_drop_down Sustainable Energy & FuelsArticle . 2019 . Peer-reviewedLicense: Royal Society of Chemistry Licence to PublishData sources: Crossrefadd ClaimPlease grant OpenAIRE to access and update your ORCID works.This Research product is the result of merged Research products in OpenAIRE.
You have already added works in your ORCID record related to the merged Research product.This Research product is the result of merged Research products in OpenAIRE.
You have already added works in your ORCID record related to the merged Research product.All Research productsarrow_drop_down <script type="text/javascript"> <!-- document.write('<div id="oa_widget"></div>'); document.write('<script type="text/javascript" src="https://beta.openaire.eu/index.php?option=com_openaire&view=widget&format=raw&projectId=10.1039/c9se00045c&type=result"></script>'); --> </script>For further information contact us at helpdesk@openaire.eumore_vert Sustainable Energy &... arrow_drop_down Sustainable Energy & FuelsArticle . 2019 . Peer-reviewedLicense: Royal Society of Chemistry Licence to PublishData sources: Crossrefadd ClaimPlease grant OpenAIRE to access and update your ORCID works.This Research product is the result of merged Research products in OpenAIRE.
You have already added works in your ORCID record related to the merged Research product.This Research product is the result of merged Research products in OpenAIRE.
You have already added works in your ORCID record related to the merged Research product.All Research productsarrow_drop_down <script type="text/javascript"> <!-- document.write('<div id="oa_widget"></div>'); document.write('<script type="text/javascript" src="https://beta.openaire.eu/index.php?option=com_openaire&view=widget&format=raw&projectId=10.1039/c9se00045c&type=result"></script>'); --> </script>For further information contact us at helpdesk@openaire.eu
description Publicationkeyboard_double_arrow_right Article , Journal 2017 United KingdomPublisher:Royal Society of Chemistry (RSC) Mzamo L. Shozi; Venkata D. B. C. Dasireddy; Sooboo Singh; Pheladi Mohlala; David J. Morgan; Sarwat Iqbal; Holger B. Friedrich;doi: 10.1039/c7se00199a
Rhenium is an effective promoter for ZnO catalysts in glycerol hydrogenolysis by enhancing catalytic activity and producing lower alcohols in good yields.
Sustainable Energy &... arrow_drop_down University of Lincoln: Lincoln RepositoryArticle . 2017Data sources: Bielefeld Academic Search Engine (BASE)add ClaimPlease grant OpenAIRE to access and update your ORCID works.This Research product is the result of merged Research products in OpenAIRE.
You have already added works in your ORCID record related to the merged Research product.This Research product is the result of merged Research products in OpenAIRE.
You have already added works in your ORCID record related to the merged Research product.All Research productsarrow_drop_down <script type="text/javascript"> <!-- document.write('<div id="oa_widget"></div>'); document.write('<script type="text/javascript" src="https://beta.openaire.eu/index.php?option=com_openaire&view=widget&format=raw&projectId=10.1039/c7se00199a&type=result"></script>'); --> </script>For further information contact us at helpdesk@openaire.eumore_vert Sustainable Energy &... arrow_drop_down University of Lincoln: Lincoln RepositoryArticle . 2017Data sources: Bielefeld Academic Search Engine (BASE)add ClaimPlease grant OpenAIRE to access and update your ORCID works.This Research product is the result of merged Research products in OpenAIRE.
You have already added works in your ORCID record related to the merged Research product.This Research product is the result of merged Research products in OpenAIRE.
You have already added works in your ORCID record related to the merged Research product.All Research productsarrow_drop_down <script type="text/javascript"> <!-- document.write('<div id="oa_widget"></div>'); document.write('<script type="text/javascript" src="https://beta.openaire.eu/index.php?option=com_openaire&view=widget&format=raw&projectId=10.1039/c7se00199a&type=result"></script>'); --> </script>For further information contact us at helpdesk@openaire.eudescription Publicationkeyboard_double_arrow_right Article , Journal 2020Publisher:Elsevier BV Authors: Ziyaad Mohamed; Venkata D.B.C. Dasireddy; Sooboo Singh; Holger B. Friedrich;Abstract Pt supported on TiO2 and ZrO2 catalysts were synthesized via wet impregnation and deposition precipitation methods. The catalysts were tested for CO removal from reformate gas following the water-gas shift reaction for on-board fuel processors. Tests included oxidation of CO to CO2, preferential oxidation of CO to CO2 in the presence of H2 (PROX), and hydrogenation of CO to CH4 (selective methanation, SMET). The Pt–ZrO2 catalysts showed better metal dispersions, particle sizes, lower degrees of reduction and higher oxygen storage capacities than the TiO2 supported catalysts. All catalysts showed low activity for the oxidation of CO in the PROX reaction, due to H2 and O2 spillover effects. ZrO2, with its high reducing properties and strong metal-support interactions, was found to be the best support for hydrogenation of CO. ZrO2 induced small well-dispersed Pt particles that were key parameters in this reaction. Both Pt–ZrO2 catalysts showed CO conversions over 99% above 350 °C with high CH4 selectivities (99%). The study shows advantageous effects of strong metal to support interactions, like participation of MOx (support) species in activating the CO molecule. The CO concentration was effectively reduced to the desired ppm levels (
add ClaimPlease grant OpenAIRE to access and update your ORCID works.This Research product is the result of merged Research products in OpenAIRE.
You have already added works in your ORCID record related to the merged Research product.This Research product is the result of merged Research products in OpenAIRE.
You have already added works in your ORCID record related to the merged Research product.All Research productsarrow_drop_down <script type="text/javascript"> <!-- document.write('<div id="oa_widget"></div>'); document.write('<script type="text/javascript" src="https://beta.openaire.eu/index.php?option=com_openaire&view=widget&format=raw&projectId=10.1016/j.renene.2019.10.088&type=result"></script>'); --> </script>For further information contact us at helpdesk@openaire.eumore_vert add ClaimPlease grant OpenAIRE to access and update your ORCID works.This Research product is the result of merged Research products in OpenAIRE.
You have already added works in your ORCID record related to the merged Research product.This Research product is the result of merged Research products in OpenAIRE.
You have already added works in your ORCID record related to the merged Research product.All Research productsarrow_drop_down <script type="text/javascript"> <!-- document.write('<div id="oa_widget"></div>'); document.write('<script type="text/javascript" src="https://beta.openaire.eu/index.php?option=com_openaire&view=widget&format=raw&projectId=10.1016/j.renene.2019.10.088&type=result"></script>'); --> </script>For further information contact us at helpdesk@openaire.eudescription Publicationkeyboard_double_arrow_right Article , Journal 2019Publisher:Royal Society of Chemistry (RSC) Mzamo L. Shozi; Venkata D. B. C. Dasireddy; Sooboo Singh; Alisa Govender; Pheladi Mohlala; Holger B. Friedrich;doi: 10.1039/c9se00045c
Incorporation of Re in supported Ni catalysts greatly improves hydrogenolysis of glycerol to mono-alcohols via increased acidity, dispersion and metal–support interaction.
Sustainable Energy &... arrow_drop_down Sustainable Energy & FuelsArticle . 2019 . Peer-reviewedLicense: Royal Society of Chemistry Licence to PublishData sources: Crossrefadd ClaimPlease grant OpenAIRE to access and update your ORCID works.This Research product is the result of merged Research products in OpenAIRE.
You have already added works in your ORCID record related to the merged Research product.This Research product is the result of merged Research products in OpenAIRE.
You have already added works in your ORCID record related to the merged Research product.All Research productsarrow_drop_down <script type="text/javascript"> <!-- document.write('<div id="oa_widget"></div>'); document.write('<script type="text/javascript" src="https://beta.openaire.eu/index.php?option=com_openaire&view=widget&format=raw&projectId=10.1039/c9se00045c&type=result"></script>'); --> </script>For further information contact us at helpdesk@openaire.eumore_vert Sustainable Energy &... arrow_drop_down Sustainable Energy & FuelsArticle . 2019 . Peer-reviewedLicense: Royal Society of Chemistry Licence to PublishData sources: Crossrefadd ClaimPlease grant OpenAIRE to access and update your ORCID works.This Research product is the result of merged Research products in OpenAIRE.
You have already added works in your ORCID record related to the merged Research product.This Research product is the result of merged Research products in OpenAIRE.
You have already added works in your ORCID record related to the merged Research product.All Research productsarrow_drop_down <script type="text/javascript"> <!-- document.write('<div id="oa_widget"></div>'); document.write('<script type="text/javascript" src="https://beta.openaire.eu/index.php?option=com_openaire&view=widget&format=raw&projectId=10.1039/c9se00045c&type=result"></script>'); --> </script>For further information contact us at helpdesk@openaire.eu
