• Energy Research

Abstract The paper shows the preliminary design of the superheated steam generator to be used in a novel hydrogen production and energy conversion system based on the combustion of aluminum particles with water. The system is aimed at producing hydrogen and pressurized superheated steam, using the heat released by the Al–H2O reaction. The interest on this type of technology arises because of the possibility of obtaining hydrogen with very low pollutant and greenhouse gas emissions, compared to the traditional hydrogen production systems, such as the steam reforming from methane. The analysis of the combustion chamber and the heat recovery system is carried out by means of a lumped and distributed parameter numerical approach. The multi phase and gas mixture theoretical principles are used both to characterize the mass flow rate and the heat release in the combustion chamber and within the heat exchangers in order to relate the steam generator performance to the system operating parameters. Finally, the influence of the steam generator performance on the whole energy conversion system behavior is addressed, with particular care to the evaluation of the total power and efficiency variation with the combustion parameters.

Abstract The working cycle of a novel hydrogen and power generation system based on aluminum combustion with water is analyzed in order to evaluate the best performance in terms of energy conversion efficiency. The system exploits the exothermic reaction between aluminum and steam and produces thermal power for a super-heated steam cycle and hydrogen as a by-product of the reaction. A lumped and distributed parameter approach is adopted for simulating the whole thermo-dynamics cycle and it includes the main components such as the combustion chamber, the steam generator, the turbine and the heat exchangers. Proper numerical models are created to account for the physical phenomena occurring in each of the considered component and are validated against experimental measurements available in literature or theoretical formulations. In particular several plant configurations corresponding to different working cycles are investigated, and their performance in terms of global efficiency, power output and hydrogen yield is discussed. The adoption of a turbine back pressure working cycle demonstrates to reduce the aluminum consumption and to enhance the electrical power conversion efficiency.

In this paper a detailed analysis focused on lumped parameters numerical modeling of high speed direct injected internal combustion engine cooling systems is presented and discussed. More in details, the cooling systems here studied are characterized by extreme performance, both in terms of circulating flow rates and thermal loads. First of all, a comprehensive description of the simulation environment properly tailored for cooling systems modeling is introduced and all its geometric, fluid-dynamic and thermodynamic characteristics are described in depth. Then, the model has been validated through an exhaustive numerical vs. experimental comparison, involving both cold and hot engine operation, for a wide range of rotational speeds. The general good accordance obtained between calculated and measured results clearly demonstrate the reliability of the numerical model. Finally, the main capabilities of the lumped parameters model as a useful design tool have been evidently showed by investigating different cooling circuit configurations and comparing the results here obtained with the baseline solution.

Abstract The paper focuses on the design of the experimental apparatus aimed at analyzing the performance of the combustion chamber of a cogeneration system based on the reaction of liquid aluminum and water steam. The cogeneration system exploits the heat released by the oxidation of aluminum with water for super-heating the vapor of a steam cycle and simultaneously producing hydrogen. The only by-product is alumina, which in a closed loop can be recycled back and transformed again into aluminum. Therefore, aluminum is used as an energy carrier to transport the energy from the alumina reduction plant to the location of the proposed system. The water is also used in a closed loop since the amount of water produced employing the hydrogen obtained by the proposed system corresponds to the oxidizing water for the Al/H 2 O reaction. This study investigates the combustor where the liquid aluminum–steam reaction takes place. In particular, the design of the combustion chamber and the interaction between the liquid aluminum jet and the water steam flow are evaluated using a numerical and an experimental approach. The test rig is specifically designed for the analysis of the liquid aluminum injection in a slightly super-heated steam stream. The first experiments are carried out to verify the correct behavior of the test rig. Thermography is employed to qualitatively assess the steam entrainment of the liquid aluminum jet. Finally, the experimental measurements are compared with the multi-dimension multi-phase flow simulations in order to estimate the influence of varying operating conditions on the reaction behavior. Further analysis will concern experiments aimed at investigating the reaction efficiency for different aluminum and water steam mass flow rates as well as the effects of the relative fuel/oxidizer speeds.