• Energy Research
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Ceramic-based packed bed solutions are becoming more common in the energy fields as both thermal energy storage and heat exchanger. Such solutions are usually designed for the working temperature ranges above600 ◦C, thus thermal radiation becomes significant and even acts as the dominant heat transfer mechanism. Therefore, applying high-temperature coatings with different thermal properties could be an efficient way in enhancing the performance of these applications. In this work, the high-temperature long residency and cyclic thermal stability of six inorganic coatings applied on a ceramic substrate are investigated. Both qualitative and quantitative assessments are performed. The results show that HIE-Coat 840MX and Pyropaint 634 ZO exhibit excellent thermal stability performance both at high-temperature testing (1000 ◦C) and under thermal cycle testing (400 ◦C–800 ◦C). TiO2 based coatings could be a viable solution if the powder is pre-treated to avoid polymorph transition during the operation. Stainless steel 304 powder-based coating could also be a possible solution, since the adhesive curbs the oxidation and hinders the coating from deterioration. Contrarily, Pyromark2500 and MgO-based coating show different degradation problems that limit their exploitation in high-temperature applications undergoing thermal cycles. The investigated coatings show a wide range of thermal emissivity (between 0.6 and 0.9), with stable or decreasing trends with temperature. This enables a potential20% change of the effective thermal conductivity for the packing structure. This work is a stepping-stone towards further detailed experimental studies on the influence of coatings on various packed bed thermal storage systems, and thus offer a new option in improving the performances of the energy equipment with packed bed systems. QC 20220502

The object of research is high-temperature thermal units – rotary kilns. Rotary kilns are used in various industries. The specified equipment has high energy consumption, which is due to the operating conditions of the kiln units in compliance with a number of technological requirements for thermal conditions. At the same time, the problem of high energy intensity is aggravated by the low level of useful energy resources. One of the most problematic places is the thermal and operational characteristics of rotary kilns, as well as the use of lining with increased thermal resistance.Physical and mathematical models are used. It is proposed to calculate a rotary kiln for the production of cement with a size of 5x185 m and a capacity of 75 t/h. A mathematical model is obtained for computer simulation of technological processes in rotary cement kilns. The possibilities of reducing fuel consumption by increasing the thermal resistance of the lining of a rotary kiln are considered. The most energy-intensive zones are determined and the effect on the thermal efficiency of using additional thermal insulation in various energy zones in a rotary kiln is analyzed. Calculations and the results of a numerical experiment are presented. The most rational areas for the use of lining with additional thermal insulation are determined. It is found that with the integrated application of the proposed method, fuel consumption in a thermal unit can be reduced by 9 %. And an increase in the thermal resistance of the lining installed in high temperature zones will increase the energy efficiency of the thermal unit. A significant advantage of this method is the fact that an increase in kiln productivity does not require additional fuel consumption, an increase in temperature, or an increase in the enthalpy of combustion products.In the future, it is planned to study the mechanism for establishing a heat-insulating layer in the refractories of the lining, determining their optimal thermal efficiency and stress-strain state to eliminate the possibility of destruction. As well as determining the optimal structural form of the refractory and the cell with thermal insulation.

This paper analyses the possible applications of medium temperature solar concentration technologies, Compound Parabolic Collector, Linear Fresnel Collector and Parabolic Trough Collector in the Spanish industrial sector. Results of this study allow evaluating whether or not solar technologies are an alternative to conventional sources. This possibility is analyzed energetically, economically and environmentally. Results show that the percentage of solar use is decisive in determining the true thermal energy generation cost. The other essential parameter is the solar field area due to produce economy of scale that reduces investment costs. Fluid temperature has significant influence mainly in Compound Parabolic Collector technology. Results obtained in this paper collect multiple alternatives and allow comparing for different scenarios the suitability to replace conventional energy sources by thermal energy obtained from medium temperature solar concentration technologies from an economic perspective. For instance, for percentage of solar use equal to 100%, the lowest thermal energy generation costs for each technology are 1.3 c€/kWh for Compound Parabolic Collector technology, fluid temperature of 100 °C and industrial process located in Seville, 2.4 c€/kWh for Linear Fresnel Collector technology, fluid temperature of 170 °C and industrial process located in Jaen, 3.3 c€/kWh for technology, fluid temperature of 350 °C and industrial process located in Jaen. These costs are lower than conventional energy sources costs.

As feature density increases within microelectronics, so does the dissipated power density, which puts an increased demand on thermal management. Thermal interface materials (TIMs) are used at the interface between contacting surfaces to reduce the thermal resistance, and is a critical component within many electronics systems. Arrays of carbon nanotubes (CNTs) have gained significant interest for application as TIMs, due to the high thermal conductivity, no internal thermal contact resistances and an excellent conformability. While studies show excellent thermal performance, there has to date been no investigation into the reliability of CNT array TIMs. In this study, CNT array TIMs bonded with polymer to close a Si-Cu interface were subjected to thermal cycling. Thermal interface resistance measurements showed a large degradation of the thermal performance of the interface within the first 100 cycles. More detailed thermal investigation of the interface components showed that the connection between CNTs and catalyst substrate degrades during thermal cycling even in the absence of thermal expansion mismatch, and the nature of this degradation was further analyzed using X-ray photoelectron spectroscopy. This study indicates that the reliability will be an important consideration for further development and commercialization of CNT array TIMs.

Active use of heat accumulators in the thermal system has the potential for achieving flexibility in district heating with the power to heat (P2H) units, such as electric boilers (EB) and heat pumps. Thermal storage tanks can decouple demand and generation, enhancing accommodation of sustainable energy sources such as solar and wind. The overview of flexibility, using EB and storage, supported by investigating the nature of thermal demand in a Danish residential area, is presented in this paper. Based on the analysis, curve-fitting tools, such as neural net and similar day method, are trained to estimate the residential thermal demand. Utilizing the estimated demand and hourly market spot price of electricity, the operation of the EB is scheduled for storing and fulfilling demand and minimizing energy cost simultaneously. This demonstrates flexibility and controlling the EB integrated into a multi-energy system framework. Results show that the curve fitting tool is effectively suitable to acknowledge thermal demands of residential area based on the environmental factor as well as user behaviour. The thermal storage has the capability of operating as a flexible load to support P2H system as well as minimize the effect of estimation error in fulfilling actual thermal demand simultaneously.

The reduction of energy consumption in the building sector has promoted the spread of the NZEB (Nearly Zero Energy Building) model. A future target is represented by positive-energy buildings (PEB), which produce more energy than they consume. The study is centred on the examination of some peculiarities of NZEB through a case study and on the analysis of opportunities for further increase in energy performance, to trace the road that each designer should take, through an extensive evaluation of the potentials variations on the project that could lead to better results. The project assessments are developed through a dynamic simulation model and the data from the monitoring of the building’s performance are used to evaluate the actual energy saving conditions. The analyses demonstrate the importance of an accurate design of the envelope and technical building systems associated with a smart management of the control systems and the setting of the set points, for the optimal operation of the systems. Ambitious but feasible design choices and an accurate analysis of the possibility of increasing the energy performance of a NZEB can lead to reaching the PEB target and energy independence, enhancing the production of energy from renewable sources.

Encapsulation of Phase Change Materials (PCM) for energy storage, thermal comfort and many other energy applications is receiving much attention due to the fact that material, physical characteristics and geometry of the container can affect drastically the thermal performance of the PCM. Phase change materials have usually low thermal conductivity which impairs their thermal charging and discharging characteristics. Different geometries were investigated including rectangular, cylindrical and spherical with and without extended surfaces to investigate the heat charge processes. Cylindrical geometries of circular sections were intensively investigated while cylinders and tubes with elliptic and elongated cross section received less attention, although they may have better thermal performance for thermal storage. The present numerical investigation is aimed at contributing to better understand the effects of the elliptic geometry and how the different geometrical and operational parameters can affect the thermal performance of the enclosed PCM. The present investigation reports the results of a numerical study on elliptic cylinders containing PCM under melting conditions. The 2D inward melting problem is modeled by using a CFD code. The numerical model is based upon the enthalpy-porosity method along with the finite control volume techniques. The numerical predictions are validated against available experimental results. The inward melting process is analyzed for two orientations of the elliptic enclosures. Due to the flow field effect namely the Rayleigh-Bénard convection, the numerical results showed that the horizontal elliptic enclosure have higher melting rate and hence lower total melting time compared to those of the vertical elliptic enclosure.