• Energy Research
• 2021-2025close

This chapter introduces the role of thermal energy storage (TES) systems in enhancing building energy flexibility and demand-side management. Different forms of TES and their related storage media and materials were reviewed and the link between TES systems and energy flexibility was discussed. The role of TES systems in building energy flexibility and demand-side management was then addressed in terms of long-term (seasonal) and short-term storage applications. Different TES materials or media, such as sensible heat storage by water tanks, aquifers, and latent heat storage by various phase change materials can be considered. Furthermore, different techniques that can be utilized to manage the demand with the aid of TES systems are discussed. Different approaches, such as model predictive control as one of the most prominent ones, can be considered to maximize the benefit of TES in demand-side management, and hence energy flexibility.

Please refer to "Ma Q, Wang P, Fan J and Klar A. Underground solar energy storage via energy piles: an experimental study. 2021." for details.

Global trends in the efficiency, safety of energy systems and energy conservation actualize the task of developing new technologies for energy storage and transportation. The article considers current technologies of storage and accumulation of thermal energy, which can be used in central heating systems, and draws conclusions about the feasibility of their use. Also, the classification of energy storage systems is presented. The most perspective thermal energy storage, which can be used to equalize the load on the energy source to ensure the peak demand for heat with a high coefficient of utilization of the equipment capacity, is noted.

High supercooling and single functionalization are the main barriers to the large-scale application of microencapsulated phase-change materials (PCMs) in the construction industry. To address these issues, we propose a new inorganic microencapsulated PCM, PW@CaWO4, which was synthesized via the in situ polymerization method using inorganic CaWO4 as shell and phase-change paraffin wax (PW) as core. We investigated the effects of different emulsifiers and core-to-shell ratios on microcapsule properties and found that the PW@CaWO4 microcapsules have regular spherical topography and good uniformity in particle size. During the synthesis process, the CaWO4 shell provides convenient conditions for heterogeneous nucleation of PW and effectively reduces the supercooling degree. The minimum supercooling degree of the PW@CaWO4 microcapsules is only 1.00 ± 0.08 °C, which is 3.41 °C lower than that of PW. Moreover, the PW@CaWO4 microcapsules can absorb ultraviolet radiation and exhibit fluorescence, which originates from the peculiar WO42– structure in the CaWO4 shell, eliminating the need for doping other light-activating ions into the shell. The newly prepared microcapsules possess several advantages, including suitable particle size, low supercooling, good heat storage, high thermal conductivity, good short-wave ultraviolet absorption, peculiar fluorescence, excellent proof of leakage, and so on. The microcapsules can be applied to fluorescent architectural energy-saving coatings.

A two-phase thermosyphon is a passive system utilizing gravity to transfer working fluids. The working fluids of a two-phase thermosyphon must undergo vaporization and condensation in the same system. Two-phase thermosyphons can also be used as solar collectors. Traditional solar collectors utilize surface absorbers to convert incident solar radiation into thermal energy, but those systems feature a large temperature difference between the surface absorbers and heat transfer fluids, resulting in a reduction in the overall thermal efficiency. Volumetric solar absorbing fluids serve both as solar absorbers and heat transfer fluids, therefore significantly improving the overall efficiency of solar collectors. Comparing to pure fluids, nanofluids possess both enhanced thermal conductivity and solar absorption capacity as volumetric absorbing fluids. Nanofluids, when serving as volumetric solar absorbing fluids, are so far reported to work only at relatively low temperatures and in a single-phase heat transfer regime due to stability issue. This research investigates the possibility of using nanofluids, especially graphene oxide (GO) nanofluids, as volumetric solar absorbing fluids in two-phase thermosyphons. Despite their reputation as both stable and solar absorptive among nanofluids, graphene oxide nanofluids still deteriorate quickly under boiling-condensation processes (~100 °C). The solar transmittance of the GO nanofluids declines from 38 to 4%, during the first 24 h of testing. Further investigation shows that the stability deterioration is caused by the thermal reduction of GO nanoparticles, which mainly featured with de-carboxylation and de-hydroxylation. A commercial dye named acid black 52, when dissolved in water, exhibits great broadband solar absorption properties and excellent stability. It remains stable for over 199 days in two-phase thermosyphon, and their transmittance in solar spectral region varies less than 9%. The stability of acid black 52 aqueous solution is further confirmed with the 191-day enhanced radiation test, as it shows less than 5% transmittance change in solar spectral region.

Thermal conductivity plays an important role in energy storage when the materials are charging and discharging. This paper presents an experimental investigation of the evolution of thermal conductivity up to 600 °C in different concretes. Moreover, the thermal conductivity was measured during thermal fatigue cycles when temperature ranged between 300 and 600 °C, simulating the operation conditions in a storage system of molten salts in a Concentrating Solar Power Plant (CSP). Five concrete compositions were analysed using diverse types of aggregates with different thermal response, covering a wide range of the initial thermal conductivity. The results confirm that the loss of thermal conductivity with temperature during the first heating is mainly due to the free water loss. Moreover, the type of aggregate influences the overall thermal performance of concrete due to its thermal conductivity and the volumetric differences with the cement paste. Siliceous aggregates underwent the highest decrease of thermal conductivity of concrete (+50%) with regard to room temperature. Regarding the cooling phase, thermal conductivity recovers between 20% and 40% depending on the type of aggregate. The outcomes of the present study demonstrate that the assumption of a constant thermal conductivity value in numerical simulations to predict its thermal capacity for energy storage is not appropriate. Es una corrección a un artículo publicado en: Sol. Energy 214 (2021) 430–442. Peer reviewed

[EN]The expected performance of an innovative Pumped Thermal Energy Storage (PTES) system based on a closedloop Brayton-Joule cycle and integrated with a Concentrated Solar Power (CSP) plant are analysed in this study. The integrated PTES–CSP plant includes five machines (two compressors and three turbines), a central receiver tower system, three water coolers and three Thermal Energy Storage (TES) tanks, while argon and granite pebbles are chosen as working fluid and storage media, respectively. A sizing of the main components of the integrated plant has been firstly carried out for the design of an integrated PTES-CSP plant with a nominal net power of 5 MW and a nominal storage capacity of 6 equivalent hours of operation. Specific mathematical models have been developed in MATLAB-Simulink to simulate the PTES and CSP subsystem in different operating conditions, and to evaluate the thermocline profile evolution within the three storage tanks during/charging and discharging processes. A control strategy has finally been developed to determine the operating modes of the plant based on the grid service request, the solar availability, and the TES levels. The performance of the system during a summer and a winter day have been analysed considering the integration of the PTES subsystem in the Italian energy market for arbitrage. Results have demonstrated the technical feasibility of the hybridization of a PTES system with a CSP plant and the ability of the integrated system to participate to energy arbitrage, although a lower exergy roundtrip efficiency (about 54 %) has been observed with respect to the sole PTES system (about 60 %).