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This study highlights how Chinese economic development detrimentally impacted water quality in recent decades and how this has been improved by enormous investment in environmental remediation funded by the Chinese government. To our knowledge, this study is the first to describe the variability of surface water quality in inland waters in China, the affecting drivers behind the changes, and how the government-financed conservation actions have impacted water quality. Water quality was found to be poorest in the North and the Northeast China Plain where there is greater coverage of developed land (cities + cropland), a higher gross domestic product (GDP), and higher population density. There are significant positive relationships between the concentration of the annual mean chemical oxygen demand (COD) and the percentage of developed land use (cities + cropland), GDP, and population density in the individual watersheds (p < 0.001). During the past decade, following Chinese government-financed investments in environmental restoration and reforestation, the water quality of Chinese inland waters has improved markedly, which is particularly evident from the significant and exponentially decreasing GDP-normalized COD and ammonium (NH4+-N) concentrations. It is evident that the increasing GDP in China over the past decade did not occur at the continued expense of its inland water ecosystems. This offers hope for the future, also for other industrializing countries, that with appropriate environmental investments a high GDP can be reached and maintained, while simultaneously preserving inland aquatic ecosystems, particularly through management of sewage discharge.

This work presents a crude bioethanol fueled integrated power system for backup and off-grid applications. The system is based on ethanol steam reformation to hydrogen that is used in polymer electrolyte fuel cells to produce electricity. We introduce the system design and overall system specifications, and report the experimental process of defining specifications for the produced hydrogen quality, a key variable affecting the final system cost, efficiency and durability. Results from development of individual subsystems are also presented together with discussion on the complete system integration.

Photoexcitation and charge carrier thermalization inside semiconductor photocatalysts are two important steps in solar fuel production. Here, photoexcitation and charge carrier thermalization in a silicon wafer are for the first time probed by a novel, yet simple and user-friendly Attenuated Total Reflectance Infrared spectroscopy (ATR-IR) system.

Radiation use efficiency values estimation based on the biomass increment (one approach) and on NPP from eddy covariance (two approaches) estimation of NPP brings the values of 0.13, 0.40, and 0.47 g (C) MJ −1 , respectively. The productivity of terrestrial ecosystems is primarily reliant on the absorption of solar radiation energy and its conversion into biomass. Monteith (1977) first introduced the concept of radiation use efficiency (RUE), which expresses the effectiveness of a plant stand to use solar radiation for the formation of new biomass and to maintain existing biomass. The presented paper uses a long-term, decadal, time series of biomass data, which is based on forest inventory data and an allometric relation, and on the application of eddy covariance (EC) estimation of Net Primary Production (NPP). These approaches provide different values of light use efficiency (LUE). LUE is based on direct carbon exchange estimation, LUE i , which denotes instantaneous efficiency based on the relationship between the daily sum of incident global radiation (GR i ) and NPP and LUES, calculated as the ratio between the sum of NPP and the sum of GR i per growing season. RUE is based on direct yearly biomass increment expressed in carbon units (carbon = 0.5 × biomass) divided by the sum of GR i per year. The obtained values amount to 0.13, 0.40, and 0.47 g(C) MJ−1 for RUE, LUES, and LUE i , respectively. The higher value of LUE i reflects a direct relation with the efficiency of photosynthetic carbon pumping. In contrast, the RUE value, based on biomass inventories, is the result of woody mass formation that is caused by several mutually related physiological processes and “wastages” of radiation utilization.

Abstract Orange Peel Waste (OPW) is a widely produced residue whose management is complicated by its physical and chemical properties. Anaerobic digestion (AD), which is commonly used for the treatment and exploitation of many biodegradable wastes, is inefficient on OPW due to the presence of essential oils (mainly d -Limonene) as well as the low pH, which cause the process to be unstable. Here we explore the effect of alkaline pre-treatment of OPW and of the addition of granular activated carbon (GAC) and Zero Valent Iron (ZVI) in improving AD in two semi-continuous reactors at a laboratory scale. The addition and pre-treatment of ZVI/GAC were shown to help process stability up to a loading of 3 kgVS·m−3·d−1 and to increase methane production even at a sub-optimal pH. The investigation of the bacterial community, by high-throughput sequencing, has also increased our insight on their involvement in AD in the presence of ZVI, including its biotic oxidation. In addition, direct interspecies electron transfer was shown to play a role in the reactor supplemented with ZVI.

The building and construction sector is a large contributor to anthropogenic greenhouse gas emissions and consumes vast natural resources. Improvements in this sector are of fundamental importance for national and global targets to combat climate change. In this context, vertical greenery systems (VGS) in buildings have become popular in urban areas to restore green space in cities and be an adaptation strategy for challenges such as climate change. However, only a small amount of knowledge is available on the different VGS environmental impacts. This paper discusses a comparative life cycle assessment (LCA) between a building with green walls, a building with green facades and a reference building without any greenery system in the continental Mediterranean climate. This life cycle assessment is carried according to ISO 14040/44 using ReCiPe and GWP indicators. Moreover, this study fills this gap by thoroughly tracking and quantifying all impacts in all phases of the building life cycle related to the manufacturing and construction stage, maintenance, use stage (operational energy use experimentally tested), and final disposal. The adopted functional unit is the square meter of the facade. Results showed that the operational stage had the highest impact contributing by up to 90% of the total environmental impacts during its 50 years life cycle. Moreover, when considering VGS, there is an annual reduction of about 1% in the environmental burdens. However, in summer, the reduction is almost 50%. Finally, if the use stage is excluded, the manufacturing and the maintenance stage are the most significant contributors, especially in the green wall system.

High-power high-density lithium rechargeable batteries are necessary to meet the energy demand of electric vehicles and high-power stationary grids. Here, we present a straightforward method for obtaining carbon nanofibers (CNFs) as a polysulfide barrier in Li-S cells, resulting in a significant increase in cell performance. CNFs were coated both on the separator and on the cathode. The CNF-coated cathode showed a specific capacity of 1010 mA h g−1 after 250 cycles at 0.2 C, with a capacity fading of 0.021% per cycle. In addition, at 1 C, it delivered 946 mA h g−1, thus presenting a fast Li+ transport with a good capacity. This result turns CNFs-coated cathodes into a promising system for obtaining high-performance Li-S cells.

AbstractThe potential impacts of future climate scenarios on water balance and flow regime are presented and discussed for a temporary river system in southern Italy. Different climate projections for the future (2030–2059) and the recent conditions (1980–2009) were investigated. A hydrological model (Soil and Water Assessment Tool) was used to simulate water balance at the basin scale and streamflow in a number of river sections under various climate change scenarios, based on different combinations of global and regional models (global circulation models and regional climate models). The impact on water balance components was quantified at the basin and subbasin levels as deviation from the baseline (1980–2009), and the flow regime alteration under changing climate was estimated using a number of hydrological indicators. An increase in mean temperature for all months between 0.5–2.4 °C and a reduction in precipitation (by 4–7%) was predicted for the future. As a consequence, a decline of blue water (7–18%) and total water yield (11–28%) was estimated. Although the river type classification remains unvaried, the flow regime distinctly moves towards drier conditions and the divergence from the current status increases in future scenarios, especially for those reaches classified as I‐D (ie, intermittent‐dry) and E (ephemeral). Hydrological indicators showed a decrease in both high flow and low flow magnitudes for various time durations, an extension of the dry season and an exacerbation of extreme low flow conditions. A reduction of snowfall in the mountainous part of the basin and an increase in potential evapotranspiration was also estimated (4–4.4%). Finally, the paper analyses the implications of the climate change for river ecosystems and for River Basin Management Planning. The defined quantitative estimates of water balance alteration could support the identification of priorities that should be addressed in upcoming years to set water‐saving actions.