• Energy Research
• natural sciences close
• Applied Energy close

Abstract Microorganisms used in syngas fermentation require nutrients to grow and convert syngas (CO, H2 and CO2) into various products. Many of the essential nutrients can be provided by biochar. Poultry litter biochar (PLBC) contains minerals and trace metals and has a high pH buffering capacity, making it suitable as a nutrient supplement. The effects of PLBC loadings from 1 to 20 g L−1 on syngas fermentation were determined in 250 ml bottle assays. Results showed that 10 and 20 g L−1 PLBC significantly increased ethanol production compared to standard yeast extract (YE) medium. Fermentations in a 3L continuous stirred tank reactor (CSTR) with 10 g L−1 PLBC with and without 4-morpholineethanesulfonic acid (MES) showed 64% and 36% more ethanol production, respectively, than standard medium. The acetic acid accumulated at the beginning of fermentation was completely converted to ethanol in all media tested in the CSTR. These results demonstrate the feasibility of using PLBC medium without costly MES in the CSTR to enhance ethanol production from syngas for potential use at commercial scale.

Abstract Economically harvesting energy from a microbial fuel cell (MFC), increasing its electrical power production, and developing its role as a practical energy supply, needs a low-cost and high-performance design of the MFC compartments. According to this strategy, a novel monolithic membrane electrode assembly (MEA) was fabricated and evaluated as an air–cathode in a single-chamber MFC (SCMFC). The MEA was made of bacterial cellulose (BC), conductive multi-walled carbon nanotubes (CNT), and nano-zycosil (NZ). BC, as a nano-celluloses with oxygen barrier property, can maintain anaerobic conditions for the anode compartment. Binder-less CNT coating on BC avoids costly binders such as poly-tetra fluoro ethylene (PTFE) and Nafion and decreases the MEA charge transfer resistance. NZ, as a very cheap modifier, not only prevents the anolyte leakage but also provides more MEA’s active sites for the oxygen reduction reaction (ORR). The electrochemical performance of the MEA was compared to a PTFE- based gas diffusion electrode (GDE) in the SCMFC. The MEA cell provided a pulse power density of 1790 mW/m2, roughly twice as high as the pulse power density of GDE (920 mW/m2). SCMFC’s internal resistance decreased from 1.84 KΩ (with GDE) to 0.8 KΩ (with MEA). Also, the cell’s columbic efficiency increased from 4.2% (with GDE) to11.7% (with MEA). Additionally, the capacitance of the MEA (65 mF) was much higher than the value for GDE (0.73 mF). Thus, the MEA compared to the GDE showed higher performance in the SCMFC for electricity generation and wastewater treatment at a lower cost.

Abstract In a trial, 10 cucumber plants ( Cucumis sativus , variety ‘Virgo’ F 1 hybrids) were exposed continuously to a concentration of negative air ions exceeding 50 000/c.c. for a period of 40 days. The yield and productivity of the treated plants were compared with those of a control group of 10 plants in a matched-pairs experiment. An Index of Initial Vigour was developed to allow the subsequent production of the previously nursery-grown young plants to be related to their condition at the beginning of the trial. No effect on the total production or productivity at the end of the 40-day period was discerned, but the interim results (e.g. for the 10th day) are consistent with a model of reaction to stress governed by a negative-feedback mechanism. No harmful effects of the use of negatively ionised air were detected.

Abstract The almost two-dimensional steady-state rates of heat loss from arrays of uniformly-spaced vertical rectangular fins, extending upwards—in otherwise stagnant air—from horizontal heated bases, have been measured. (The vertical air gaps between the fins were closed at their sides, by insulated vertical end-barriers.) The effects of various combinations of height, thickness and spacing of the fins, for different base temperatures (in the range 40 to 100°C), have been studied. For the configuration considered, in a normal ambient environment (∼ 20°C), there is an optimal fin spacing (⋍ 16 mm) corresponding to the greatest steady-state rate of free convective/conductive heat loss through the air from the finned system, and this is almost independent of the temperature of the heat exchanger base (in the range 40–100°C). At this optimal spacing for base temperatures not greater than 50°C, the convective/conductive heat transfer rate from the array increases with the fin height up to about 60 mm, so that it would be uneconomic to employ taller fins if convection/conduction is dominant compared with radiation. If the radiation contribution is also considered, then the optimal spacing corresponding to the maximum total steady-state rate of heat loss through the air is somewhat less than the optimal spacing for which, under the same temperature conditions, the maximum steady-state rate of convective/conductive heat leak occurs. The greater the emissivity of the heat exchanger surfaces, the narrower the optimal uniform gaps between the fins. A two-dimensional finite-difference computer program has been composed to predict the temperature distribution throughout the heat exchanger for a stipulated ambient environmental temperature and experimentally-determined distribution of the heat transfer coefficient over the surfaces of the exchanger. This enables, for instance, any hot spots to be located prior to a proposed design being built.

In-situ biomethanisation reduces the CO2 in biogas to CH4 via direct H2 injection into an anaerobic digester, but volumetric methane production (VMP) is limited by organic loading. Ex-situ biomethanisation, where gaseous substrates are fed to pure or mixed cultures of hydrogenotrophic methanogens, offers higher VMP but requires an additional reactor and supply of essential nutrients. This work combined the two approaches in a novel hybrid application achieving simultaneous in-situ and ex-situ biomethanisation within an organically-loaded anaerobic digester receiving supplementary biogas. Conventional stirred-tank digesters were first acclimated to H2 addition, increasing biogas methane content from 50% to 95% and VMP from 0.86 to 1.51 L L-1 day-1 at a moderate loading rate of 3 g organic chemical oxygen demand per L per day (g CODorg L-1 day-1). Externally-produced biogas was then added to demonstrate simultaneous biomethanisation of endogenous and imported CO2. This further increased VMP to 2.76 L L-1 day-1 without affecting organic substrate degradation. In-situ CO2 reduction can alter digester pH by reducing bicarbonate buffering: the combined process operated stably at around pH 8.0 with 3-5% CO2 in the headspace. Microbial community analysis indicated the process was mediated by bacterial syntrophic acetate oxidation and highly enriched hydrogenotrophic methanogenic archaea (up to 97% of the archaeal population). This approach presents the opportunity to retrofit a single digester for H2 injection to convert and upgrade biogas from several others, minimising capital and operating costs by utilising both existing infrastructure and waste-derived feedstock nutrients for simultaneous biogas upgrading and power-to-methane.

The United Nations’ Sustainable Development Goals (SDGs) provide a guideline for humanity to respond to an array of pressing challenges. Due to our increasing need for energy supply and more stringent standards for environmental quality, having access to affordable and clean energy has been the foremost pursuit of SDG 7. Development in renewables represents a way to achieve this goal. Here, we establish a Footprint-Driver-Scenario (FDS) framework for accounting for the renewable energy footprint of 189 global economies based on a global multi-regional input − output (MRIO) model and identifying the major drivers behind based on the logarithmic mean Divisia index (LMDI) in 1990–2015, and projecting the national renewable energy footprint by 2030 based on the Shared Socioeconomic Pathways (SSPs) scenarios. We find that total and per capita renewable energy footprint varies substantially between nations. The improvement in energy efficiency (SDG 7.3) and decline in footprint-to-energy ratio contribute to the reduction of renewable energy footprint, as opposed to the per capita GDP, population, share of renewable energy in energy mix (SDG 7.2) and proportion of population with access to electricity (SDG 7.1), all of which lead to footprint increase considerably. Despite the great progress in SDGs 7.1–7.3 by 2030, the expected goals still cannot be fully reached in any of the SSP scenarios. Our research findings can assist policy makers in better understanding the critical role of renewable energy in achieving SDG 7. The FDS framework can be potentially applied to a wide range of SDGs at the global, national and sub-national scales.

Abstract Many organizations in the world are interested in waste management problems and their potential solutions. In order to solve these problems, a Japanese venture company has developed an innovative thermal decomposer for organic wastes called ERCM (Earth-Resource-Ceramic-Machine). The ERCM reactor employs electron injected air to promote the thermal decomposition reaction, while the effect of electron injection into air has not yet been clarified. An experimental work was performed using a fixed bed reactor to explore the effects of different parameters of electron injection into air, the reaction temperature and different feedstock on the syngas generation. The main purpose of this study is to clarify the phenomena occurring in the ERCM reactor where a direct current electric field is produced in the flame reaction zone to enhance the thermal decomposition of wastes. In this regard, a mathematical model for simulating the thermal decomposition of solid waste in the presence of an electric field have been developed. The equations of aero-thermochemistry are coupled to the balance equations for densities of charged species, and the Poisson equation for the electrical potential is solved. The model was validated by the experimental data and showed a good agreement. The results showed that the electric field significantly improves the stabilization of the flame. From the release behavior of CO and CO2, it is noted that the electron injection would affect the char combustion process significantly. Finally the effect of the flame reaction zone generated by the field induced ion wind on the thermal decomposition was investigated.

Abstract An experimental investigation of the steady-state rates of heat transfer from an array of vertical rectangular fins of 3 mm thickness and 250 mm length, protruding 60 mm perpendicularly upwards from a 250 mm × 190 mm horizontal rectangular base, is reported. For constant (to ±0·1°C) base temperatures between 40°C and 80°C, in an ambient environment of 20±0·2°C, the optimal separation of the parallel fins, corresponding to the maximum rate of heat loss, is 10·5±1·0 mm. The effects of the extent of the fin protrusions on the thermal performances of such vertical fins, on the same base, which was arranged to be either vertical or horizontal , have been studied. The experiments were performed with three different fin protrusions, namely 32 mm, 60 mm and 90 mm, for a base temperature of 40°C above that of the ambient environment. The steady-state rate of heat dissipation from the fin array increased slightly less than linearly with the fin protrusion for both orientations, but the relationship became closer to linear as the fin spacing was increased. A comparison of the abilities to dissipate heat to the room air from the same geometrical configuration having a rectangular fin array but positioned with vertical fins on a vertical base, vertical fins protruding upwards from a horizontal base, or horizontal fins on a vertical base, has been made. The orientation with vertical fins protruding upwards from the horizontal base, is the preferred option because of the relatively high rates of heat transfer that can then be achieved.