• Energy Research
• 2016-2025close
• natural sciences close
• 7. Clean energy close
• 11. Sustainability close
• 12. Responsible consumption close

In this study, levulinic acid (LA) was produced from rice straw biomass in co-solvent biphasic reactor system consisting of hydrochloric acid and dichloromethane organic solvent. The modified protocol achieved a 15% wt LA yield through the synergistic effect of acid and acidic products (auto-catalysis) and the designed system allowed facile recovery of LA to the organic phase. Further purification of the resulting extractant was achieved through traditional column chromatography, which yielded a high purity LA product while recovering ∼85% wt. Upon charcoal treatment of the resultant fraction generated an industrial grade target molecule of ∼99% purity with ∼95% wt recovery. The system allows the solvent to be easily recovered, in excess of 90%, which was shown to be able to be recycled up to 5 runs without significant loss of final product concentrations. Overall, this system points to a method to significantly reduce manufacturing cost during large-scale LA preparation.

Comfort temperature and sleep quality involving 20 participants were determined in two cases: Case A (arbitrary, controlled air-conditioner setting) and Case B (adjustment of 3 °C higher than the setting of Case A with cool bed linen). Data of indoor thermal comfort and electricity consumption were collected every night throughout the measurement period. Questionnaires on thermal comfort and sleep quality were distributed twice a night for a duration of three nights for each case; the first night was for respondents’ adaptation and the following two nights were for measurement. The sleep quality of the respondents was objectively measured using a commercially available activity tracker. Results found that most respondents were thermally comfortable in both cases, with 39% lower energy consumption reported for Case B compared to Case A. The thermal conditions of Case B were found to be more tolerable than those of Case A. Most respondents reported to have a calm and satisfied sleep for both cases. Comfort temperature and Sleep Efficiency Index (SEI) were found to be maintained in both cases.

A range of optical fibre-based sensors for the measurement of ethanol, primarily in aqueous solution, have been developed and are reviewed here. The sensing approaches can be classified into four groups according to the measurement techniques used, namely absorption (or absorbance), external interferometric, internal fibre grating and plasmonic sensing. The sensors within these groupings can be compared in terms of their characteristic performance indicators, which include sensitivity, resolution and measurement range. Here, particular attention is paid to the potential application areas of these sensors as ethanol production is globally viewed as an important industrial activity. Potential industrial applications are highlighted in the context of the emergence of the internet of things (IoT), which is driving widespread utilization of these sensors in the commercially significant industrial and medical sectors. The review concludes with a summary of the current status and future prospects of optical fibre ethanol sensors for industrial use.

AbstractPreparation of uniform, spherical Li4Ti5O12 with high tap density is significant to achieve a high volumetric energy density in lithium‐ion batteries. Herein, Li4Ti5O12 microspheres with variable tap density and tunable size distribution were synthesized by a newly designed industrial spray‐drying approach. The slurry concentration, sintering time, sintering conditions after spraying, and the effect of lithium/titanium molar ratio on the lithium‐ion (Li+) storage capability were investigated. A narrow particle size distribution of around 10 μm and a high tap density close to 1.4 g cm−3 of the Li4Ti5O12 spheres can be obtained under the optimized conditions. The Li4Ti5O12 spheres can deliver a much higher capacity of 168 mAh g−1 at a rate of 1 C and show a high capacity retention of 97.7 % over 400 cycles. The synthetic conditions are confirmed to be critical for improving the electron conductivity and Li+ diffusivity by adjusting the crystal and spatial structures. As‐prepared high‐performance Li4Ti5O12 is an ideal electrode for lithium‐ion batteries or capacitors; meanwhile, the presented approach is also applicable for preparing other kind of spherical materials.

Abstract Heat pipes and two-phase thermosyphons are highly efficient heat transfer devices utilizing continuous evaporation and condensation of working fluid for two-phase heat transport in closed systems. Because of the nearly isothermal and fully passive phase-change heat transfer mechanism, heat pipes and thermosyphons have found many applications in nuclear engineering, space technologies, and other energy systems. High-temperature heat pipes are used in nuclear microreactors to remove fission power from the primary system and are coupled with power conversion systems or process heat applications. Modeling of the two-phase flow phenomena inside a heat pipe is essential to its design and safety analysis. In this study, a comprehensive one-dimensional two-phase three-field flow model has been developed for the analysis of heat pipes in normal operation conditions and transients. The conservation or field equations of mass, momentum, and energy were developed for the liquid film, vapor, and droplet. In addition, constitutive models or correlations were reviewed thoroughly and provided for the closure of the three-field equations. Specific constitutive equations regarding interfacial mass and heat transfer at two interfaces, namely film-gas interface and gas-droplet interface, were reviewed for droplet entrainment and deposition rates as well as film and droplet evaporation rates. Additionally, mechanistic correlations of annular flow film thickness were recommended for the modeling of the thermosyphons without a wick as a critical constitutive correlation. Furthermore, experimental data needs from new experiments using a prototype working fluid or surrogate fluids for the model validation of high-temperature heat pipes in microreactors were recommended for future research.

Progressive urban density affects city centers especially and results in growing congestion, lack of parking spaces, and increasing environmental costs of transportation, causing increased air pollutant emissions and noise. These phenomena reduce the attractiveness of the city and result in a degradation of the quality of life for its residents. In light of these phenomena, there is a clear need for intelligent management of urban space using new technologies that would be complementary to existing intelligent transportation systems. Expanding information resources obtained from mobile cameras will have a positive impact on increasing the efficiency of transportation management and use of limited space in city centers. It will also have an impact on reducing external transport costs and increasing the quality of logistics services provided in the city. The main aim of the paper is to develop a concept of a transport management system in cities using mobile vision systems mounted on unmanned aerial vehicles. The model will concern the cases of lane occupation by freight vehicles and the analysis of parking spaces in the city in order to improve their management. The results of the developed model will contribute to the automation of the parking space management process and increase the efficiency of the use of city parking space resources.

The study assessed the effects of firewood usage on rural women health in Ogun State. Samples of 128 respondents were randomly selected from four local government areas of Ogun State. Data were collected with the aid of structured questionnaire. Percentages were used for data analysis. Majority of the respondents were married (91%) with a mean age of 50 years. Most of the respondents (86.7%) used firewood for cooking, the preference of the utilization of firewood over other alternatives was due to non-availability of other sources (40%) and availability of firewood (33%). Some perceived health effects on the respondents were discomfort caused by the smoke from the firewood (𝑥 ̅ = 2.81) and eyes irritation (= 2.53). The study recommended alternative energy sources that are with lesser health hazards be made readily available at subsidized rate in the rural areas since this was the major attractive driving force for the use of firewood.