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Microalgae are recognized as a third generation feedstock for biofuel production due to their rapid growth rates and lignin-free characteristics. In this study, a lipid extracted microalgal biomass residues was used as the raw material to produce isoprene, α-pinene and β-pinene with an engineered E. coli strain. We adopted an optimal sulfuric acid hydrolysis method (1:7 ratio of solid to acid solution, 32% (w/v) concentration of sulfuric acid solution at 90 °C for 90 min) to efficiently convert holocellulose into glucose efficiently (6.37 g/L). Futhermore, we explored a novel detoxification strategy (phosphoric acid/calcium hydroxide) to remove inhibitors and notably acetic acid, furfural and 5-hydroxymethylfurfural (5-HMF) were reduced by 5.32%, different number given later 99.19% and 98.22%, respectively. Finally, the fermentation concentrations of isoprene (223.23 mg/L), α-pinene (382.21 μg/L) and β-pinene (17.4 mg/L) were achieved using the detoxified hydrolysate as the carbon source, equivalent to approximately 86.02%, 90.16% and 88.32% of those produced by the engineered E. coli strain fermented on pure glucose, respectively.

AbstractWe have measured the effect of degradation on the I-V characteristics in APFO3:PCBM solar cells. The solar cell devices were subject to ambient air under simulated solar illumination. We found that the degradation resulted in a lowering of the fill factor and short circuit current while the open circuit voltage remained unchanged. In order to gain insight into what has caused the degraded I-V characteristics we have studied the active layer film using various techniques. We found clear spectral changes both in absorption and in photoinduced absorption spectroscopy correlated with increased carrier lifetimes and lowered mobility when comparing the degraded film with a pristine one. The results show a significant degradation of the active layer causing a lower fill-factor and short circuit current.

Abstract Three-dimensional (3D) metal halide perovskite solar cells (PSCs) have a power conversion efficiency that is now comparable with conventional silicon solar cells. For PSC applications to succeed in the market, long-term reliability under open-air conditions is essential. Recent experiments have shown that two-dimensional (2D) perovskites seem to exhibit good stability due to the presence of hydrophobic organic spacers, but 2D PSCs are incapable of generating and transporting a large amount of charge due to their extended optical bandgaps. Mixed dimensional perovskites with dimension lies between 2D and 3D recently became a promising candidate to sustain long-term stability and high performances concurrently to address this obstacle. The current research article presents the finding of simulation-based studies performed on novel device architecture consisting of ITO/Nb-Ti2O3/3D Perovskite/2D Perovskite/Spiro-OMeTAD/Au. Using optical simulation features of SCAPS, absorption of light is computed in the proposed device. The computational results show that the thickness of the 2D perovskite layer badly affects the solar cell parameters. A thin 2D perovskite behaves as a capped coating that avoids the deterioration of 3D perovskite in open-air environments. The effect of a multivalent defect in the 3D perovskite layer is mathematically modelled, and their impact on overall performance parameters are analyzed. The findings are compared to the same configuration results, except where the absorber layer’s multivalent defect has been substituted by a neutral defect of the same defect density of about (1011 cm−3). Results show that the multivalent defect leads to an underestimation of the efficiency by 4.2%.

The shipping industry faces a large challenge as it needs to significantly lower the amounts of Green House Gas emissions. Traditionally, reducing the fuel consumption for ships has been achieved during the design stage and, after building a ship, through optimisation of ship operations. In recent years, ship efficiency improvements using Machine Learning (ML) methods are quickly progressing, facilitated by available data from remote sensing, experiments and high-fidelity simulations. The data have been successfully applied to extract intricate empirical rules that can reduce emissions thereby helping achieve green shipping. This article presents an overview of applying ML techniques to enhance ships’ sustainability. The work covers the ML fundamentals and applications in relevant areas: ship design, operational performance, and voyage planning. Suitable ML approaches are analysed and compared on a scenario basis, with their space for improvements also discussed. Meanwhile, a reminder is given that ML has many inherent uncertainties and hence should be used with caution.

AbstractThe planetary boundary framework constitutes an opportunity for decision makers to define climate policy through the lens of adaptive governance. Here, we use the DICE model to analyze the set of adaptive climate policies that comply with the two planetary boundaries related to climate change: (1) staying below a CO2 concentration of 550 ppm until 2100 and (2) returning to 350 ppm in 2100. Our results enable decision makers to assess the following milestones: (1) a minimum of 33% reduction of CO2 emissions by 2055 in order to stay below 550 ppm by 2100 (this milestone goes up to 46% in the case of delayed policies); and (2) carbon neutrality and the effective implementation of innovative geoengineering technologies (10% negative emissions) before 2060 in order to return to 350 ppm in 2100, under the assumption of getting out of the baseline scenario without delay. Finally, we emphasize the need to use adaptive path-based approach instead of single point target for climate policy design.

A field experiment was conducted during 1993–1995 to study the effect of industrial effluent on the initial growth of Azadirachta indica A. Juss. (Neem) in arid region. The effluent released from textile industry had high pH, EC, SAR and RSC. Various treatments were: irrigation with effluent only (W1), effluent mixed with canal water at 1:1 ratio (W2), gypsum‐treated effluent (W3), gypsum‐treated soil (W4) and wood ash‐treated soil (W5). W5 was the best treatment where neem attained 218 cm height, 118 cm crown diameter and 11.2 cm collar circumference at 28 months of age; followed by W1 treatment, where trees were on an average 186 cm tall and had 104 cm crown diameter and 9.4 cm collar circumference. Growth of the seedlings was the poorest in W2treatment. Increase in biomass accumulation over W2 treatment (1.89 kg tree−1) was 3.6 fold in W5, 2.1 fold in W1, 2.0 fold in W4 and 1.4 fold in W3 treatments. Though effluent application increased soil organic matter, electrical conductivity and in some cases pH also, but gypsum‐ and wood ash‐ treated soil ameliorated the pH by 0.25 units in comparison to the initial data. These results suggest that industrial wastewater can be effectively used to boost up establishment and growth of Neem (Azadirachta indica) in arid zone. Addition of wood ash improves the rate of growth. Irrigation with industrial effluent caused slight increase in electrical conductivity and decline in the soil pH. Santrauka Eksperimentas vyko 1993–1995 m. siekiant ištirti pramoninių nuotekų poveikį Azadirachta indica A. Juss. (Neem) sodinukų augimo pradžiai sausringuose regionuose. Tekstilės pramonės išleidžiamų nuotekų didelės pH rodiklio reikšmės, elektrinis laidumas, natrio adsorbcijos santykis ir natrio karbonato liekana. Tiriant taikyti įvairūs dirvožemio apdorojimo būdai: drėkinta tik nuotekomis (W1 ), nuotekos maišytos su kanalo vandeniu santykiu 1:1 (W2 ), nuotekos veiktos gipsu (W3 ), į dirvožemį dėta gipso (W4 ) ir dirvožemis tręštas medienos pelenais (W5 ). Efektyviausias buvo W5 apdorojimo būdas. 28 mėnesių augalai siekė 218 cm aukštį, jų vainiko skersmuo buvo 118 cm, žiedo perimetras – 11,2 cm. Stebint W1 apdorojimo tipą, medžiai buvo vidutiniškai 186 cm aukščio, vainikas – 104 cm skersmens, žiedai 9,4 cm perimetro. Blogiausiai sodinukai augo apdorojant W2 būdu. Nors naudojant nuotekas dirvožemio organinių medžiagų kiekis, elektrinis savitasis laidumas ir kai kuriais atvejais pH reikšmė padidėjo, tačiau gipsu ir medienos pelenais apdorotame dirvožemyje pH padidėjo per 0,25 vienetus, palyginti su pirminiais duomenimis. Šie rezultatai rodo, kad pramoninės nuotekos gali būti efektyviai naudojamos Neem (Azadirachta indica) želdinti ir auginti sausose teritorijose. Medienos pelenai pagerino augimo spartą. Drėkinimas pramoninėmis nuotekomis lėmė nežymų elektrinio savitojo laidumo augimą ir dirvožemio pH sumažėjimą. Резюме Экспериментальное поле возделывалось в 1993–1995 гг. с целью изучить воздействие промышленных стоков на начало роста Azadirachta indica A. Juss. (Neem) в засушливых районах. В стоках от производства текстиля высоко значение pH, электропроводимость, соотношение адсорбции натрия и остаток карбоната натрия. Применялись разные способы обработки почвы: орошение только стоками (W1 ); смесью стоков с водой из канала в соотношении 1:1 (W2 ); стоками, обработанными гипсом (W3 ); обработка почвы гипсом (W4 ) и удобрение древесной золой (W5 ). Наиболее эффективным способом оказалась обработка древесной золой. Высота растений в возрасте 28 месяцев составляла 218 см, венчик в поперечнике – 118 см, цветок – 11,2 см. После обработки почвы по типу W1 растения достигали 186 см в высоту, венчик в поперечнике – 104 см, цветок – 9,4 см. Наименее эффективным для растений способом оказалась обработка почвы по типу W2 . Несмотря на то, что при применении стоков количество органических веществ в почве, электропроводимость и в некоторых случаях значение pH увеличилось, однако при обработке почвы гипсом и древесной золой pH увеличилось более чем на 0,25 единиц по сравнению с начальными данными. Эти результаты показали, что промышленные стоки могут эффективно применяться для озеленения и выращивания Neem (Azadirachta indica) на засушливых территориях. Древесная зола ускоряла рост растений. Орошение промышленными стоками способствовало незначительному увеличению электропроводимости и уменьшению в почве pH.

It has been established that Wave Energy Converters efficiency can be improved by control. One of the main challenges of reactive control is the non-causality of the optimal controller. This study presents a methodology to solve the non-causality issue by providing a deterministic forecast of the controlled body velocities. This forecast is achieved by using the measurements of the states of the most up wave device of the array. The reactive control approach also implies strong instabilities due to the extreme dynamics of the controlled devices. The proposed method suggests to mitigate this behavior by applying a window function on the optimal controller impedance. In order to maximize the efficiency of the resulting control and ensure the robustness of the system, a stability analysis is conducted. Optimal sets of parameters are determined and applied to a time domain simulation of an array of 10 cylindrical floating WECs. The results obtained show an average efficiency of the array of 83% of the maximum energy retrievable in the waves.