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Abstract Specification by central government of the heating levels which are to be maintained in British school buildings has recently been altered. This paper is concerned with examining the nature of changes that have been made by comparing present requirements with their counterparts during the preceding one hundred years. Attention is focused on the apparently contradictory implications of these changes for those charged with responsibility for maintaining heating levels in school buildings while, at the same time, conserving fuel. It is suggested that the new statutory requirements present those who are responsible with a duty which may, in practical terms, prove difficult or costly to discharge. Although discussion is specifically restricted to British school buildings, issues are raised which are pertinent to attempts to integrate regulation of heating with control of fuel consumption in other types of non-domestic buildings both in Britain and abroad.

Abstract Wood biomass char was used in a direct carbon fuel cell (DCFC) as an alternative fuel. This has many advantages because the DCFC is a high-efficiency system and wood biomass is a carbon-free and regenerative material. Several analytical techniques were employed to analyze the characteristics of three fuels, their effects on the cell’s performance, and the electrochemical reactions between the fuels and the electrolyte in the system. The morphological and textural characteristics of biomass char were similar to those of two types of coal used as fuels for a DCFC system in spite of the char’s significantly lower carbon content. A practical evaluation of the fuels used in the DCFC system was conducted, and when using the biomass char, the maximum power density was 60–70% that of the corresponding value for coal under the same conditions. The performance of the biomass char fuel was improved by stirring. The possibility of its practical application was also discussed.

Abstract Hydrothermal treatment (HT) is one of the efficient approaches for upgrading municipal solid waste (MSW). In the present study, emission characteristics of polycyclic aromatic hydrocarbons (PAHs) from hydrothermally treated municipal solid waste (H-MSW) combustion alone and H-MSW/coal co-combustion were investigated at different temperatures. The results showed that for all fuel combustion, the majority of PAHs were 3- or 4-ring PAHs. In addition, flue gas had the highest yields of PAHs followed by fly ash and bottom ash, while the ring number of dominated PAHs in fly ash was higher than those in flue gas and bottom ash. Compared to MSW, H-MSW combustion generated less PAHs at the value of 1131.95–7649.24 μg/g. The blending of H-MSW and coal reduced total PAH emissions and positive interactions were observed between H-MSW and coal during co-combustion. The toxicity equivalent quantity (TEQ) values of the PAHs from combustion were in the order MSW > H-MSW > H-MSW/coal, which was consistent with the total PAH emissions. The present study illustrated that significant reduction of PAH emissions and toxicity from combustion could be achieved by HT and the blending of H-MSW and coal.

It is conventionally believed that there are no self-sustained thermoacoustic oscillations in the absence of acoustic modes in combustors. However, such oscillations (also known as intrinsic thermoacoustic instability) are recently found to occur in a premixed combustor with a mean flow present but no acoustic eigenmodes involved. Practical combustors are associated with entropy waves, pressure jump and mean flow, which are ignored in previous studies without justification. In this work, an entropy-involved energy measure is defined and used to study the stability behaviors of intrinsic thermoacoustic modes. The concepts and methods are exemplified with the classical time-delay n–τ unsteady heat release model. The intrinsic thermoacoustic eigenmodes are found to be related to not only a flame transfer/describing function but also the acoustic impedance at the flame, which is boundary-dependent. It is shown that the predicted frequency ωfr of the intrinsic modes and the critical gain nc depend on the ratio T¯2/T¯1 between the after- and before-combustion temperatures and the inlet mean flow Mach number M¯1. Comparison is then made between the present results and those available in literature. Good agreement is obtained for ωfr. Furthermore, the predicted stability of intrinsic modes based on calculated nc is found to agree well with direct numerical simulations (DNS). It is also interesting to show that as T¯2/T¯1→1, the critical gain as predicted from the previous models is nc→+∞, which means that all intrinsic eigenmodes are stable. However, the present works shows that nc→1.0. Further illustration is then performed by conducting case studies of measured flame transfer and describing functions in premixed combustors. The present work opens up an alternative but more applicable way to study intrinsic thermoacoustic oscillations via the entropy-involved energy measure.

Metal-based fuel-borne catalysts (FBCs) have been used with diesel fuels to effectively reduce soot and diesel particulate matter (DPM) emissions from both on-road and off-road applications. However, there is a lack of detailed investigations on the potential changes in the properties of particulates, when FBCs-doped fuels are combusted in diesel engines. This study fully evaluates the potential impacts of ferrocene-doped ultralow sulfur diesel (ULSD) fuels on physical, chemical and toxicological characteristics of the particulates emitted by a single cylinder, direct-injection diesel engine working at a constant speed and at three engine loads. The results indicated that ferrocene-doped fuels could effectively reduce the particulate mass and elemental carbon (EC) emissions, while increasing the proportion of both organic carbon (OC) and water-soluble organic carbon (WSOC) in particles. Particle-phase PAHs and n-alkanes emissions increased with an increase of Fe in the fuels. Ferrocene addition also led to lower soot ignition temperature and activation energy. However, the total number emissions of particles from ferrocene-doped fuels dramatically increased due to the formation of Fe-rich nuclei mode particles. Compared to pure ULSD, the particles emitted from ferrocene-doped fuels showed a slight decline in cell viability. The Fe in the particles and the changes in chemical composition of particulates are thought to be responsible for the variation of cell viability.

Abstract This paper deals with an optimization of the Stirling engine regenerator’s. Firstly, different materials are experimented (Stainless Steel, Copper, aluminum and Monel 400). The engine performances and the state of each material after 15 h of use are considered. The Stainless steel was the material that best satisfies these two conditions. Five regenerators in stainless steel with different porosities were manufactured and experimented (95%, 90%, 85%, 80% and 75%). Porosity that gives the best trade-off between maximizing the engine brake power, maximizing the heat transfer and minimizing the pressure drops, was retained. Thus, the regenerator in stainless steel with porosity of 85% was considered as the most suitable matrix maximizing the Stirling engine performances and minimizing heat and friction losses.

Abstract The Biofuels Directive sets reference values for the quantity of biofuels and other renewable fuels to be placed on the transport market. Biogas from agricultural crops can be used to meet this directive. This paper investigates biogas production for three crop rotations: wheat, barley and sugar beet; wheat, wheat and sugar beet; wheat only. A technical and economic analysis for each crop rotation was carried out. It was found that wheat produces significantly more biogas than either barley or sugar beet, when examined on a weight basis. However sugar beet produces more biogas and subsequently more energy when examined on an area basis. When producing biofuels, land is the limiting factor to the quantity of energy that may be produced. Thus if optimising land then a crop rotation of wheat, wheat and sugar beet should be utilised, as this scenario produced the greatest quantity of energy. This scenario has a production cost of €0.90/mN3, therefore, this scenario is competitive with petrol when the price of petrol is at least €1.09/l (VAT is charged at 21%). If optimising the production costs then a crop rotation of wheat only should be utilised when the cost of grain is less than €132/ton. This scenario has the least production cost at €0.83/mN3, therefore, this scenario is competitive with petrol when the price of petrol is at least €1.00/l. But as this scenario produces the least quantity of biogas, it also produces the least quantity of energy. In comparing with other works by the authors it is shown that a biomethane system produces more energy from the same crops at a cheaper cost than an ethanol system.

Abstract This study presents a detailed kinetic investigation into ultra-rich oxidation of H 2 S-CH 4 under high temperature (900–1250 °C) and ambient pressure. Effects of temperature, initial H 2 S/CH 4 ratio and equivalence ratio (Φ) on reactants conversions and products distributions were experimentally studied in a tubular flow reactor and kinetically analyzed by CHEMKIN software. A detailed kinetic mechanism involving 85 species and 515 reactions has been developed and validated using reference data for H 2 S-CH 4 decomposition and results from extended experimental conditions involving the O 2 addition. For H 2 S-CH 4 system, conversion of H 2 S increased steady with the rising temperature while reactivity of CH 4 was weak at temperature below 1000 °C. At temperature higher than 1000 °C, conversion of CH 4 increased rapidly and devoted further formation of H 2 and CS 2 mainly via reacting with H 2 S decomposition products. The H 2 production efficiency was negatively associated with initial H 2 S fraction as H 2 S decomposition was dominant H 2 source within 1150 °C. The stoichiometric ratio for H 2 S/CH 4 merely showed its advantage in H 2 production at higher temperature under which CH 4 reached its equilibrium conversion swiftly. Introduction of little amount of O 2 (Φ = 6 or higher) accelerated the whole reaction process and triggered H 2 S partial oxidation and H 2 formation at lower temperature. CH 4 explicitly showed inferior position in oxidation competition with H 2 S and maintained poor conversion at temperature below 950 °C. The results of rate of production (ROP) analysis at condition without O 2 showed that CH 4 reactivity showed dependence on free S radical via S + CH 4 = SH + CH 3 , and the formed CH 3 was mainly converted via reacting with SH and H radicals. CH 3 could be concurrently reverted to CH 4 via reactions with H 2 S and H 2 . O 2 activated the whole system by forming chain branching radicals O and OH. These radicals promoted H 2 S and CH 4 conversions to form richer S, H and CH 3 radicals. SH + CS = CS 2 + H was important for CS 2 formation and with presence of O 2 , CS 2 was likely to be consumed via oxidation reactions. Finally reaction pathways for H 2 S, CH 4 conversion and H 2 , CS 2 formation were presented.