• Energy Research
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Interfacial resistance at electrode‐high Li+ conductive solid electrolytes must be reduced well to develop high‐power all‐solid‐state batteries using oxide‐based solid electrolytes (Ox‐SSBs). Herein, crystalline electrode films of LiCoO2 (LCO) are formed on a high Li+ conductive crystalline‐glass solid electrolyte sheet, Li1.3Al0.3Ti2(PO4)3 (LATP) (σ25 °C = 1 × 10−4 S cm−1), at room temperature by aerosol deposition (AD), and the effects of the annealing temperature on the interfacial resistivities (Rint) at the LCO/LATP are investigated. The Rint visibly increases by annealing over 500 °C with the growth of Co3O4 as a reactant. In contrast, Rint is reduced to ≈100 Ω cm2 by low‐temperature annealing at 250–350 °C due to superior contact through the structural rearrangement of an artificial metastable interface formed by the AD. These results are applied to bulk‐type Ox‐SSB, Li/Li7La3Zr2O12(LLZ)/LCO–LATP, and our best Ox‐SSB delivers a discharge capacity of 100 mA cm−2 at 100 °C.

Dans des scénarios réalistes, la performance dynamique d'un cluster de micro-réseaux est largement affectée par la puissance intermittente des sources d'énergie renouvelables et les changements de charge fréquents. Pour résoudre ce problème, un contrôleur secondaire à double couche basé sur le temps fixe distribué est conçu pour améliorer les performances dynamiques inter-microgrid et intra-microgrid dans un temps de stabilisation fixe. Le contrôleur proposé est indépendant des valeurs de fonctionnement initiales par opposition à la loi de contrôle à temps fini. Chaque agent global dans un micro-réseau fonctionne pour atténuer le décalage de charge entre les autres agents globaux, tandis que chaque agent local dans un micro-réseau fonctionne pour réaliser un partage de courant de charge proportionnel et une régulation de tension moyenne entre eux dans un temps fixe. Cependant, comme l'atténuation de la non-concordance de chargement dans des conditions de charge légère affecte l'efficacité du système en raison de pertes de ligne importantes, le fonctionnement du cluster passe à une approche de minimisation des pertes distribuées, qui fonctionne en utilisant des mesures en ligne des micro-réseaux voisins. Pour caractériser le mode de fonctionnement dans la cyber-couche globale, un seuil de point de chargement critique pour le cluster est ainsi déterminé. La performance du cluster utilisant la stratégie proposée est simulée dans l'environnement MATLAB/SIMULINK pour divers scénarios afin de démontrer sa fiabilité et son efficacité. En escenarios realistas, el rendimiento dinámico de un grupo de microrredes se ve afectado en gran medida por la potencia intermitente de las fuentes de energía renovables y los frecuentes cambios de carga. Para abordar este problema, un controlador secundario de doble capa basado en tiempo fijo distribuido está diseñado para mejorar el rendimiento dinámico entre microrredes y entre microrredes dentro de un tiempo de asentamiento fijo. El controlador propuesto es independiente de los valores operativos iniciales en oposición a la ley de control de tiempo finito. Cada agente global en una microrred opera para mitigar el desajuste de carga entre otros agentes globales, mientras que cada agente local en una microrred opera para lograr un reparto de corriente de carga proporcional y una regulación de voltaje promedio entre ellos en un tiempo fijo. Sin embargo, como la mitigación de la falta de coincidencia de carga durante condiciones de carga ligera afecta la eficiencia del sistema debido a pérdidas de línea significativas, la operación del clúster cambia a un enfoque de minimización de pérdidas distribuidas, que opera utilizando mediciones en línea de las microrredes vecinas. Para caracterizar el modo de operación en la capa cibernética global, se determina así un punto crítico de umbral de carga para el clúster. El rendimiento del clúster que emplea la estrategia propuesta se simula en el entorno MATLAB/SIMULINK para varios escenarios para demostrar su confiabilidad y eficiencia. In realistic scenarios, the dynamic performance of a microgrid cluster is largely affected by the intermittent power of renewable energy sources and frequent load changes. To address this issue, a distributed fixed-time based dual layer secondary controller is designed to improve inter-microgrid and intra-microgrid dynamic performance within a fixed settling time. The proposed controller is independent of initial operating values as opposed to the finite time control law. Each global agent in a microgrid operates to mitigate loading mismatch between other global agents, whereas each local agent in a microgrid operates to achieve proportionate load current sharing and average voltage regulation between them in fixed time. However, as loading mismatch mitigation during light load conditions affects the system efficiency due to significant line losses, the cluster operation switches to a distributed loss minimization approach, which operates using online measurements from the neighboring microgrids. To characterize the mode of operation in the global cyber layer, a critical point of loading threshold for the cluster is thus determined. The performance of the cluster employing the proposed strategy is simulated in MATLAB/SIMULINK environment for various scenarios to demonstrate its reliability and efficiency. في السيناريوهات الواقعية، يتأثر الأداء الديناميكي لمجموعة الشبكات الصغيرة إلى حد كبير بالطاقة المتقطعة لمصادر الطاقة المتجددة والتغيرات المتكررة في الحمل. لمعالجة هذه المشكلة، تم تصميم وحدة تحكم ثانوية ثنائية الطبقة موزعة على أساس الوقت الثابت لتحسين الأداء الديناميكي بين الشبكات الدقيقة وداخلها في غضون وقت استقرار ثابت. وحدة التحكم المقترحة مستقلة عن قيم التشغيل الأولية بدلاً من قانون التحكم في الوقت المحدود. يعمل كل عامل عالمي في شبكة صغرى على التخفيف من عدم تطابق التحميل بين العوامل العالمية الأخرى، في حين يعمل كل عامل محلي في شبكة صغرى على تحقيق مشاركة تيار الحمل المتناسب ومتوسط تنظيم الجهد بينهما في وقت محدد. ومع ذلك، نظرًا لأن تخفيف عدم تطابق التحميل أثناء ظروف الحمل الخفيف يؤثر على كفاءة النظام بسبب الخسائر الكبيرة في الخطوط، تتحول عملية المجموعة إلى نهج تقليل الخسارة الموزعة، والذي يعمل باستخدام القياسات عبر الإنترنت من الشبكات الصغيرة المجاورة. لتوصيف طريقة التشغيل في الطبقة السيبرانية العالمية، يتم تحديد نقطة حرجة لعتبة التحميل للمجموعة. تتم محاكاة أداء المجموعة التي تستخدم الاستراتيجية المقترحة في بيئة ماتلاب/سيمولينك لسيناريوهات مختلفة لإثبات موثوقيتها وكفاءتها.

It is crucial to reduce the energy penalties related to CO2 capture processes if CCS is to be implemented at industrial scale. In this context, gas-solid sorption has become a relevant technology. The absence of large amounts of water when using dry solid sorbents and their high heat capacity reduce the energy requirements in the gas-solid sorption CO2 capture process. Depending on the sorbent composition, the gas-solid sorption process carries out at high or low temperatures. High temperature sorbents allow the utilization of waste energy while energy requirements in low temperature processes will be less demanding. This study is focused on the assessment and comparison of the final energy penalty of low-temperature (amine impregnated alumina-based solid particles) and high-temperature solid sorbents capture process (calcium oxide).

Abstract This study sought to quantify and characterize cassava waste as fuel. The wastes from three cultivars were collected to study and were divided into three distinct parts of the cassava plant: seed stem, thick stalks, and thin stalks. Physical and chemical analyzes were carried out to determine the elemental composition of the waste: volatile matter; fixed carbon; ash; moisture; lignin; cellulose; hemicellulose; ash composition and higher heating value were determined. We conducted a thermogravimetric analysis in oxidizing and inert atmospheres to study the behavior of the waste as fuel. The root productivity obtained ranged from 7.7 to 13.0 t ha−1 yr−1 on a dry basis (db), and the ratio between waste and roots varied from 0.36 to 0.91. The physical and chemical properties of cassava waste are analogous to those of woody biomass regarding the elemental composition, the higher heating value, and thermogravimetric analysis. Ash content varied from 2.5% to 3.5%, reaching around 6.0% in samples unwashed. Approximately 60% of the ashes are alkali oxides, especially P2O5, K2O, and CaO, which have low melting points. The alkali index calculated suggests that there is a strong tendency that the combustion process leads to ash fouling and the formation of ash deposits.

Green certificate is the green attribute of renewable energy generation. At present, voluntary green certificate purchase has been carried out in China. This paper firstly analyses the background and key points of green certificate policy in China. Secondly, it studies the implement situation and existing problems of green certificate transaction. Then, combining the new requirements of grid parity and renewables portfolio standards (RPS) policy, this paper proposes "2+2+2+3" green certificate trading mode in China, and establishes green certificate trading volume evaluation model. Evaluation result shows that the green certificate trading volume in State Grid Corporation of China (SGCC) business area in 2019 is 4.8 TWh.

AbstractTo estimate the life cycle cost of thermal power equipments in engineering, this paper established a comprehensive evaluation model of life cycle cost with the life cycle breakdown and cost breakdown structure. Based on the model, this paper defined the cost elements of the thermal power equipment, analyzed influences of the thermal power equipment. Finally, the model is applied to an instance to estimate various cost categories in each life phase, which were summed up to the life cycle cost of the thermal power equipment.

The rapid development of advanced metering infrastructure provides a new data source—building electrical load profiles with high temporal resolution. Electric load profile characterization can generate useful information to enhance building energy modeling and provide metrics to represent patterns and variability of load profiles. Such characterizations can be used to identify changes to building electricity demand due to operations or faulty equipment and controls. In this study, we proposed a two-path approach to analyze high temporal resolution building electrical load profiles: (1) time-domain analysis and (2) frequency-domain analysis. The commonly adopted time-domain analysis can extract and quantify the distribution of key parameters characterizing load shape such as peak-base load ratio and morning rise time, while a frequency-domain analysis can identify major periodic fluctuations and quantify load variability. We implemented and evaluated both paths using whole-year 15-minute interval smart meter data of 188 commercial office building in Northern California. The results from these two paths are consistent with each other and complementary to represent full dynamics of load profiles. The time- and frequency-domain analyses can be used to enhance building energy modeling by: (1) providing more realistic assumptions about building operation schedules, and (2) validating the simulated electric load profiles using the developed variability metrics against the real building load data.

AbstractThis report illustrates the experimental data associated with solar overheating. The experimental data has validated an analytical model which allows for the study of the influences a primary circuit's design has on the overheating of the solar tank.Secondly, the report includes a study of the stagnation in a solar facility. The evolution of the temperature in the hydraulic circuit by means of its measurement at 30 different points, together with the data of the pressure and flow, allow for the real behavior of the solar installation in stagnation conditions to be investigated.Finally, the study shows the measurements obtained on a solar thermal installation located in Alicante (southern Spain). Every installation has been monitored for several months and the main temperatures and pressures around the solar circuit have been noted. The measurements and their processing have allowed for the detection of overheating and stagnation problems in real operating conditions.