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AbstractThe ethylene glycol oxidation reaction on nickel and ruthenium modified palladium nanocatalysts was investigated with electrochemical, spectroelectrochemical, and chromatographic methods. These carbon‐supported materials, prepared by a revisited polyol approach, exhibited high activity towards the ethylene glycol electrooxidation in alkaline medium. Electrolysis coupled with high performance liquid chromatography/mass spectrometry (HPLC‐MS) and in situ Fourier transform infrared spectroscopy (FTIRS) measurements allowed us to determine the different compounds electrogenerated in the oxidative conversion of this two‐carbon molecule. High value‐added products such as oxalate, glyoxylate, and glycolate were identified in all electrolytic solutions, whereas glyoxylate was selectively formed at the Ru45@Pd55/C electrode surface. In situ FTIRS results also showed a decrease in the pH value in the thin layer near the electrode as a consequence of OH− consumption during the spectroelectrochemical experiments.

Abstract In this paper, a general mathematical model for the dynamic simulation of a single-effect LiBr/water absorption chiller is presented. The model is based on mass and energy balances applied to the internal components of the machine, and it accounts for the non-steady behaviour due to thermal and mass storage in the components. The validation of the mathematical model is performed through experimental data collected on a commercial small-capacity water-cooled unit. Due to the peculiar technology adopted in the real chiller, a special effort was made to identify the appropriate values of the main physical parameters. The validation of the model is based on the values of the water temperature at the outlet of the machine, as no measurement inside the machine was possible; anyway, a consistency analysis applied to the internal parameters is also presented. The agreement between experimental and simulated results is very good, both on a daily and on a seasonal basis.

This paper addresses the study of vibrations induced by turbulent boundary layers (TBLs) flowing over plate-like structures. The aim is here to propose a predictive method in order to evaluate the vibroacoustical behaviour of a plate excited by TBL pressure fluctuations. The ultimate goal is to develop tools for predicting internal cabin noise in an aircraft during flight. Hence TBL is considered. Different TBL models are discussed and compared. A prediction method well suited for mid-high frequencies is also presented. The method called simplified energy method (SEM) is based on local energetic considerations and extends the well-known statistical energy analysis (SEA). Two different SEM formulations are presented. The first one is of heat conduction type, whilst the second is radiative. The TBL source model was integrated in the local energy proposed formulations. When applied to a simple Kirchhoff-Love simply supported plate, SEM allows prediction of averaged energy quantities. Comparisons are drawn between heat and radiative formulations. Good concordance was observed between energy results and pure analytical calculations of the structural response under TBL excitation over a wide frequency range.

Cu(In,Ga)Se-2-based solar cells buffered with indium sulfide grown by numerous techniques have reached efficiencies comparable to those achieved by standard devices buffered with (CBD)CdS. The present paper firstly recalls some of the properties of the indium sulfide single crystal and Points Out the disagreements concerning the thin films properties inventoried in the literature. Secondly, the influence of the presence of some "foreign elements" within file indium sulfide on its properties is presented. It is shown that these "foreign elements", even at low concentration levels, are possibly at the origin or the thin films properties deviations compared to the single crystal. The impact of these contaminants on the solar cells performance is finally discussed.

The movement of the powdery material occurs in a multi-phase non-uniform electrostatic field at determined values of the voltage and the frequency, using travelling wave technique. This technique was applied for very small particles such as bacteria and other similar particle size. The objective of this work is to analyze the movement of PVC micronized particles and the feasibility of the separation of PVC/copper granular mixture of average size 100 μm. Two-phase and three-phase conveyors, which are supplied by high voltage amplifiers controlled by digital function generators, have been the subject of a parametric experimental investigation. Several factors were analyzed such as the voltage level up to 1400 V, the frequency, the phase shift and the number of phases of the conveyor. The obtained results showed that depending on the values of the above factors: i) the micronized particles can move instantly right after switching the conveyor, ii) the particles move towards one direction or the other of the conveyor iii) the separation of a granular mixture of plastic and copper micronized particles is possible.

n the French context of increasing renewable penetration and significant nuclear power, the optimal contribution of this energy source is discussed from two viewpoints. On the one hand, from the social planner viewpoint, the nuclear optimum contribution is the one that minimizes the overall electric price, whatever the resulting load factor. The use of screening curves, often implemented to design the optimal power mix is questioned, being highly sensitive to the assumptions. On the other hand, from the plant operator viewpoint, the nuclear power plants need to amortize the capital expenses, hence achieve the longest operating time. With a view to make the two viewpoints meet, we propose to operate nuclear power plants as baseloads and consider modulation through the power use, i.e. supply electricity to the electric system when requested and use the remaining power to produce other valuable products, such as heat or hydrogen.

This paper presents a careful study related to a more efficient energy management between lithium battery (with rated voltage of 24V) and Ultracapacitors (UC) for Hybrid Electric Vehicle (HEV) applications. This association is due to the present trend in the field, knowing that the major drawback of the HEV is the autonomy problem. Thus, using the Hybrid energy source (such as UC + battery) and with a good energy management improves the HEV performances. In this paper, battery and Ultracapacitors (10 cells of 2.7V in series) are coupled to DC-bus using two buck-boost converters. The main contribution of this paper is focused on DC-bus voltage and currents control strategy based on polynomial (RST) controller. Through some simulations in MATLAB/Simulink software and experimental results, the authors present an improved energy management for HEV.